A pesticide runoff event was simulated on two 10 m x 50 m constructed wetlands (one non-vegetated, one vegetated) to evaluate the fate of methyl parathion (MeP) (Penncap-M). Water, sediment, and plant samples were collected at five sites downstream of the inflow for 120 d. Semi-permeable membrane devices (SPMDs) were deployed at each wetland outflow to determine exiting pesticide load. MeP was detected in water at all locations of the non-vegetated wetland (50 m), 30 min post-exposure. MeP was detected 20 m from the vegetated wetland inflow 30 min post-exposure, while after 10d it was detected only at 10 m. MeP was measured only in SPMDs deployed in non-vegetated wetland cells, suggesting detectable levels were not present near the vegetated wetland outflow. Furthermore, mass balance calculations indicated vegetated wetlands were more effective in reducing aqueous loadings of MeP introduced into the wetland systems. This demonstrates the importance of vegetation as sorption sites for pesticides in constructed wetlands.

Interest in selenium pollution and remediation technology has escalated during the past two decades. Although not known to be essential for plants, selenium is essential but could be toxic for humans and animals, depending on its concentration. A major selenium controversy in the 1980's emerged in California when the general public and scientific community became aware of selenium's potential as an environmental contaminant. After extensive research on several strategies to reduce loads of mobile Se for entering the agricultural ecosystem a plant-based technology, defined as 'phytoremediation' received increasing recognition, as a low-cost environmentally friendly approach for managing soluble Se in the soil and water environment. Successful long-term field remediation of Se by plants is, however, dependent upon acceptance and widespread use by growers, who are also concerned about potential commercial value from using the plant-based technology. Obtaining products with economic value from plants used in the cleanup of soil would certainly be an additional benefit to phytoremediation, which could help sustain its long-term use.

The removal of phenanthrene, anthracene and benzo(a)pyrene added at three different concentrations was investigated with or without earthworms (Eisenia fetida) within 11 weeks. Average anthracene removal by the autochthonous micro-organisms was 23%, 77% for phenanthrene and 13% for benzo(a)pyrene, while it was 51% for anthracene, 47% for benzo(a)pyrene and 100% for phenanthrene in soil with earthworms. At 50 and 100 mg phenanthrene kg−1E. fetida survival was 91% and 83%, but at 150 mg kg−1 all died within 15 days. Survival of E. fetida in soil amended with anthracene ≤1000 mg kg−1 and benzo(a)pyrene ≤150 mg kg−1 was higher than 80% and without weight loss compared to the untreated soil. Only small amounts of PAHs were detected in the earthworms. It was concluded that E. fetida has the potential to remove large amounts of PAHs from soil, but more work is necessary to elucidate the mechanisms involved.

Canopy leaf area index (LAI) is an important structural parameter of the vegetation controlling pollutant uptake by terrestrial ecosystems. This paper presents a computationally efficient algorithm for retrieval of vegetation LAI and canopy clumping factor from satellite data using observed Simple Ratios (SR) of near-infrared to red reflectance. The method employs numerical inversion of a physics-based analytical canopy radiative transfer model that simulates the bi-directional reflectance distribution function (BRDF). The algorithm is independent of ecosystem type. The method is applied to 1-km resolution AVHRR satellite images to retrieve a geo-referenced data set of monthly LAI values for the conterminous USA. Satellite-based LAI estimates are compared against independent ground LAI measurements over a range of ecosystem types. Verification results suggest that the new algorithm represents a viable approach to LAI retrieval at continental scale, and can facilitate spatially explicit studies of regional pollutant deposition and trace gas exchange. The paper presents a physics-based algorithm for retrieval of vegetation LAI and canopy-clumping factor from satellite data to assist research of pollutant deposition and trace-gas exchange. The method is employed to derive a monthly LAI dataset for the conterminous USA and verified at a continental scale.

An integrative passive sampler consisting of a C18 Empore® disk receiving phase saturated with n-octanol and fitted with low-density polyethylene diffusion membrane was calibrated for the measurement of time-weighted average concentrations of hydrophobic micropollutants, including polyaromatic hydrocarbons and organochlorine pesticides, in water. The effect of temperature and water turbulence on kinetic and thermodynamic parameters characterising the exchange of analytes between the sampler and water was studied in a flow-through system under controlled conditions. It was found that the absorption of test analytes from water to the sampler is related to their desorption to water. This allows for the in situ calibration of the uptake of pollutants using offload kinetics of performance reference compounds. The sampling kinetics are dependent on temperature, and for most of the tested analytes also on the flow velocity. Sampler–water partition coefficients did not significantly change with temperature.

The mussel, Brachidontes variabilis, and the limpet, Patella sp., were used as indicators to monitor cadmium, lead and mercury concentrations along the Lebanese coast. Studies were carried out in order to define the best strategy for assessing and minimizing the effects of size and physiological condition on the metal contents of the molluscs, and corrective models were constructed. Metal concentrations in surface water were measured to estimate bioconcentration factors (BCFs). The BCFs varied from 8.3 x 10(3) to 3.4 x 10(4), from 7.5 x 10(3) to 8.0 X 10(3) and from 3.0 x 10(4) to 3.2 x 10(4), for Cd, Pb and Hg, respectively. For limpets, BCFs varied from 1.7 x 10(4) to 7.4 x 10(4) for Cd, from 2.5 x 10(3) to 6 x 103 for Pb and remained fairly constant at around 104 for Hg. The highest BCFs were associated with lowest contamination levels. The results of the geographical survey exhibited a similar large-scale spatial pattern for the two species and followed the metal concentration distributions measured in the waters.

