Breast cancer is the most common cancer worldwide. Recent studies suggest that organic solvent exposure could be closely related to breast cancer, although the evidence remains controversial. Thus, we evaluated existing epidemiological evidence for the association between occupational solvent exposure and breast cancer. PubMed, Embase, and Cochrane Library were searched to identify published case–control and cohort studies that addressed occupational exposure to organic solvents and breast cancer, up to April, 2021. Meta-analyses using random-effects models were conducted to obtain the pooled odds ratios (OR) and 95% confidence intervals (CI) on the incidence of breast cancer in relation to occupational exposure. The pooled OR of breast cancer among workers exposed to organic solvents overall was 1.18 (95%CI, 1.11 ~ 1.25; I² = 76.3%; 24 studies), compared to those with no exposure. After stratification by menopause and study location, it was revealed that the association between occupational exposure to organic solvents and the risk of breast cancer in postmenopausal women (OR, 1.35; 95% CI, 1.09 ~ 1.67; I² = 73.4%; 7 studies) was significant, and there was also a clear association in workers in Europe (OR, 1.21; 95% CI, 1.12 ~ 1.32; I² = 82.9%; 13 studies). We observed a significant association between occupational exposure to organic solvents and breast cancer in both cohort and case–control studies.

Caustic chemicals are widely distributed in our environment. Exposure to caustic agents is a lifelong problem associated with severe tissue and mucous membrane injuries. In pediatrics, corrosive exposure is the most common cause of nonpharmaceutical exposure presenting to poison control centers. Therefore, this study evaluated the role of the Pediatric Early Warning System (PEWS) and Drooling Reluctance Oropharynx Others Leukocytosis (DROOL) scores as early in-hospital outcome predictors following corrosive ingestion. The current study was a two-center, retrospective, cross-sectional study carried out among pediatric patients diagnosed with acute caustic ingestion during the past 4 years. Most exposure occurred accidentally among boys (59.4%) living in rural areas (51.9%) of preschool age (50% were 2–4 years old). Residence, body temperature, respiratory rate, vomiting, skin and mucosal burns, retrosternal pain, respiratory distress, Oxygen (O2) saturation, Glasgow Coma Scale score, HCO₃ level, total bilirubin level, anemia, leukocytosis, and presence of free peritoneal fluid were significant predictors of esophageal injuries (p < 0.05). DROOL and PEWS scoring were the most significant predictors of esophageal injuries with worthy predictive power, where odds ratio (95% confidence interval (CI)) was 1.76 (0.97–3.17) and 0.47 (0.21–0.99) for PEWS and DROOL, respectively. At a cutoff of < 6.5, the DROOL score could predict esophageal injuries excellently, with AUC = 0.931; sensitivity, 91.7%; specificity, 72.5%; and overall accuracy, 91.3%. At a cutoff of > 6.5, PEWS could significantly predict unfavorable outcomes, with AUC = 0.893; sensitivity, 94.4%; specificity, 71.9%; and overall accuracy, 89.3%. However, PEWS better predicted the need for admittance to the intensive care unit (ICU). Pediatric Early Warning System (PEWS) and Drooling Reluctance Oropharynx Others Leukocytosis (DROOL) are potentially useful accurate scorings that could predict the esophageal injuries and ICU admission following corrosive ingestion in pediatrics.

This paper investigates the relationship between energy intensity, economic freedom, and carbon emissions. The problem of environmental degradation, economic freedom, and energy use is mainly studied for developed economies; however, this study has selected forty-one Asia-Pacific economies representing all income groups of the World Bank’s classification. In the presence of income, economic freedom plays a dual role for environment and energy: direct impact and as moderating factor impact. Here, we empirically test for a panel of 41 Asia-Pacific countries using the autoregressive distributed lag approach. Our findings suggest, although there is no bidirectional causality between all the variables, the long-run estimates of economic freedom for economy and environment are positive. The results imply for substantial structural reforms with a favorable economic and regulatory environment for Asia-Pacific countries. Our empirical analysis also implies that GDP growth levels for Asia-Pacific countries are becoming increasingly dependent on economic freedom and energy intensity. The results underline the critical role played directly and indirectly by economic freedom in creating an atmosphere that promotes research and development activities to help reduce energy intensity shortly to solve environmental problems.

