Few systematic and scientific assessments have been conducted on marine environmental quality in the coastal waters of Macao, a major city in the Pearl River Delta, China. In this study, we investigated the spatial distribution of trace metals (TMs) and comprehensive contamination indicators of marine water in Macao and evaluated their ecological risks. The total amount of typical TMs (∑TMs) in surface water ranged from 2.71 μg/L to 201 μg/L. ∑TMs (Hg, As, and Cd) in sediments ranged from 0.34 mg/kg to 54.8 mg/kg. TM contamination in surface water was influenced by spatial position and tidal current direction. The spatial distribution and correlation analysis of TMs and comprehensive contamination indicators were assessed, and ecological risk assessment indicated that the surface water and sediments in coastal waters of Macao are of relatively good quality, although high sulfide levels could be detected in surface water.

This paper increases knowledge on litter transfer from sediments towards the trophic web throughout sea cucumbers, key protected benthic species. In October, sediment and holothurian samples from seventeen sampling sites from Croatian Islands characterized by different levels of protection (Silba n = 7; Telašćica MPA n = 10) were collected. Collected particles ranged in sediments within 113.4–377.8 items/kg d.w., and in holothurians within 0.6–9.4 items/animal, showing sizes within 1.4–10,493 μm. In holothurians, cellulose and cellulose acetate (non-synthetic materials) mean percentages were within 5.0–12.7% of the total amount of particles. Nylon fibres ranged within 0–26.7%; while PP, PE, PA, and PS% were more abundant than in sediments. Among factors of variability tested, “island group” and “level of protection” resulted to affect plastic composition in sediments. Otherwise, other environmental factors (i.e. orientation, morphology of sampling site, P. oceanica) were significantly related to chemical composition of microplastic ingested by holothurians.

PURPOSE OF REVIEW: The study of organic aerosol hygroscopic growth and cloud droplet activation is crucial for accurately quantifying their climate and environmental impacts. However, the physical mechanisms behind organic aerosol hygroscopicity variations are not well understood. In this review, we summarized laboratory and field measurements of the organic aerosol hygroscopicity parameter κOA, discussed the physical understanding of why κOA was generally positively correlated with organic aerosol oxidation level, summarized proposed κOA parameterization schemes, and examined possible explanations for the marked differences among these parameterization schemes. RECENT FINDINGS: Recent findings challenged the general cognition that cloud condensation nuclei (CCN) activity of secondary organic aerosol depended largely on solubility, showing it to be mainly controlled by molecular weight, yet the universality of this finding needs to be further examined. It was found that carbon chain length and functional groups had significant impacts on κOA and additional parameters other than O/C ratio need to be included when parameterizing κOA of multifunctional compounds, which is typically the case for ambient atmospheric aerosols. Additionally, laboratory results of secondary organic aerosol suggest that κOA might be highly RH-dependent under sub-saturated conditions, especially for biogenic secondary organic aerosols. This review summarized laboratory and field measurements of atmospheric organic aerosol hygroscopicity parameter κOA and its parameterization schemes. The results demonstrate that representing κOA with a single oxidation level parameter still bears large uncertainty, and physical mechanisms associated with hygroscopic growth and cloud activation processes of organic aerosol still remain unresolved and need further investigation.

As part of the Deepwater Horizon Oil Spill Natural Resource Damage Assessment in the Gulf of Mexico, we conducted a large passive acoustic survey across the eastern Gulf continental shelf edge to assess impacts to sperm whale population. In the months immediately after the spill, sperm whale occurrence was significantly higher in areas closest to the spill. Over the following seasons in 2010–2011, we documented cyclical patterns of decreased and increased occurrence suggesting that this population exhibits a seasonal occurrence pattern in the region, with seasonal movements to other regions, and not likely directly influenced by the oil spill. Unfortunately, a lack of adequately scaled, pre-spill data on sperm whales, along with limitations on the survey duration constrain our ability to infer spill-related changes in sperm whale occurrence. However, our study establishes post-disaster baseline data for continued monitoring, and an expanded study design could provide a model for continued monitoring.

Copper (Cu) is an essential metal capable to alter many metabolic and physiological processes in animal species, depending on the environmental concentration and salinity. The present study evaluated the effects of Cu exposure on the metabolism of the blue crab Callinectes sapidus under different osmotic situations. Crabs were acclimated at two different salinities conditions (30 and 2). Subsequently, they were exposed to Cu during 96 h at each salinity and under hypo-osmotic shock. Results demonstrated that Cu exposure increased whole-body oxygen consumption. In addition, the activity of LDH decreased while citrate synthase increased in anterior gills from animals submitted to hypo-osmotic shock. This scenario indicates extra stress caused by sudden environmental osmotic changes, as commonly observed in estuarine environments, when combined with copper exposure. Therefore, the activity of LDH and citrate synthase enzymes might be sensitive indicators for aquatic toxicology studies approaching Cu contamination in estuarine environments.

