The chiral herbicide imazethapyr (IM) is frequently used to control weeds in soybean fields in northeast China. However, the impact of IM enantiomers on microbial communities in soil is still unknown. Genetic markers (16S rRNA V3-V4 regions) were used to characterize and evaluate the variation of the bacterial communities potentially effected by IM enantiomers. Globally, the bacterial community structure based on the OTU profiles in (−)-R-IM-treated soils was significantly different from those in (+)-S-IM-treated soils, and the differences were enlarged with the treatment dose increasing. Interestingly, the Rhizobiaceae family and several other beneficial bacteria, including Bradyrhizobium, Methylobacterium, and Paenibacillus, were strongly enriched in (−)-R-IM treatment compared to (+)-S-IM treatment. In contrast, the pathogenic bacteria, including Erwinia, Pseudomonas, Burkholderia, Streptomyces, and Agrobacterium, were suppressed in the presence of (−)-R-IM compared to (+)-S-IM. Furthermore, we also observed that the bacterial community structure in (−)-R-IM-treated soils was more quickly restored to its original state compared with those in (+)-S-IM-treated soils. These findings unveil a new role of chiral herbicide in the development of soil microbial ecology and provide theoretical support for the application of low-persistence, high-efficiency, and eco-friendly optical rotatory (−)-R-IM.

Swine production chain generates residues with potential application in environmental processes. This study aimed at the use of swine hair as a potential biofilter for hexavalent chromium (Cr(VI)) removal from wastewater of tannery industry. The hair was pretreated using H₂O₂ in alkaline medium, and statistical analysis was carried out to evaluate the hair degradation, as well the Cr(VI) removal by the potential pretreated biofilter. The results showed 99% of Cr(VI) removal in 105 min of treatment in large pH range (1–10). Treated and untreated effluents were submitted to cytotoxicity study using vegetable and animal cells, demonstrating a significant reduction on toxicity to both cells. Therefore, swine hair demonstrated to be a promising residue for heavy metal removal on the perspective of an environmentally friendly technique.

The anaerobic digestion of wastewater from the cleaning of tank cars transporting food and fodder was investigated in both bench and pilot scales with a single-stage, mesophilic (39 °C), completely mixed process. The promising results lead to the planning and building of a 1200-m³ full-scale biogas plant at TS-Clean cleaning station in Fahrbinde, Germany. Due to softened water used in the cleaning of the car tanks, the alkalinity in the digester decreased as predicted by the physicochemical model developed for this treatment process. The model showed that 2.4 kg NaHCO₃/m³ of wastewater has to be added in order to control digester pH at 7.2 and to maintain the digester alkalinity at 3.1 g CaCO₃/L. In a laboratory study, the decrease of alkalinity caused a volatile organic acids accumulation and pH drop below the optimal range. In this case, if chemical buffering was not added into the digester, the digester deteriorated. In a 3-year investigation, we confirmed that the strongly polluted WW from the cleaning of tank cars transporting food and fodder is suitable for an anaerobic treatment if the organic loading rate is controlled below 4 kg COD/m³/day, digester alkalinity is adjusted by NaHCO₃, and micronutrients are added despite constant considerable variations in strength and composition of the wastewater. A biogas yield of 35–45 m³ CH₄/m³ of wastewater and a COD elimination of 80–90% were achieved in bench- and pilot-scale experiments and are achieved in the full-scale biogas plant. The full-scale biogas plant is working stable with a biogas yield of 68 m³ biogas/m³ of wastewater.