Membrane biofouling in water purification plants is a serious issue of worldwide concern. Various chemical, physical, and biochemical processes are practised for membrane clean-up. A high-dosage treatment adversely affects the life expectancy of the membrane, and minimum dosage seems unable to deteriorate the biofilms on the membrane. It is reported that quorum quenchers like nitric oxide (NO) disrupt biofilm signals through metabolic rewiring, and also NO is known to be secreted by probiotics (good bacteria). In the present review, it is hypothesized that if probiotic biofilms secreting NO are used, other microbes that aggregate on the filtration membrane could be mitigated. The concept of probiotic administration on filtration membrane seeks to be encouraged because probiotic bacteria will not be hazardous, even if released during filtration. The fundamental motive to present probiotics as a resource for sequestering NO may serve as multifunctional bioweapons for membrane remediation, which will virtually guarantee their long-term sustainability and green approach.

Urban heat island (UHI) has a great influence on human wellbeing in urban areas. Previous studies have investigated impact on environment, ecosystem, and human health of UHI. To investigate economic impact of UHI is a lack of research. In this study, spatial-econometric hedonic housing price models are developed for estimating the marginal value of summer UHI in Beijing, China. The results showed that UHI effects in Beijing became severe from 2015 to 2017. The heat islands showed a mix of high and sub-high land surface temperature (LST). The spatial Durbin model estimates that one-unit increase of UHI intensity (UHII) would lower the housing value by 3.91%. Regarding the different districts, households had different attitudes to the UHI effect. Specifically, households regarded UHI effect as amenity in the four suburban districts with hills and relatively low LSTs; however, in most urban districts and their surroundings, households were willing to pay to avoid UHI effects with 13.0 dollars to 826.3 dollars for one-degree UHII decrease. This study highlights the urgent need for planners and decision-makers to consider urban expansion, UHI effect, and their economic impact in future urban planning.

The improper use of antibiotics and their discharge into the environment can have serious and hazardous consequences. The purpose of this research is to synthesize an activated carbon impregnated magnetite composite (PAC/Fe), prepare PAC/Fe/Ag/Zn nanocomposites, and innovate by simultaneously synthesizing two metals, zinc and silver, on magnetically activated carbon and check its ability to remove azithromycin antibiotic (AZT) from an aqueous solution via UV system. PAC/Fe/Ag/Zn nanocomposites were characterized by various techniques including XRD, FESEM, and EDX. A series of batch experiments were carried out under various experimental conditions such as pH of the solution (3–11), contact time (0–120 min), initial concentration of AZT (10–40 ppm), amount of PAC/Fe/Ag/Zn nano-absorbent (0.01–0.04 g/l), and recoverability and reuse. Some common isotherm models were used for the study of AZT adsorption removal and finding the best model. Also, kinetic studies of AZT removal were performed by fitting the experimental data on first-order and second-order models. In this system, under optimal conditions of pH = 9, 120 min with 0.04 g/l of PAC/Fe/Ag/Zn, 99.5% of 10 ppm AZT were degraded under UV-C irradiation. Furthermore, the obtained results of isotherm and kinetic studies revealed that Langmuir (R² = 0.9336) isotherm model, and the pseudo-first-order kinetic model (R² = 0.9826) had the highest correlation with the experimental data of AZT antibiotic adsorption. Finally, the reusability experiments showed that PAC/Fe/Ag/Zn nanocomposites have a high ability of antibiotic adsorption and high stability after four cycles of application (99.5 to 40%).

Perennial ryegrass (Lolium perenne L.) was planted in uranium-contaminated soil mixtures supplemented with different amounts of citric acid to investigate the defense strategies of perennial ryegrass against U and the enhanced mechanism of citric acid on the remediation efficiency in the laboratory. The uranium content in the plant tissues showed that the roots were the predominant tissue for uranium accumulation. In both root and shoot cells, the majority of U was located in the cell wall fraction. Furthermore, antioxidant enzymes were also stimulated when exposed to U stress. These results suggested that perennial ryegrass had evolved defense strategies, such as U sequestration in root tissue, compartmentalization in the cell wall, and antioxidant enzyme systems, to minimize uranium stress. For an enhanced mechanism, the optimal concentration of citric acid was 5 mmol/kg, and the removal efficiency of U in the shoots and roots increased by 47.37% and 30.10%, respectively. The treatment with 5 mmol/kg citric acid had the highest contents of photosynthetic pigment and soluble protein, the highest activity of antioxidant enzymes, and the lowest content of MDA (malondialdehyde) and relative electrical conductivity. Moreover, the TEM (transmission electron microscope) results revealed that after 5 mmol/kg citric acid was added, the cell structure of plant branches partially returned to normal, the number of mitochondria increased, chloroplast surfaces seemed normal, and the cell wall became visible. The damage to the cell ultrastructure of perennial ryegrass was significantly alleviated by treatment with 5 mmol/kg citric acid. All the results above indicated that perennial ryegrass could accumulate uranium with elevated uranium tolerance and enrichment ability with 5 mmol/kg citric acid.

