The study investigates the long-run impact of tourism development on ecological footprint by employing the time-varying coefficient cointegration approach (TVC), in addition to the conventional cointegration techniques in the case of Azerbaijan for the period of 1996–2014. Based on the TVC estimation results, the coefficient of tourism development, which is the income elasticity of environmental degradation, was found to be time invariant. The paper uses energy consumption, trade, urbanization, and institutional quality indicators as control explanatory variables. The estimation results revealed that trade and energy consumption have statistically significant and positive impact on ecological footprint, while the coefficients of the other explanatory variables were found to be insignificant. Both the conventional estimation methods and the TVC concluded that, for the relationship between ecological footprint and tourism development, the EKC hypothesis is not present in Azerbaijan. Policy implications for the resource-rich economies have been discussed.

As a commonly used surfactant, sodium dodecyl sulfate (SDS) usually coexists with inorganic anions in the industrial wastewater. These anions have a significant influence on SDS removal, indirectly threatening the environment. It is important to understand the relationship between the adsorption of SDS and inorganic anions. In this study, calcium-based layered double hydroxide (CaAl-LDH-Cl) as an efficient adsorbent was synthesized for investigating the effect of SO₄²⁻ on SDS removal. The SDS adsorption capacities were enhanced to 3.21 and 4.21 mmol g⁻¹ in the presence of SO₄²⁻ with low/high SDS concentration, respectively. The phenomenon and mechanism were confirmed by X-ray diffraction (XRD), Fourier transform infrared (FTIR) spectroscopy, and Scanning electron microscopy (SEM). Anionic exchange played a dominant role in the adsorption of SDS onto CaAl-LDH-Cl at DS⁻/SO₄²⁻ < 2, while both anion exchange and precipitation occurred when DS⁻/SO₄²⁻ exceeded 2. Moreover, the thermal analysis (TG–DTA) was employed to further reveal the interaction mechanism. The results showed the highest total mass loss and the lowest loss temperature of interlayer water in the sulfate coexist system, confirming the enhancement of SDS adsorption amount in the presence of SO₄²⁻.

Availability of clean water and adequate sanitation facilities are the principal measures for limiting various waterborne diseases. These basic amenities are critical for health and sustainable socio-economic development. This study attempted to assess the status of water and sanitation facilities and practices of the people living in rural areas of Chandigarh including awareness about the waterborne diseases. The community-based cross-sectional study design was adopted having 300 households across 12 villages of city Chandigarh. A standardized interview schedule was used to collect information related to water uses, storage, water treatment options, water conservation practices, personal hygiene, knowledge about waterborne diseases, and government schemes. The interview schedule was administered with the head of the family as a study approach during the door-to-door survey. Households in rural Chandigarh have municipal water supply for drinking as well as other domestic purposes. The mean per capita water usage was 67 ± 13.4 l. Most (68.6%) of the study participants reported that they do not treat water before drinking and store it in plastic bottles or bucket (58%). The survey shows that 97% of the household had functional toilets in their premises, remaining reported lack of finances, and space for construction as major barriers. Regarding personal hygiene, 83% of respondents wash hands with soap and rest used only water or ash. Observations made under the study highlighted the need to create awareness regarding the role of water and sanitation practices on health including knowledge about various government schemes to improve water quality, sanitation, and hygiene practices for better health.

Aside from the ability of plants to remove domestic-industrial wastewater contaminants from various types of water, macrophytes can also serve as an alternative source of energy. The goal of the present study was to test the viability of biogas production using aquatic macrophyte species—Eichhornia crassipes and Pistia stratiotes—contaminated with cadmium (Cd) after the phytoremediation process. The plants were transferred to a nutrient solution contaminated with 0.8 mg L⁻¹of Cd. The experiment was set up in a 2 × 3 factorial scheme with the presence or absence of Cd and three phytoremediation times (20, 40, or 60 days) using P. stratiotes followed by an additional treatment consisting of P. stratiotes + E. crassipes for 20 days. The acute and chronic effects of bioassays with the microcrustacean Daphnia similis were used to evaluate the ability of the macrophytes to remove toxicity by phytoremediation. The viability test of biogas production after phytoremediation was evaluated using micro-biodigesters. According to the results, at least 60 days of phytoremediation are necessary to remove/remediate the Cd present in the contaminated solution. The metal did not influence the macrophytes’ methanogenic activity, showing that these macrophytes can be used for biogas/methane production. The combination of Pistia stratiotes with Eichhornia crassipes is a good alternative to reduce phytoremediation time, but for 20 days of testing, the presence of Eichhornia crassipes reduces the biogas production/CH₄. However, it is believed that if the digestion time is extended, this effect can be minimized. The phytoremediation time indicated that Pistia stratiotes must remain at least 60 days to remove/remediate the Cd present in the contaminated solution.