The faunistic analysis of soft bottom benthic materials collected from the Aegean and Levantine coasts of Turkey in August 2016 and 2017 revealed a total of 7 sipuncula species and 975 individuals belonging to 6 genera. The maximum population density of sipunculans was found to be 1790 ind.m⁻² in the Aegean Sea and 730 ind.m⁻² in the Levantine Sea. Onchnesoma steenstrupii steenstrupii was the most dominant species, comprising 83.1–92.8% of the total number of specimens in the Aegean Sea and 87.2–96.2% of the total number of specimens in the Levantine Sea. Four major sipunculan assemblages were found in the regions, and the main environmental factors controlling these assemblages were depth, temperature, salinity, the sediment grain size, nutrients and total organic carbon. Different abiotic factors affected the distribution of different sipunculan species in the regions. The present study included two cryptogenic sipunculan species; Apionsoma (Apionsoma) misakianum and Aspidosiphon (Aspidosiphon) mexicanus.

Colonization dynamics of protozoan communities were investigated at a depth of 1 m in the coastal waters of the Yellow Sea, northern China from May to June 2019, using modified glass slide (mGS) and modified polyurethane foam unit (mPFU) systems. The colonization process and growth curves of protozoa were well fitted to the MacArthur-Wilson and logistic models in both systems, respectively. However, they showed significant differences in both colonization dynamics and biodiversity/functional parameters between the mGS and mPFU systems. The Hˊ (species diversity), the G (colonization rate), and Aₘₐₓ (maximum abundance) were higher, while the value of T₉₀% (the time for reaching 90% equilibrium species number) was lower in the mGS system than those in the mPFU system. Multivariate analyses demonstrated that protozoa showed different models of colonization dynamics in both systems. The results suggest that the mGS system might be more effective than the mPFU system in marine bioassessment surveys.

As oil production worldwide continues to increase, particularly in the Gulf of Mexico, marine oil spill preparedness relies on deeper understanding of surface oil spill transport science. This paper describes experiments carried out on a chronic release of crude oil and aims to understand the residence time of oil slicks using a combination of remote sensing platforms and GPS tracked drifters. From April 2017 to August 2018, we performed multiple synchronized deployments of drogued and un-drogued drifters to monitor the life time (residence time) of the surface oil slicks originated from the MC20 spill site, located close to the Mississippi Delta. The hydrodynamic design of the two types of drifters allowed us to compare their performance differences. We found the un-drogued drifter to be more appropriate to measure the speed of oil transport. Drifter deployments under various wind conditions show that stronger winds lead to reduce the length of the slick, presumably because of an increase in the evaporation rate and entrainment of oil in the water produced by wave action. We have calculated the residence time of oil slicks at MC20 site to be between 4 and 28 h, with average wind amplitude between 3.8 and 8.8 m/s. These results demonstrate an inverse linear relationship between wind strength and residence time of the oil, and the average residence time of the oil from MC20 is 14.9 h.

A statistical oil spill risk forecast model in support of emergency response and environmental risk assessment is presented by combing the deterministic model, probabilistic strategy and frequency estimation. When applied to evaluate various potential spill sources (oil port, fairway, anchorage and pipeline) in the Zhoushan offshore area, the model provides the probability of slick spatial position, oil slick thickness, and exposure duration of floating slick. An oil spill risk map is generated after integrating multiple spill sources, which is a powerful tool for identifying high-risk areas and developing contingency plan. Impact scope and damage degree vary among different sources because of special local topographical, hydrological, and meteorological conditions, where generally exists high pollution intensity of point-source and wide range of line-source. Huge Changjiang River runoff prevents coastal sea in the north from being contaminated by spilled oil from the southern Zhoushan offshore area.

We investigated the source, composition, and reactivity of particulate organic carbon (POC) in two contrasting Korean estuary systems, a closed estuary (Geum) (i.e., with an estuary dam at the river mouth) and an open (Seomjin) estuary. A dual isotope (δ¹³CPOC and Δ¹⁴CPOC) approach was applied to surface water samples collected along a salinity gradient in August 2016. Our results indicate that phytoplankton-derived POC was the main contributor to the total POC pool in the reservoir of the Geum estuary, while terrestrial-derived POC predominated the upper Seomjin estuary. A simple binary mixing model using Δ¹⁴CPOC revealed a higher modern POC contribution (87–90%) in the Geum estuary reservoir than that (77%) of the upper Seomjin estuary. Accordingly, it appears that an estuary dam can alter the source and reactivity of POC in a reservoir, which can be transferred to the adjacent coastal ecosystem.