The present study aimed to prepare a highly efficient power ultrasound modified novel biosorbent using seaweed (UAS). Response surface methodology (RSM) and artificial neural network (ANN) were applied for modeling and optimizing the removal of methylene blue (MB), a cationic dye from the aqueous solution. The optimal adsorption efficiency of the biosorbent was achieved at the ultrasonic amplitude of 100%, treatment time of 7 min, and the solid–liquid ratio of 70 mL. The application of ultrasound on the raw seaweed increased the surface area by 27.33%, which was then analyzed for its adsorptive capacity on MB dye. Langmuir isotherm model described the best adsorption behavior and showed a maximum adsorption capacity of 1095.29 mg/g which was 63.47% higher compared to the tomato waste-based activated carbon for MB dye. Furthermore, adsorbent doses, pH, temperature, and dye concentration affect the adsorption capacity of UAS. The optimum values of pH and adsorbent doses were observed as 6.3 g/L and 2 g/L, respectively. The maximum desorption efficiency (DE) was observed for ethanol (95%), whereas it was least (58%) for sodium chloride (NaCl). The result shows the potential use of prepared power ultrasound-assisted seaweed biosorbent for removal of cationic dye (MB) as well as an efficient green technology for ecological and environmental sustainability. Prediction of increased adsorption capacity of prepared biosorbent was successfully done by artificial neural networks with a coefficient of correlation of 0.9991.

Renewable energy plays a significant role in achieving energy savings and emission reduction. As a sustainable and environmental friendly renewable energy power technology, concentrated solar power (CSP) integrates power generation and energy storage to ensure the smooth operation of the power system. However, the cost of CSP is an obstacle hampering the commercialization of this emerging industry, so the paper studies the technical characteristics, economic analysis, and policy implications of CSP. This paper sorts out the relevant policies of CSP and uses the levelized cost of electricity (LCOE) model by considering financial parameters, investment parameters, operation and maintenance parameters, tax parameters, capacity parameters, etc., to analyze the economics of CSP. The model parameters are set by the actual situation of CSP projects. The economic evaluation of different technology types of parabolic trough (PT), solar tower (ST), secondary reflection ST, and linear Fresnel reflector (LFR) is carried out. The LCOE of PT project is 1.11 RMB/kWh (0.17 US$/kWh), the ST project is 0.93 RMB/kWh (0.14 US$/kWh), the secondary reflection ST project is 0.97 RMB/kWh (0.15 US$/kWh), and the LFR project is 0.92 RMB/kWh (0.14 US$/kWh). The results show that the grid parity era of CSP in China is within reach, and ST is the most potential technology type. Based on the results of economic analysis and the problems faced by CSP in China, this paper puts forward policy implications by preferential loans, tax incentives, and R&D fund support to promote the development of CSP.

Herein improved solar light–driven photocatalytic degradation and mineralization of two emerging pollutants as well as recalcitrant beta blockers propranolol (PR) and atenolol (AT) have been demonstrated by metal-free carbon dot/TiO₂ (CDT) composite. Hydrothermally synthesized TiO₂ has been decorated with electrochemically synthesized carbon dots (CDs) and was well characterized by various analytical techniques viz. XRD, FTIR, Raman, XPS, UV–visible DRS, FESEM, and TEM. The optimized CDT composite, 2CDT (2 mL carbon dot/TiO₂), showed ~ 3.45- and ~ 1.75-fold enhancement in the photodegradation rate as compared to pristine TiO₂ for PR and AT respectively in 1 hour of irradiation along with complete degradation of PR and AT after 3 hours of irradiation. 2CDT exhibited 76% and 80% mineralization of PR and AT in contrast with 62% and 47% observed by pristine TiO₂. Further, the major reaction intermediates formed after degradation have been identified by HPLC/MS analysis, confirming more than 99% reduction of the parent compound for both PR and AT. Reusability of the optimized catalyst also showed successful degradation up to 3 cycles, showing reduction abilities of 97%, 95%, and 94% for 1st, 2nd, and 3rd cycle respectively. The enhanced degradation and mineralization efficiency of the 2CDT composite could be attributed to the excellent photosensitizer and electron reservoir properties of the CD along with upconverted photoluminescence behavior. The present study unlocks the possibility of using metal-free, facile CDT composite for effective degradation and mineralization of widely used beta blockers and other pharmaceuticals.