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Synthesis of biodiesel from chicken skin waste: an economic and environmental biofuel feedstock in Bangladesh 全文
2021
One of the dominating meat supply industries, the poultry chicken sector, is facing waste management concerns worldwide. Due to high oil content containment, biofuel researchers emphasized poultry waste as abundant, cheap, and high-quality feedstock for biodiesel production. Therefore, in the current study, an experimental investigation of biodiesel production from wasted chicken skin through the transesterification process has been performed. The chicken skin used in this study for biodiesel production can be used as the potential waste source for biodiesel production worldwide. Techno-economic, environmental, and sustainability analyses were also performed. During the synthesis, the reaction was conducted with potassium hydroxide (KOH), and the process yielded 48% biodiesel. The cost of electricity for providing electricity is estimated at US$0.575 per kWh when an auto-sized generator has been fueled by biodiesel. The environmental and substantiality analysis found that biodiesel is more suitable than conventional diesel as an environmentally friendly and sustainable fuel.
显示更多 [+] 显示较少 [-]Dust emission reduction in iron ore concentrate production plant using value engineering method 全文
2021
Dust emission is one of the critical problems of the mining industry. Dust emission can cause respiratory diseases among workers and adjacent residents of the factory and environmental pollution in the region. This study aims to reduce dust emissions of an iron ore concentrate plant in Iran. Applying dust control methods can affect the production process. Therefore, in this study, the value engineering (VE) method has been used, which focuses on improving the processes without affecting the main functions. This method is implemented in three stages. In the pre-study stage of VE, the prerequisites of study, such as determining the management requirements, study scope, evaluation criteria, forming the VE team, and planning, were met. In the study stage, the required information was collected; the studied process functions were identified and ranked; 62 ideas were created based on the functions and then evaluated; the final scenarios for the selected device, hopper, were developed and ranked using the VIKOR method; and finally, confirmation of the results by the management was obtained. In the post-study stage, the results will be implemented. The approach of this study was based on maintaining the functions of the production process and production rate and finding the most effective solution to reduce dust and environmental hazards, the most efficient solution in terms of performance, and the most cost-effective solution in terms of fixed and variable costs. According to the results, dry and wet dust suppression systems are the best options among the scenarios to meet the objectives of this study.
显示更多 [+] 显示较少 [-]Fixation stability of glass matrix co-existent with crystal phases for heavy metals formed by high-temperature vitrification 全文
2021
Vitrification is an effective solidification method for heavy metal-containing wastes. However, most investigations focused on the formation of glass matrix. Seldom report discussed the influence of co-existing crystals on heavy metal stabilizations. In this work, Ca-Al-Si phase was formed in the glass matrix by adjusting the composition of feeding ingredient and melting temperature. As a result, when molar ratio of CaO/(SiO₂+Al₂O₃) was lower than 0.97 and reaction temperature was bigger than 1300 °C, small-size Ca-Al-Si phase (Ca₂Al₂SiO₇ and CaAl₂Si₂O₈) was homogeneously distributed in vitreous matrix. At the same time, Cr, Zn, and Pb leaching concentrations were the lowest, far lower than the leaching standard values. According to theoretical calculations, Zn and Pb replaced Ca atom; Cr replaced Al atom in Ca-Al-Si phase under thermal conditions. These replacements resulted in the fixation and stabilization of heavy metals. When the CaO/(SiO₂+Al₂O₃) molar ratio was bigger than 1.00, neither glass nor Ca-Al-Si was formed. Similarly, when the melting temperature was decreased, Ca-Al-Si phase formed a bigger size. Both these went against the stabilization, resulting in high leaching concentrations of heavy metals. The main of this work will help the development of high-temperature melting for the treatment of hazardous wastes.
显示更多 [+] 显示较少 [-]The potential impact of Octopus cyanea extracts to improve eggplant resistance against Fusarium-wilt disease: in vivo and in vitro studies 全文
2021
The novelty of the present research is conducting a new method in the systemic resistance of plant diseases by using distinct marine extracts. The ability of two octopus extracts to reduce the wilt disease caused by Fusarium oxysporum was observed. The applied methods are soaked roots (SR) and foliar shoots (FS). The antioxidant enzyme activities, percent disease index (PDI), and growth parameters were measured. In vitro antifungal potential of the octopus extracts against F. oxysporum was examined. The obtained result shows that SR extracts reduced PDI. Additionally, all the tested treatments promoted the growth and photosynthetic pigments of the infected plants. SR (in ethanolic extracts) was the most prominent inducer which offered a high advancement in the total soluble protein contents. Also, SR (in methanolic extracts) was the most suitable inducer which provided a very necessary development not only in the total phenol but also in the peroxidase (POD) and polyphenol oxidase (PPO) activities. GC-MS investigation of the octopus extracts exhibited that the compounds which possess antifungal activity were furoscrobiculin B and/or eugenol. They demonstrated a notable antifungal potential against F. oxysporum with a maximum activity of 38.5 and 12.7 mm ZOI after the treatment with the ethanolic and methanolic extract, respectively. FTIR results illustrated the functional group of the compound responsible for the antifungal activity. Additionally, an atomic absorption result reveals that there are traces of metals detected such as Pb, Ag, Cu, Zn, and Mg. The antifungal activity was decreased as the concentrations were reduced. Accordingly, the present extracts may be used as the vital agents in the agricultural field to restrain the plant pathogenic fungi, especially F. oxysporum from a proliferation.
