Carbon emissions in the power sector are an important part of China’s total carbon emissions and have a significant impact on whether China can achieve the 2030 carbon peak target. Based on the three perspectives of decomposition, decoupling, and prediction, this paper studies the feasibility of carbon emission peaks in eight major regional power sectors in China. First, the generalized Divisia index model (GDIM) is used to decompose the carbon emissions of the eight regional power sectors, and the driving factors and their effects on carbon emissions in the power sector of each region are compared. Then, the decoupling index based on the generalized Divisia index model (GDIM-D) is used to study the decoupling relationship between the carbon emissions of the eight regional power sectors and economic growth. Finally, the carbon emissions and decoupling indices of the power sector from 2017 to 2030 are predicted. The results show the following. First, the gross domestic product (GDP) and output scale are the main factors contributing to the carbon emissions of the eight regional power sectors. The carbon intensity of the power sector in GDP (C/G) and output carbon intensity(C/E) are the main factors that contribute to the reduction. Second, the carbon emissions of the southern coast, the middle Yellow River, and the Southwest peaked in 2013 and have been decoupled from economic growth, while those in the other regions have not peaked or decoupled. Third, if the carbon emissions of the power sector in the Northeast, northern coast, eastern coast, middle Yangtze River, and Northwest reach a peak in 2030, they will face many emission reduction pressures. This paper provides a reference for studying the carbon emissions of China’s regional power sectors and their relationship with economic growth and has important implications for peak carbon emissions at the national level.

Pig farming has a very strong economic importance in Brazil. The residues from this activity are applied to the soil because of their excellent characteristics as biofertilizers. The present study aimed at studying the estrone, 17β-estradiol, and estriol natural hormones, emerging contaminants present in this type of residue that are not mentioned in the current legislation. The characterization of the pig farming effluent presented high concentrations of hormones (mg L⁻¹). The objective was to apply the biosorbents to the removal of the hormones in batch systems directly in the manure heaps without affecting the potential of the effluent as a fertilizer. It was verified that the adsorption of hormones using the rice husk biomass in natura and soybean hull in natura, abundant alternative adsorbents, presented a good capacity of removal of hormones. The presence of the organic materials (rice husk and soybean hull) caused few alterations in the biofertilizer characteristics, demonstrating that these adsorbents present a potential of application in batch treatment systems, with possible applications related to pig farming effluents containing natural hormones.

Anammox process is considered as a promising technology for removing total nitrogen from low-strength ammonium and phenol-containing wastewater. However, it is still a challenge for the anammox process to treat high-strength ammonium and phenol-containing wastewater. A completely separated partial nitritation and anammox (CSPN/A) process was developed to remove total nitrogen from high-strength phenol-containing wastewater. About 92% of COD, 100% of phenol, and 82.4% of total nitrogen were successfully removed at a NH₄⁺-N concentration of 200 mg L⁻¹ with a phenol/NH₄⁺-N mass ratio of 0.5 in the CSPN/A process. Furthermore, a shock loading of 300 mg phenol L⁻¹ with a phenol/NH₄⁺-N mass ratio of 1.5 led to a complete failure of partial nitritation, but the performance was rapidly recovered by the increase of NH₄⁺-N concentration. Although the activities of ammonium-oxidizing bacteria and anammox bacteria were severely inhibited at a phenol/NH₄⁺-N mass ratio of 1.5, the enrichment of efficient phenol degraders in the CSPN stage could strengthen the performance robustness of partial nitritation and anammox process. Therefore, this study presented a new insight on the feasibility of the anammox process for treating high-strength ammonium and phenol-containing wastewater.