Biodegradable chelator–assisted phytoextraction is an effective method to enhance remediation efficiency of heavy metals. A greenhouse experiment was conducted to investigate the effects of S,S-ethylenediamine disuccinic acid (EDDS), citric acid (CA), and oxalic acid (OA) application before planting on the biomass and physiological characteristics of hyperaccumulator Sedum alfredii Hance, and its cadmium (Cd), lead (Pb), and zinc (Zn) uptake. The results showed that EDDS and CA slightly inhibited the plant growth, while the 1.0 mmol kg⁻¹ (OA-1) and 2.5 mmol kg⁻¹ OA (OA-2.5) addition produced 55.3% and 35.2% greater shoot biomass compared with the control, which may be related to that OA can produce higher leaf chlorophyll and soluble protein contents, as well as lower concentrations of malondialdehyde. At the same time, the concentrations of Pb and Zn in leaf after OA-2.5 treatment significantly increased by 127% and 28.4%, and the Cd, Pb, and Zn uptake by shoot was obviously enhanced by 21.5%, 117%, and 44.9% for OA-1 addition and by 39.1%, 80.0%, and 58.3% for OA-2.5 addition, respectively, in comparison with the control (P < 0.05). The reductions in available contents of Cd, Pb, and Zn in soil were observed after phytoextraction by Sedum alfredii Hance when OA was treated. These findings imply that OA was suitable for facilitating Sedum alfredii Hance to remove Cd, Pb, and Zn in co-contaminated soil.

The aim of this study was to assess the genotoxic potential of surface waters located in a rural area in the north east of Buenos Aires province (Argentina) using the Allium cepa test. Water samples were collected at four sites located in a drainage channel and two sites on the Burgos stream that receives water from the channel, taking into account the sowing and harvesting months and rainfall periods. Analytical determinations revealed high total concentrations of Cd, Cu, Pb, and Zn (maximum values: 0.030, 0.252, 0.176, and 0.960 mg L⁻¹, respectively), and concentrations of glyphosate and its metabolite aminomethylphosphonic acid (AMPA), with maximum values of 13.6 and 9.75 μg L⁻¹, respectively. Statistically positive correlations were observed between the total metal concentrations and precipitation. No cytotoxicity (mitotic index MI) was observed in A. cepa. However, several water samples showed significant increases in micronucleus (MN) frequencies with respect to the controls. No correlations were observed between MN and the abiotic variables or precipitation. These results showed a state of deterioration in the water quality at the rural area studied in Buenos Aires province, and heavy metal contamination may contribute to the genotoxic activity. A. cepa was shown to be a useful tool for the detection of genotoxicity in water samples from areas with agricultural and livestock activities.

The study was designed to evaluate the impact of differentiated technological innovation efficiencies of industrial enterprises on the local emissions of environmental pollutants in Anhui province, China, during the period of 2012–2016. The econometric models of DEA and SEM-PLS and Malmquist index are used to explore the potential impacts of differentiated technological innovation efficiencies of industrial enterprises on the local emissions of environmental pollutants in Anhui province. After an initial analysis of SEM-PLS model, the models of DEA and Malmquist index are used to evaluate the differentiated degrees and dynamic development levels of local technological innovation efficiencies of industrial enterprises in different regions of Anhui province. With these analyses, the study presents three main results as follows. There is a positive correlation between the technological innovation efficiencies of industrial enterprises and the technological performance levels of environmental disposal. Meanwhile, there is a large gap among the environmental disposing performances of industrial enterprises in different regions of Anhui province. There is also a large gap between the expected and actual technological performances of industrial enterprises’ environmental disposal, according to the results of SEM-PLS analysis. Furthermore, there are several obvious characteristics of geographical distribution in the impact of differentiated technological innovation efficiencies of industrial enterprises on local environmental pollutant emissions observed from the results of the DEA and Malmquist index models. However, it is not consistent with the overall provincial development trend and regional distribution pattern of industrial economics in Anhui province over the period of 2012–2016. Under the rapid development of social economics and modern technological advance, there is a weak impact of differentiated technological innovation efficiency on the technological performance of industrial environmental disposal in different regions of Anhui province. Meanwhile, the environmental disposal capacity of enterprises’ technological innovation become declining too. Finally, some countermeasures and policy suggestions are put forward based on the investigation and comprehensive analyses of the DEA and SEM-PLS and Malmquist index models.