显示更多 [+] 显示较少 [-]Noise pollution and effectiveness of policy interventions for its control in Kathmandu, Nepal 全文
2021
In Nepal, much emphasis has been given to the pollution of air, water, and solid waste both in terms of research and policymaking. Noise is an ignored pollutant, yet a growing public health concern in Kathmandu. This study is aimed at making an assessment of noise pollution in Kathmandu and study the effectiveness of the enforcement of noise standards and No Horn Regulation to control noise pollution. The study was conducted in 23 locations of four different zones (high traffic, low traffic, commercial, and residential) where 12 sites were considered for evaluating the effectiveness of No Horn Regulations. Noise level was studied at five different times of the day using a sound level meter to compute maximum, minimum, equivalent, and average noise level. This study concludes that (i) there is noise pollution problem in Kathmandu, (ii) No Horn Regulation is in place but it has not been strictly followed by the drivers and riders and monitored adequately by concerned authorities, and (iii) the regulation has been effective in reducing the noise level significantly. The average noise level of Kathmandu was recorded as 66.8 dB(A) with the highest noise level in High traffic zones, followed by commercial, low traffic, and residential zones. In 65.2% of the sampled sites, the noise level was beyond the permissible limit of WHO and National Sound Quality Standard of Nepal, 2012. Of the total honking events, 48.1% were against the provision of the No Horn Regulation. After the enforcement of the regulation, noise level was reduced significantly by 2.1 dB(A) in high traffic, low traffic, and residential zones. A comprehensive noise strategy with more emphasis on compliance monitoring and regular noise assessment should be formulated to address environmental noise as a major public health issue.
显示更多 [+] 显示较少 [-]Optical detection of microplastics in water 全文
2021
Unfortunately, the plastic pollution increases at an exponential rate and drastically endangers the marine ecosystem. According to World Health Organization (WHO), microplastics in drinking water have become a concern and may be a risk to human health. One of the major efforts to fight against this problem is developing easy-to-use, low-cost, portable microplastic detection systems. To address this issue, here, we present our prototype device based on an optical system that can help detect the microplastics in water. This system that costs less than $370 is essentially a low-cost Raman spectrometer. It includes a collimated laser (5 mW), a sample holder, a notch filter, a diffraction grating, and a CCD sensor all integrated in a 3D printed case. Our experiments show that our system is capable of detecting microplastics in water having a concentration less than 0.015% w/v. We believe that the designed portable device can find a widespread use all over the world to monitor the microplastic content in an easier and cost-effective manner.
显示更多 [+] 显示较少 [-]Small-scale on-site treatment of fecal matter: comparison of treatments for resource recovery and sanitization [Erratum: December 2021, v.28(45), p.63965-63967] 全文
2021
Small-scale on-site treatment of fecal matter: comparison of treatments for resource recovery and sanitization [Erratum: December 2021, v.28(45), p.63965-63967] 全文
2021
On-site small-scale sanitation is common in rural areas and areas without infrastructure, but the treatment of the collected fecal matter can be inefficient and is seldom directed to resource recovery. The aim of this study was to compare low-technology solutions such as composting and lactic acid fermentation (LAF) followed by vermicomposting in terms of treatment efficiency, potential human and environmental risks, and stabilization of the material for reuse in agriculture. A specific and novel focus of the study was the fate of native pharmaceutical compounds in the fecal matter. Composting, with and without the addition of biochar, was monitored by temperature and CO₂ production and compared with LAF. All treatments were run at three different ambient temperatures (7, 20, and 38°C) and followed by vermicomposting at room temperature. Materials resulting from composting and LAF were analyzed for fecal indicators, physicochemical characteristics, and residues of ten commonly used pharmaceuticals and compared to the initial substrate. Vermicomposting was used as secondary treatment and assessed by enumeration of Escherichia coli, worm density, and physicochemical characteristics. Composting at 38°C induced the highest microbial activity and resulted in better stability of the treated material, higher N content, lower numbers of fecal indicators, and less pharmaceutical compounds as compared to LAF. Even though analysis of pH after LAF suggested incomplete fermentation, E. coli cell numbers were significantly lower in all LAF treatments compared to composting at 7°C, and some of the anionic pharmaceutical compounds were detected in lower concentrations. The addition of approximately 5 vol % biochar to the composting did not yield significant differences in measured parameters. Vermicomposting further stabilized the material, and the treatments previously composted at 7°C and 20°C had the highest worm density. These results suggest that in small-scale decentralized sanitary facilities, the ambient temperatures can significantly influence the treatment and the options for safe reuse of the material.