The objectives of this study were to (1) conduct laboratory bench and column experiments to determine the oxidation kinetics and optimal operational parameters for trichloroethene (TCE)-contaminated groundwater remediation using potassium permanganate (KMnO₄) as oxidant and (2) to conduct a pilot-scale study to assess the efficiency of TCE remediation by KMnO₄ oxidation. The controlling factors in laboratory studies included soil oxidant demand (SOD), molar ratios of KMnO₄ to TCE, KMnO₄ decay rate, and molar ratios of Na₂HPO₄ to KMnO₄ for manganese dioxide (MnO₂) production control. Results show that a significant amount of KMnO₄ was depleted when it was added in a soil/water system due to the existence of natural soil organic matters. The presence of natural organic material in soils can exert a significant oxidant demand thereby reducing the amount of KMnO₄ available for the destruction of TCE as well as the overall oxidation rate of TCE. Supplement of higher concentrations of KMnO₄ is required in the soil systems with high SOD values. Higher KMnO₄ application resulted in more significant H⁺ and subsequent pH drop. The addition of Na₂HPO₄ could minimize the amount of produced MnO₂ particles and prevent the clogging of soil pores, and TCE oxidation efficiency would not be affected by Na₂HPO₄. To obtain a complete TCE removal, the amount of KMnO₄ used to oxidize TCE needs to be higher than the theoretical molar ratio of KMnO₄ to TCE based on the stoichiometry equation. Relatively lower oxidation rates are obtained with lower initial TCE concentrations. The half-life of TCE decreased with increased KMnO₄ concentrations. Results from the pilot-scale study indicate that a significant KMnO₄ decay occurs after the injection due to the reaction of KMnO₄ with soil organic matters, and thus, the amount of KMnO₄, which could be transported from the injection point to the downgradient area, would be low. The effective influence zone of the KMnO₄ oxidation was limited to the KMnO₄ injection area (within a 3-m radius zone). Migration of KMnO₄ to farther downgradient area was limited due to the reaction of KMnO₄ to natural organic matters. To retain a higher TCE removal efficiency, continuous supplement of high concentrations of KMnO₄ is required. The findings would be useful in designing an in situ field-scale ISCO system for TCE-contaminated groundwater remediation using KMnO₄ as the oxidant.

Chromium (Cr) is one of the most common metal pollutants and has thus attracted considerable attention. In this study, we investigated the potential use of biogas solid residue (BSR) from anaerobic digestion as an effective amendment to decrease the bioavailability of Cr in Cr(VI)-polluted soil using pot experiments. Compared to the no-addition treatment, the addition of BSR (treatments—50, 100, and 150 g kg⁻¹ soil) increased the soil nutrient levels, microbial diversity and activities, and decreased the redox potential (Eh). BSR treatment of Cr(VI)-contaminated soil caused a reduction in soil Cr(VI) concentration (16.6–52.1%) and the exchangeable Cr proportion (15.2–52.4%), thereby decreasing the available Cr for uptake by plants. BSR treatments resulted in a reduction in the Cr contents of the roots and aboveground biomass of pakchoi plants. The Cr(VI) content in treated soils decreased with increasing BSR addition, with 150 g kg⁻¹ being the most efficient application. The relative abundance of Cr-reducing groups, such as Pseudomonas, Microbacterium, and Bacillus, increased with the increase in BSR application. The enhancement of soil Cr(VI) immobilization by the addition of the BSR was mostly attributed to the simultaneous effect of organic matter addition, stimulation of microorganisms, and reduced Eh value. Organic matter contributed more to the variation in Cr. The presence of BSR decreased the bioavailability of Cr in the soil and, therefore, lowered the potential mobilization of Cr(VI) from the soils. Our results demonstrated that BSR application may offer a potentially promising solution for enhancing agricultural production in Cr-contaminated soils.

Various perovskite-type catalysts including La₂CoMnO₆, LaCoO₃, and LaMnO₃ are first evaluated for the activities toward C₇H₈ removal. Experimental results indicate that double-type La₂CoMnO₆ shows better activity if compared with single perovskites due to high lattice oxygen content and good reducibility. Subsequently, perovskite catalysts are combined with plasma (NTP) to form in-plasma catalysis (IPC) and post-plasma catalysis (PPC) systems. The results indicate that IPC systems have better higher performance than that of NTP-alone and PPC. Especially, high C₇H₈ conversion (100%) and mineralization efficiency (96.8%) can be achieved with the applied voltage of 18 kV and temperature of 120 °C when La₂CoMnO₆ is integrated with NTP to form IPC system. Also, it owns the highest energy efficiency (0.14 g/kWh). It is concluded that IPC performance for C₇H₈ removal is closely related with the properties of catalyst surface. In addition, the kinetics of IPC systems are investigated by a simplified model, and the result indicates that IPC with La₂CoMnO₆ as catalyst has a higher overall energy constant. This study reveals that double-type La₂CoMnO₆ is of higher activity than single perovskites for C₇H₈ removal, and demonstrates that double-type La₂CoMnO₆ is of high potential to form plasma catalysis system for VOCs removal.