Based on the China’s 1997, 2002, 2007, and 2012 multiregional input–output model, this study calculates China’s provincial CO₂ emissions from investment demand and interprovincial transfer of CO₂ emissions caused by investment demand. The findings of this study are as follows: (1) From 1997 to 2012, the CO₂ emissions from China’s investment demand have seen rapid growth—the CO₂ emissions from investment demand has increased by 4.52 times, and the per capita CO₂ emissions caused by investment demand has increased by 4.13 times. Investment demand is an important driver of growth of China’s CO₂ emissions. The proportion of CO₂ emissions from investment demand in CO₂ emissions from China’s three final demands rose from 37.72% in 1997 to 50.68% in 2012. (2) The CO₂ emissions from investment demand are relatively large in provinces which have large-scale industries. Affected by investment-driven economic growth, CO₂ emissions from investment demand in central, western, and northeastern provinces have increased more rapidly. (3) Large amounts of CO₂ are emitted in the less-developed central and western provinces to meet the investment demand of the developed eastern provinces. As China’s economy enters the “new normal,” economic growth is shifting from investment-driven to consumption-driven, and the growth of CO₂ emissions from investment demand will slow down.

Monitoring on urban water environment and analysis of engineering improvement measures are intricate and time-consuming tasks. In previous studies, the integration of hydrodynamic and water quality models and geographical information system (GIS) usually takes three approaches: loose coupling, tight coupling, and full coupling. However, this paper adopted a special loose coupling approach—case-based reasoning (CBR) to develop an integrated decision support system. This was characterized by invoking the case base stored in the GIS platform as the output of the model. The fused capability of model’s water quality predication and strong spatial data processing analysis of GIS can be realized at the same time by integration. The functionality of the integrated system was illustrated through a case study of Chaohu, a medium-sized city in China, which includes case retrieval, result interpretation, and the visual display in the GIS platform. Results verified the feasibility and operability of the developed method. As a useful tool, the integrated decision support system makes it simpler and more convenient for decision makers to make decisions efficiently and quickly.

In this study, Broussonetia papyrifera leaves collected from land near a restored manganese mine in the Hunan Province of China were converted into biochar under high-temperature anaerobic conditions, regeneration and utilization of agricultural and forest waste, and applied to the prevention of eutrophication. The physicochemical properties of the B. papyrifera biochar were characterized using Micromeritics 3Flex analyzer, scanning electron microscope (SEM), Fourier transform infrared spectrometer (FT-IR), thermogravimetric analyzer (TGA), X-ray photoelectron spectrometer (XPS), zeta potential meter (zeta), and X-ray diffraction (XRD). The effects of pH, ionic strength, coexisting ions, time, initial concentration, and temperature on the decontamination process of phosphate in water were studied. The results indicated that adsorption was enhanced under alkaline conditions. The pseudo-second-order model of adsorption kinetics was applied to illustrate the adsorption processes. The chemical adsorption reaction was the main rate-limiting step in the adsorption process. Isotherm experimental data were best fitted by the Freundlich model at 25 °C and by the Langmuir model at 35 °C. The phosphate combined with B. papyrifera biochar mainly in the forms of exchangeable phosphorus (Ex-P), Al-bound phosphorus (Al-P), and Fe-bound phosphorus (Fe-P). These results indicate that B. papyrifera biochar is a suitable candidate for the treatment of a eutrophic body of water.