显示更多 [+] 显示较少 [-]Small-scale on-site treatment of fecal matter: comparison of treatments for resource recovery and sanitization 全文
2021
Kelova, Mariya Evgenieva | Ali, Aasim Musa Mohamed | Eich-Greatorex, Susanne | Dörsch, Peter | Kallenborn, Roland | Jenssen, Petter D.
On-site small-scale sanitation is common in rural areas and areas without infrastructure, but the treatment of the collected fecal matter can be inefficient and is seldom directed to resource recovery. The aim of this study was to compare low-technology solutions such as composting and lactic acid fermentation (LAF) followed by vermicomposting in terms of treatment efficiency, potential human and environmental risks, and stabilization of the material for reuse in agriculture. A specific and novel focus of the study was the fate of native pharmaceutical compounds in the fecal matter. Composting, with and without the addition of biochar, was monitored by temperature and CO2 production and compared with LAF. All treatments were run at three different ambient temperatures (7, 20, and 38°C) and followed by vermicomposting at room temperature. Materials resulting from composting and LAF were analyzed for fecal indicators, physicochemical characteristics, and residues of ten commonly used pharmaceuticals and compared to the initial substrate. Vermicomposting was used as secondary treatment and assessed by enumeration of Escherichia coli, worm density, and physicochemical characteristics. Composting at 38°C induced the highest microbial activity and resulted in better stability of the treated material, higher N content, lower numbers of fecal indicators, and less pharmaceutical compounds as compared to LAF. Even though analysis of pH after LAF suggested incomplete fermentation, E. coli cell numbers were significantly lower in all LAF treatments compared to composting at 7°C, and some of the anionic pharmaceutical compounds were detected in lower concentrations. The addition of approximately 5 vol % biochar to the composting did not yield significant differences in measured parameters. Vermicomposting further stabilized the material, and the treatments previously composted at 7°C and 20°C had the highest worm density. These results suggest that in small-scale decentralized sanitary facilities, the ambient temperatures can significantly influence the treatment and the options for safe reuse of the material. | publishedVersion
显示更多 [+] 显示较少 [-]Small-scale on-site treatment of fecal matter: comparison of treatments for resource recovery and sanitization 全文
2021
Kelova, Mariya Evgenieva | Ali, Aasim Musa Mohamed | Eich-Greatorex, Susanne | Dörsch, Peter | Kallenborn, Roland | Jenssen, Petter D.
publishedVersion | On-site small-scale sanitation is common in rural areas and areas without infrastructure, but the treatment of the collected fecal matter can be inefficient and is seldom directed to resource recovery. The aim of this study was to compare low-technology solutions such as composting and lactic acid fermentation (LAF) followed by vermicomposting in terms of treatment efficiency, potential human and environmental risks, and stabilization of the material for reuse in agriculture. A specific and novel focus of the study was the fate of native pharmaceutical compounds in the fecal matter. Composting, with and without the addition of biochar, was monitored by temperature and CO2 production and compared with LAF. All treatments were run at three different ambient temperatures (7, 20, and 38°C) and followed by vermicomposting at room temperature. Materials resulting from composting and LAF were analyzed for fecal indicators, physicochemical characteristics, and residues of ten commonly used pharmaceuticals and compared to the initial substrate. Vermicomposting was used as secondary treatment and assessed by enumeration of Escherichia coli, worm density, and physicochemical characteristics. Composting at 38°C induced the highest microbial activity and resulted in better stability of the treated material, higher N content, lower numbers of fecal indicators, and less pharmaceutical compounds as compared to LAF. Even though analysis of pH after LAF suggested incomplete fermentation, E. coli cell numbers were significantly lower in all LAF treatments compared to composting at 7°C, and some of the anionic pharmaceutical compounds were detected in lower concentrations. The addition of approximately 5 vol % biochar to the composting did not yield significant differences in measured parameters. Vermicomposting further stabilized the material, and the treatments previously composted at 7°C and 20°C had the highest worm density. These results suggest that in small-scale decentralized sanitary facilities, the ambient temperatures can significantly influence the treatment and the options for safe reuse of the material.
