After a general presentation of the polluted sites set of problems, several case studies involving the use of geosynthetic materials for their remediation (including industrial former plants) have been analysed and are briefly presented. This allows a first classification of the panel of geosynthetic materials used according to the various remediation techniques that have been applied. We also tried to analyse the conceptual principles that have been followed for these remediation works and we propose a critical analysis and some recommendations. | Après une présentation de la problématique générale des sites et sols pollués, plusieurs exemples d'utilisation des matériaux géosynthétiques dans les techniques de dépollution des sols et des sites industriels sont présentés brièvement. Cette analyse permet un premier classement des domaines d'utilisation et des familles de produits géosynthétiques correspondants. Nous nous sommes attachés également à rechercher les principes conceptuels qui ont été suivis dans le cadre des chantiers étudiés, afin d'en proposer une analyse critique et de formuler des recommandations.

Since the confinement technics development, the trend used to be to search complete impermeable solutions to stop completely the transfers from or toward the polluted source. On the contrary, it can be interesting to take advantage from natural attenuation mechanisms, by using geosynthetics for example, to regulate the transfer ratio in order to obtain environmental compatible conditions. The paper presents a case study of gaseous and liquid transfer management in Bora Bora, French Polynesia. | Depuis l'avènement des solutions de confinement des sources polluantes, la tendance des concepteurs a souvent été de faire le choix d'une imperméabilité poussée dont l'objectif visait l'arrêt des transferts solides, liquides et gazeux vers l'extérieur. Ce concept peut poser le problème de la durabilité des solutions et de transfert du problème aux générations futures. Le contre-pied de cette tendance, obtenu en réglant les niveaux de transfert à des valeurs éco-compatibles, via des géosynthétiques sur mesure par exemple, permet de mettre à profit certains mécanismes d'atténuation pour viser une atténuation maîtrisée de la source de pollution tout en maintenant un niveau de risque acceptable pour l'homme et les milieux. La communication présente une étude de cas de maîtrise des transferts liquides et gazeux sur l'île de Bora-Bora.

This paper discusses safety culture in the petrochemical sector and the causes and consequences of safety culture. A sample of 520 responses selected by simple random sampling completed questionnaires for this survey, the return rate was 86.75%. The research instrument comprises four sections: basic information, the safety leadership scale (SLS), the safety climate scale (SCS), and the safety performance scale (SPS). SPSS 12.0, a statistical software package, was used for item analysis, validity analysis, and reliability analysis. Exploratory factor analysis indicated that (1) SLS abstracted three factors such as safety caring, safety controlling, and safety coaching; (2) SCS comprised three factors such as emergency response, safety commitment, and risk perception; and (3) SPS was composed of accident investigation, safety training, safety inspections, and safety motivation. We conclude that the SLS, SCS, and SPS developed in this paper have good construct validity and internal consistency and can serve as the basis for future research.

Rainwater has been used as drinking water in Thailand for centuries especially in the rural parts and is accepted as an important water resource. From past to present, the quality of rainwater has changed with the landuse of the landscape, and its water quality is influenced by a diverse range of conditions such as the management of pollutant sources, the catchment condition, wind and meteorological conditions, and the location of rainwater collection points. In this study, the quality of rainwater collected off roofs at several locations was examined. Granular activated carbon (GAC) filtration was used as a pretreatment to microfiltration (MF) to remove the dissolved organic matter (DOC). After an initial adsorption period, the biofilm that formed on the GAC (biofilter) was found to remove DOC by up to 40%, 35%, and 15% for bed filter depths of 15, 10, and 5 cm, respectively. Biofilters also removed nitrate and phosphate by more than 80% and 35%. The hollow fiber membrane microfiltration with pore size of 0.1 μm was used to treat the effluent from biofiltration to remove the microorganisms/pathogens in the rainwater. Although there was no significant additional removal of DOC by MF, the biofilter removed all microorganisms. The use of biofilters as pretreatment to MF/UF could remove a higher amount of DOC, remove microorganisms, increase the membrane treatment efficiency, and reduce membrane fouling.