Mining activity constitutes a potential source of heavy metal pollution in the environment. Long-term exposure to heavy metals (e.g., cadmium) has adverse health effects. Rodents frequently serve as bioindicators to monitor the levels of heavy metals in the environment. In the present study, concentrations of 10 heavy metals (Cd, Co, Cr, Cu, Fe, Mo, Ni, Pb, Sb, and Zn) in kidney, liver, and muscle tissue of the Persian jird (Meriones persicus) were evaluated. This is the first study to examine the histopathological changes in Persian jird tissues caused by the bioaccumulation heavy metals. The samples were taken at location that surrounded by Sangan Iron Ore Mine (SIOM) mining activities, in northeastern Iran. The results show that the highest concentrations for the metals were observed in kidney and liver, whereas lowest concentrations were found in muscle of Persian jirds. The concentration of Pb was below the limit of detection. Sex and age were two factors that could explain the different levels of heavy metal bioaccumulation, which affects the concentration of some metals. Adults had significantly higher Cu and Cd levels compared to juveniles. Males bioaccumulated more Zn in their kidneys than females, whereas females bioaccumulated more Fe in their livers. As expected, heavy metals affected various organs of the studied specimens. Hyperemia, hemorrhage, necrosis, and degenerative damage to the epithelial cells of the tubules, the presence of hyaline casts, and in one case, mononuclear leukocyte infiltration, were observed in samples of renal tissue. Hemorrhage and hepatocyte vacuolization were the most common histopathological changes found in samples of hepatic tissue. These effects and the concentrations of heavy metals in the studied specimens indicate the need for monitoring and frequent sampling to evaluate long-term persistent pollutants.

Camorim is a small, eutrophic reservoir in Rio de Janeiro, Brazil, with a phytoplankton community dominated most of the year by the filamentous diatom Aulacoseira spp. and the toxic cyanobacterium Cylindrospermopsis raciborskii. As filamentous species can be a poor food for grazers, we hypothesize that phytoplankton from this reservoir would constrain cladoceran fitness due to nutritional limitation and/or toxicity when animals fed mixtures of cultured green algae and natural seston. Clones of different cladoceran species were exposed either to seston from Camorim reservoir sampled in different seasons or to a C. raciborskii strain (CYLCAM-2) isolated from the reservoir. In short-term assays, cladocerans were exposed to either 100% seston or mixtures of 50% seston added to green algae (200 μg C L⁻¹), and their survivorship and somatic growth were measured for 4 days. In life table assays, neonates were exposed to the same seston treatments over 14 days and age at first reproduction, survivorship, fecundity, total offspring, and the intrinsic rate of natural increase (r) were assessed. In general, seston negatively affected cladoceran survivorship and fitness (r), but this response was seasonally and species specific. Stronger effects of CYLCAM-2 than those caused by seston on survivorship, somatic growth, and r were found for all cladoceran species, especially when the proportion of CYLCAM-2 was higher than 50% in relation to green algae in a fixed total food concentration. Our results suggest that both nutritional (C/P and morphology) and toxicity factors can act to impair cladoceran fitness and help explain the absence of cladocerans in Camorim reservoir.

Advanced oxidation processes (AOPs) using various energy sources and oxidants to produce reactive oxygen species are widely used for the destruction of recalcitrant water contaminants. The current study is about the degradation of two emerging pollutants—salicylic acid (SA) and methyl paraben (MP)—by high-frequency ultrasonication followed by identification of the oxidation byproducts and modeling of the reaction mechanisms using the density functional theory (DFT). The study also encompasses prediction of the aquatic toxicity and potential risk of the identified byproducts to some aquatic organisms bussing the ECOSAR (Ecological Structure Activity Relationships) protocol. It was found that the degradation of both compounds was governed by •OH attack and the pathways consisted of a cascade of reactions. The rate determining steps were decarboxylation (~ 60 kcal mol⁻¹) and bond breakage reactions (~ 80 kcal mol⁻¹), which were triggered by the stability of the reaction byproducts and overcome by the applied reaction conditions. Estimated values of the acute toxicities showed that only few of the byproducts were harmful to aquatic organisms, implying the environmental friendliness of the experimental method.

Effect of arsenate [As(V)] on biomass, photosynthetic rate, stomatal conductance, transpiration, oxidative stress, accumulation of As, Fe, Zn, Cu and Mn and expression of NRAMP genes was investigated in As(V) tolerant and sensitive genotypes of bioenergy crop Ricinus communis. As(V) treatments (100 and 200 μM) led to significant reduction in root and leaf biomass, photosynthetic rate, stomatal conductance and transpiration in GCH 2 and GCH 4 genotypes but no significant change or increase was observed in WM and DCH 177 genotypes. No significant difference was observed in hydrogen peroxide content and lipid peroxidation in As(V)-treated tolerant genotypes compared to control, whereas these parameters enhanced significantly in As(V)-treated sensitive genotypes. GCH 2 accumulated around two times As in leaves and showed significant reduction in concentration of Zn and Mn in the leaves and roots due to 200 μM As(V) treatment compared to WM. NRAMP genes are critical for uptake and distribution of essential divalent metal cations, photosynthesis and controlled production of reactive oxygen species in plants. RcNRAMP2, RcNRAMP3 and RcNRAMP5 genes showed differential expression in response to 200 μM As(V) in GCH 2 and WM suggesting that NRAMP genes are associated with differential responses of WM and GCH 2 genotypes to As(V) stress.