The microalgae-based CO₂ sequestration is considered to be an effective technique with great potential to cope with carbon emission. However, most researches are only focused on microalgae; the effects of physicochemical factors, which are carbon concentration, medium pH, and bubbling depth, on absorption and utilization of supplied CO₂ in culture is less known. In order to understand and improve CO₂ absorption in microalgae culture, the effects of these three factors were studied with different levels and combinations. Results revealed that when medium carbon concentration increased from 4.76 to 95.24 mmol/L, CO₂ absorption ratio increased by about 12%, 10%, 12%, and 11% at medium depths of 10, 20, 40, and 80 cm, with the initial pH 10.6 to 9.7 by bubbling CO₂, respectively. As bubbling depth increased from 10 to 80 cm, CO₂ absorption ratio increased by about 25%, 22%, and 25% at carbon concentrations of 4.76, 9.52, and 95.24 mmol/L, with the initial pH 10.6 to 9.7 by bubbling CO₂, respectively. In range of 10.6–7.0, pH had no significant effect on CO₂ absorption ratio (P > 0.05) when carbon concentration is below 9.52 mmol/L, while above 9.52 mmol/L, pH had significant effect on CO₂ absorption ratio (P < 0.05). It was found for the first time that the effect of pH on the CO₂ absorption ratio was affected by carbon concentration. In addition, equilibrium pH, at which the CO₂ partial pressure in the medium equals to that in the air, of medium with different carbon concentrations was also determined. Overall, in microalgae culture for CO₂ sequestration, increasing CO₂ bubbling depth and keeping higher carbon concentration and higher pH can improve CO₂ absorption ratio, which will optimize the biofixation of CO₂ by microalgae furthermore.

The development of industrial civilization has greatly enriched the material and spiritual life of human beings, but it is accompanied by the intensification of the consumption of earth resources and environmental pollution. The smog that has emerged in various parts of China in recent years is a typical problem, which not only endangers human health but also affects normal human work and life. It is difficult to control smog in a short time productively, so people need to understand the rule of smog formation gradually, and effectively predict the PM2.5 index to help people continuously analyze relevant mechanisms and timely protect-related hazards. This paper proposes a hybrid model that uses the Complementary Ensemble Empirical Modal Decomposition algorithm to mine the information in the original PM2.5 sequence and then predicts the pertinent random forests. The trend of PM2.5 concentration during the decomposition process is effectively reflected, and the decomposition sequence is modeled by the high tolerance of the random forest to the noise data and the good fitting ability. In the modeling process, the parameters are optimized according to the evaluation function of the model on the verification set, and eventually, the prediction sequences are superimposed to obtain the final predicted PM2.5 concentration value. The validity of the model is verified by the data of several Chinese cities with different geographical features in the past 5 years. The results show that the recommendation model is higher than other comparison models in terms of model stability and prediction accuracy.

Reservoirs have been given priority as an important resource for fisheries enhancement in inland open waters. This paper described the spatial and temporal pattern of fish diversity using GIS platform, assemblage structure, and studied the influence of environmental parameters in these variables in a large tropical reservoir, Chandil, located in the eastern India using multiple approaches. Altogether, 42 fish species belonging to 30 genera were recorded from the reservoir, including two exotic species: pangas, Pangasianodon hypophthalmus, and Nile tilapia, Oreochromis niloticus. The diversity indices indicated lowest fish diversity in the lacustrine zone, but without distinct seasonal variation. The taxonomic distinctness was lower in the lacustrine zone as compared to other zones, and the summer season exhibited higher taxonomic distinctness, though the number of species was lowest. Most of the physicochemical parameters recorded are within the favorable range for fisheries enhancement. Among the environmental parameters, pH and nitrate significantly influenced the fish abundance. The study recommends suitable measures and interventions for conservation of the native fish diversity and sustainable fisheries development: closed season, protected/conservation area, introduction of fish aggregating device (FAD), and regulated fish culture in enclosures.

Vegetable oils are found suitable alternate of diesel fuel as per the results of short-run studies. Long-run studies with vegetable oil as a fuel pointed out the problems related to wear and maintenance of the engine. A single cylinder, variable compression ratio diesel engine was tested for 512 h (32 cycles of 16 h per day) to investigate longevity implications of fueling Thumba vegetable oil. Results of the study revealed that a very little damage was observed over the running surface of the cylinder liner, piston rings, valves, and valve seats. Wear in the piston outer diameter was observed to be 13 to 30 microns. Cylinder wear was about 80 microns. The closed gap in the oil piston ring increased up to 200 microns. Heavy carbon deposition was found on different internal parts of the engine, which indicates poor combustion of fuel. Amount of copper (66 mg/kg) and silicon (112 mg/kg) dissolved in the lubricating oil was found more than permissible limits (Cu 50 mg/kg, Si 25 mg/kg), after 450-h engine test run. But all the dissolve materials remain in allowable limits when the durability test conducted with diesel. Smoke, CO, HC, and NOX emissions were found to increase initially then decrease in the further engine running hours. But these emissions were found inferior to the engine emissions fueled with diesel in all the running hours. CO2 emissions were found superior throughout the test with the preheated T20 Thumba oil blend than diesel. The maximum reduction in the viscosity of the lubricating oil, during endurance testing, was found 60 centipoises but it was found 25 centipoises when the test conducted with diesel.