Larval stages of bivalve molluscs are highly sensitive to pollutants. Oysters from a hatchery from Normandy (English Channel) were induced to spawn, and fertilized eggs were exposed to copper or cadmium for 24 h. Metal accumulation (from 0.125 to 5 mu g Cu L-1 and from 25 to 200 mu g Cd L-1) and MT concentrations were measured in larvae. Compared to controls, larvae accumulated copper and cadmium with an increase in MT concentrations particularly with cadmium (i.e. 130.96 ng Cu (mg protein)(-1) and 12.69 mu g MT (mg protein)(-1) at 1 mu g Cu L-1 versus 23.19 ng Cu (mg protein)(-1) and 8.92 mu g MT (mg protein)(-1) in control larvae; 334.3 ng Cd (mg protein)(-1) and 11.70 mu g MT (mg protein)(-1) at 200 mu g Cd L-1 versus 0.87 ng Cd (mg protein)(-1) and 4.60 mu g MT (mg protein)(-1) in control larvae). Larvae were also obtained from oysters of a clean area (Arcachon Bay) and a polluted zone (Bidassoa estuary) and exposed to copper in the laboratory, their MT concentration was measured as well as biomarkers of oxidative stress. Biomarker responses and sensitivity to copper for the larvae from Arcachon oysters were higher than for those from Bidassoa.

This study aimed at comparing toxic element (Hg, Cd) bioaccumulation in relation to age for bottlenose (Tursiops truncatus) and striped dolphins (Stenella coeruleoalba) from Mediterranean and Atlantic waters. Metal concentrations were also measured in selected prey to infer metal exposure through the diet. As expected, Mediterranean prey exhibited the highest Hg levels, probably as a consequence of the Hg enrichment of the Mediterranean Sea. Comparing the predators from each area and taking age into account, Mediterranean bottlenose dolphins displayed higher Hg levels than Atlantic dolphins (p = 0.032), whereas Mediterranean striped dolphins did not (p = 0.691). The consumption of Myctophid fish, which showed the highest Hg levels (105 +/- 80 ng g(-1) w.wt.) among Atlantic prey, may explain the high Hg levels in the liver of the Atlantic striped dolphins and suggested a preferential offshore feeding behaviour in this area. Concerning Cd, no clear differences were found between geographical areas. (c) 2006 Elsevier Ltd. All rights reserved.

To improve total nitrogen removal, a full-scale experimental study was conducted on a hybrid constructed wetlands plant designed for 100 p.e.. The plant composed of a 1st stage of vertical filters (fed with raw wastewater) followed by a 2nd stage of horizontal filters was monitored over one year measuring hydraulic conditions, physico-chemical conditions, gas emission, oxygen of the gas phase and regular treatment performances by 24 h composite samples. Different vertical filter configurations (media depth, intermediate and passive aeration system) were tested as well as two horizontal filter designs. The N removal is discussed on efficiency of each stage in relation to the season and the load applied. This study leads to draw the limit of the plant configuration and gives some design avenues of hybrid systems to reach high and regular level of nitrogen removal with acceptable surface area per person.

[Departement_IRSTEA]MA [TR1_IRSTEA]TED / EPURE | The constraints on sanitation in Mayotte, a small French island with a tropical climate in the straight of Mozambique are strong: The interior landscape is rugged with seep slopes, a dense and very rapidly increasing population lives mostly along the coastline, where space for human activity becomes scarce. Yet, the generalization of access to tap water on a household or community level immediately created a need for sanitation programs. Because of the size of the plots and the nature of the subsoil however, onsite sanitation is often impossible and centralized sewerage systems not affordable in the near future. The most appropriate solutions seem to be decentralized low maintenance treatment systems of a capacity of a few hundred person-equivalent, which can be build using mostly local resources, do not require high technical expertise and have low running costs. In order to meet these challenges, SIEAM, the local syndicate which will operate all sewage treatment equipment on the island, asked for expert back-up from Cemagref and asked SINT to design two pilot plants using constructed wetlands. The first constructed wetland plant consists of an Imhoff tank followed by a sub-surface horizontal flow filter with local filter material; divided in three compartments, each planted with different local plants. The second plant is a local adaptation of the type of vertical flow systems working with raw sewage, like the one SINT designs and constructs in Europe. Because sand for a second stage vertical filter is not found on the island, a design with a single stage filter with recirculation was chosen. Both pilot plants are working very well, but in order to optimize dimensioning and to reduce the required surface area, they will have to be tested under higher loadings. | Les contraintes de l'assainissement à Mayotte, une petite île dont le climat est tropical dans le canal du Mozambique, sont fortes: la topographie est très pentue, une population dense et croissant rapidement vit le long de la côte où les espaces pour les activités humaines sont réduits.