显示更多 [+] 显示较少 [-]Towards a rational design of materials for the removal of environmentally relevant cations: polymer inclusion membranes (PIMs) and surface-modified PIMs for Sn2+ sequestration in aqueous solution 全文
2021
This work is focused on the design and preparation of polymer inclusion membranes (PIMs) for potential applications for stannous cation sequestration from water. For this purpose, the membranes have been synthesized employing two polymeric matrices, namely, polyvinylchloride (PVC) and cellulose triacetate (CTA), properly enriched with different plasticizers. The novelty here proposed relies on the modification of the cited PIMs by selected extractants expected to interact with the target cation in the membrane bulk or onto its surface, as well as in the evaluation of their performances in the sequestration of tin(II) in solution through chemometric tools. The composition of both the membrane and the solution for each trial was selected by means of a D-Optimal Experimental Design. The samples such prepared were characterized by means of TG-DTA, DSC, and static contact angles investigations; their mechanical properties were studied in terms of tensile strength and elastic modulus, whereas their morphology was checked by SEM. The sequestering ability of the PIMs toward stannous cation was studied by means of kinetic and isotherm experiments using DP-ASV. The presence of tin in the membranes after the sequestration tests was ascertained by μ-ED-XRF mapping on selected samples.
显示更多 [+] 显示较少 [-]Sustainable metropolitan areas perspectives through assessment of the existing waste management strategies 全文
2021
Vardopoulos, Ioannis | Konstantopoulos, Ioannis | Zorpas, Antonis A. | Limousy, Lionel | Bennici, Simona | Inglezakis, Vassilis J. | Voukkali, Irene
Human activities are considered among the main producers of any kind of pollution. This paper, through a Driver-Pressure-State-Impact-Response (DPSIR) model analyses, focuses on the evaluation and assessment of the existing practices, procedures, and results obtained in order to determine whether the municipal solid waste (MSW) management implemented in three major Greek municipalities in the greater urban area of Attica, namely the municipalities of Nea Smirni, Vyronas, and Piraeus, could be considered viable and sustainable. The evaluation indicated that MSW in Greek cities have reduced over the last years, also suggesting a steady downward trend, which could be considered consistent with that of the per capita incomes in Greece due to the extended economic austerity, while at the same time the recycling indicator seems to optimize. The results are very useful for policymakers and local authorities towards taking actions related to the targets set from the circular economy strategies as well as the targets set from United Nation Development Program and the European Green Deal Strategy.
显示更多 [+] 显示较少 [-]Effects of low molecular weight organic acids on adsorption of quinclorac by sepiolite 全文
2021
Yang, Lihua | Deng, Yaocheng | Gong, Daoxin | Luo, Haifeng | Zhou, Xuguo | Jiang, Fangzhou
The effects of low molecular weight organic acids (LMWOAs) on the adsorption of quinclorac by sepiolite were investigated using laboratory batch technique. Experiments were conducted with two natural sepiolite samples with different crystal structures and chemical compositions and high-purity sepiolite. The LMWOAs used were acetic, oxalic, and citric acid. And the adsorption mechanism was characterized using X-ray photoelectron spectroscopy (XPS), X-ray diffraction (XRD), and Fourier transform infrared spectroscopy (FTIR). Our analysis revealed that adsorption of quinclorac on α-sepiolite and β-sepiolite was inhibited in the presence of 4 mmol L⁻¹ LMWOAs, whereas LMWOAs stimulated the adsorption of quinclorac in the high-purity sepiolite. Inhibition or stimulation varied across the different types of organic acids. The adsorption isotherms in the presence of 4 mmol L⁻¹ LMWOAs were better explained by Freundlich and linear model. The effect of organic acid concentrations (0–32 mmol L⁻¹) on the adsorption of quinclorac by the three sepiolite samples varies greatly depending on the type of organic acid and the property of sepiolite. FTIR, XRD, and XPS analyses showed that LMWOAs bound strongly to the Si–O bond structure, and Si–O-quinclorac-acetic acid (oxalic acid or citric acid) was formed on the surface of β-sepiolite. The adsorption of quinclorac by β-sepiolite was via hydrogen bond, complexation reactions, and charge transfer in the presence of LMWOAs. These results indicate that LMWOAs affect quinclorac adsorption through various interactions involving competition, electrostatic attraction, bridging action, and hydrogen bonding.
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