The use of inks containing organic solvents by the offset printing process implies in the release of volatile organic compounds to the work environment. Many of these compounds such as benzene, toluene, ethylbenzene, and the xylene isomers (well known by the acronym BTEX) are extremely toxic. In this study, the BTEX concentrations were determined in two different printing plants that use distinct types of inks: the conventional and the so-called ecological, which is manufactured based on vegetal oil. Concentration ranges were 43-84, 15-3,480, 2-133, 5-459, and 2-236 μg m⁻³ for benzene, toluene, ethylbenzene, m + p-xylene, and o-xylene, respectively, for the conventional printing plant. At the ecological printing plant, concentration ranges were below limit of detection (<LD)-31, <LD-618, <LD-1,690, <LD-10,500, <LD-3,360 μg m⁻³ for benzene, toluene, ethylbenzene, m + p-xylene, and o-xylene, respectively. BTEX concentrations are lower at the ecological printing environment than in the conventional, where mineral oil-based inks are used. However, the worker who cleans the printing matrices is exposed to high concentrations of ethylbenzene and xylenes, due probably to the cleaning product's composition (containing high amounts of BTEX). Although the BTEX concentrations found in both printing work environments were below the limits considered by the Brazilian Law for Activities and Unhealthy Operations (NR-15), the exposure to such vapors characterizes risk to the workers' health for some of the evaluated samples, mainly the personal ones.

The adsorption of two taste- and odor-causing compounds, namely MIB (2-methyl isoborneol—C₁₁H₂₀O) and geosmin (C₁₂H₂₂O) on activated carbon was investigated in this study. The impact of adsorbent pore size distribution on adsorption of MIB and geosmin was evaluated through single solute and multicomponent adsorption of these compounds on three types of activated carbon fibers (ACFs) and one granular activated carbon (GAC). The ACFs (ACC-15, ACC-20, and ACC-25) with different degrees of activation had narrow pore size distributions and specific critical pore diameters whereas the GAC (F-400) had a wider pore size distribution and lesser microporosity. The effect of the presence of natural organic matter (NOM) on MIB and geosmin adsorption was also studied for both the single solute and binary systems. The Myers equation was used to evaluate the single solute isotherms as it converges to Henry's law at low coverage and also serves as an input for predicting multicomponent adsorption. The single solute adsorption isotherms fit the Myers equation well and pore size distribution significantly influenced adsorption on the ACFs and GAC. The ideal adsorbed solute theory (IAST), which is a well-established thermodynamic model for multicomponent adsorption, was used to predict the binary adsorption of MIB and geosmin. The IAST predicted well the binary adsorption on the ACFs and GAC. Binary adsorption isotherms were also conducted in the presence of oxygen (oxic) and absence of oxygen (anoxic). There were no significant differences in the binary isotherm between the oxic and anoxic conditions, indicating that adsorption was purely through physical adsorption and no oligomerization was taking place. Binary adsorptions for the four adsorbents were also conducted in the presence of humic acid to determine the effect of NOM and to compare with IAST predictions. The presence of NOM interestingly resulted in deviation from IAST behavior in case of two adsorbents, ACC-15 and F-400.

In Tabasco the petroleum industry pollutes soil recurrently by oil spills. We analysed Pb, V, Ni and Cr concentrations in water samples, and total metal contents and metal fractions in soil samples of contaminated and non-contaminated soils and in sediments. Besides, we determined Eh, pH, DOC and major ions in water and Eh, pH, Corg in soils and sediments. Sediments contained considerably larger heavy metal (HM) concentrations than soils. Local background concentrations of V, Ni and Cr in soils are larger than global means and oil spillages have not added these metals in quantities that exceed the natural variation. Spillage of formation water increases Pb concentrations in soils, particularly in mobile fractions. The contribution of the oil industry to HM loads is diluted by large fluvial water and sediment discharges and difficult to assess by comparison of total metal contents. Therefore, easily mobile metal fractions are much better indicators.