A novel multi-functional and environmental friendly tannic acid polymer (Fe³⁺-TA-HCHO) with Fe³⁺ and formaldehyde as double crosslinking agents together with cysteine as heteroatom source was prepared by a one-pot hydrothermal method. Characterization with transmission electron microscope (TEM), scanning electron microscopy (SEM), Fourier transform infrared spectrometer (FT-IR), and elemental analysis demonstrated that the Fe³⁺-TA-HCHO possessed uniform structure and particle size as well as plentiful functional groups. The resulted Fe³⁺-TA-HCHO material as a adsorbent to remove methylene blue, sunset yellow, Pb²⁺, Hg²⁺, and AsO₃³⁻ from water. The results suggested that Fe³⁺-TA-HCHO polymer (pHpzc is 2.33) showed different adsorption properties for anionic pollutants (sunset yellow and AsO₃³⁻) and cationic pollutants (methylene blue, Pb²⁺, and Hg²⁺). The material exhibited remarkable selectivity for adsorption and separation of pollutants. The maximum adsorption capacities calculated from Langmuir model for methylene blue, Pb²⁺, and Hg²⁺ were 154.32, 819.67, and 699.30 mg g⁻¹, respectively. This is the first time that tannic acid polymer is synthesized by double crosslinking method, which not only developed a promising adsorbent for selective removal of cation pollutants, but also opened up a new avenue for synthesis and application of tannic acid polymer.

The presented study summarizes laboratory tests results to define the inhibition effect of selected pharmaceuticals on biogas production under anaerobic digestion conditions. Two sets of inhibition tests were realized: (i) with real anaerobic sludge (from municipal wastewater treatment plant (WWTP) where sludge is present and includes a wide spectrum of pharmaceuticals over a long period) and (ii) with laboratory sludge (sludge without pharmaceuticals). Methanogenic tests lasting 20 days were performed with three analgesics (diclofenac, ibuprofen, and tramadol), two antibiotics (amoxicillin and ciprofloxacin), β-blocker (atenolol), three psychoactive compounds (carbamazepine, caffeine, and cotinine), and a mixture of these compounds. All tests were performed with two concentrations of pharmaceuticals (10 μg/L and 500 μg/L). Results of the methanogenic tests showed the different behaviors of the investigated sludges in the presence of individual pharmaceuticals. Stimulation of anaerobic digestion was mostly detected for laboratory (unadapted) sludge (e.g., the addition of ibuprofen at a concentration of 500 μg/L increased biogas production by 61%). On the other hand, pharmaceuticals inhibited biogas production for real sludge (e.g., the addition of ciprofloxacin 500 μg/L decreased biogas production by 52%).

This study characterized the extruded polymeric substances (EPS) secreted from Synechococcus mundulus cultures under the effect of 2-KGy gamma irradiation dose. The EPS demonstrated seven monosaccharides, two uronic acids and several chemical functional groups: O–H, N–H, =C–H, C=C, C=O, COO–, O–SO₃, C–O–C and a newly formed peak at 1593 cm⁻¹ (secondary imide). The roughness of EPS was 96.71 nm and only 28.4% total loss in weight was observed at 800 °C with a high degree of crystallinity quantified as CIDSC (0.722) and CIXRD (0.718). Preliminary comparative analyses of EPS exhibited high protein content in the radiologically modified (R-EPS) than control (C-EPS). Modified EPS were characterized with a high biosorption efficiency, which could be attributed to its high content of uronic acids, protein and sulphates as well as various saccharide monomers. Data revealed that 0.0213 mg L⁻¹ h⁻¹ is the maximum biosorption rate (SBRₘₐₓ) of Cr(VI) for R-EPS, whereas 0.0204 mg L⁻¹ h⁻¹ SBRₘₐₓ for the C-EPS respectively.