Soil samples from agricultural and adjacent forest soils in Northwest Ohio were collected and analyzed for As, Cr, Cu, Ni, Pb, and Zn. pH, Eh, electrical conductivity, and moisture content were also measured. Selected samples were also evaluated for grain size and X-rayed to identify clay minerals. In this region, soils contain a large proportion of fines (~32% clay and ~37% silt) with illite, dickite, and chlorite as the main clay minerals. Surface soils in the arable land are slightly acidic (pH ~5.6) while forest soils are near-neutral to slightly basic. All soils become more basic with depth. Soil Eh and electrical conductivity range from 300 to 450 mV and 100 to 375 μS, respectively. In the soil profiles, between 0 and 50 cm depth, As increases from 4.6 to 11 mg/kg, Cr increases from19 to 23 mg/kg and Ni increases 21 to 29 mg/kg. In contrast, Cu decreases from 23 to 17 mg/kg and Pb decreases from17 to 10 mg/kg. Surface enrichment of Cu and Pb can be the result of aerosol deposition, while the downward increase in As, Cr and Ni is related to pedogenic variation. The average concentration of Zn in the samples is 64 mg/kg and does not change with land-use or depth. With the exception of As, the concentration of metals in the agricultural soil is not significantly different from the concentration in forest soil. The concentration of As in the near-surface arable soil (5.6 mg/kg) is significantly different from the concentration of As in the near-surface forest soil (4.3 mg/kg). In both cases, deeper soils have similar As contents. The relative enrichment of As in the surface arable soil could indicate input from herbicides or pesticides. The upward increase in electrical conductivity is interpreted to show that the exchangeable fraction of each metal is higher in the surface soils. However, the near neutral pH and organic, clay-rich soils may limit the mobility. The concentration of these heavy metals and As in the soils are much lower than the limits set by the United States Environmental Protection Agency.

Laboratory culture experiments were conducted with common reed (Phragmites australis) to elucidate the role of root exudates on CH₄ production in wetland soils as well as the importance of different plant organs as routes of CH₄ to the atmosphere. In the 50 d experiment period, root exudates ranged from 0.03 to 1.53 μmolg⁻¹d⁻¹, which increased with reed growth. CH₄ production rate of soil was stimulated as root exudates collected was added. CH₄ transport capacity rate also increased with plant growth and influenced by light intensity. Root tips were the most important part of controlling diffusion of CH₄ into reed shoots, and leave transport accounted for 45.34% of total emissions into the atmosphere.

The use of enhanced-flushing technologies has emerged as a promising technique for the remediation of sites contaminated with immiscible liquids. An important aspect for the effective remediation of these sites depends on the physical heterogeneity of the subsurface and the related distribution of immiscible liquid present within porous media. Recent interest has developed in using mass flux-based approaches to evaluate remediation success and performance for immiscible liquid-contaminated sites. The unique focus of these experiments was to evaluate trichloroethene (TCE) mass flux behavior and mass removal effectiveness for various solubilization agents when the distribution of immiscible liquid is uniform. In order to accurately compare the performance of each enhanced-solubilization agent, the distribution of immiscible liquid must be consistent and uniform. Previous dissolution experiments have typically relied upon injecting immiscible liquid into the porous media which can result in nonuniform immiscible liquid distribution causing nonideal dissolution and mass flux behavior (i.e., immiscible liquid fingering and bypass flow). Homogeneous 20/30 quartz sand was thoroughly mixed with a predetermined amount of immiscible liquid TCE and packed into columns to ensure that uniform distributions of residually saturated TCE (S N = 8-11%) were created. These columns were then flushed with a specific enhanced-solubilization flushing agent to initiate dissolution. Of the four enhanced-solubilization used, the lower solubilization power flushing agents (i.e., cyclodextrins) resulted in more ideal TCE mass flux behavior in which mass flux is maximized and maintained during the majority of the flushing experiment. A strong positive correlation (R ² = 0.92) exists between enhancement factor and mass flux ideality which may suggest that these systems were in fact uniformly distributed with immiscible liquid. In order to appropriately evaluate and compare the effectiveness of specific solubilization agents, it is important to consider mass flux behavior in conjunction with elution behavior and mass removal efficiency.