The geochemical characteristics of sediments deposited within a channel-type reservoir situated behind the weir of a water mill on the River Liswarta (southern Poland) were studied in relation to land use in the catchment. The catchment in question is an agricultural one with large forest areas. The contamination of sediments with trace elements was assessed using the geoaccumulation index. The sediments studied were moderately to heavily contaminated with As, Cu, Co, Ni and Ba. They were also heavily contaminated with Sr. Additionally, V and Cr contamination ranged from heavy to extreme. The basic composition of sediments and the trace elements present in them indicate both natural and anthropogenic sources of pollution. Mill impoundments provide zones where the sediments transported by rivers accumulate. Within the Liswarta catchment, their removal may cause the remobilisation of contaminated alluvial deposits.

The relationship between agricultural carbon emissions and agricultural economic growth has attracted a significant research attention. A key issue to address in the development of agriculture is the reduction of agricultural carbon emissions while maintaining agricultural economic growth. This study investigated the interactions between agricultural carbon emissions and agricultural economic growth from multiple perspectives based on agricultural carbon emission data from 30 provinces in China measured from 1997 to 2015. Using this dataset, the coupling and decoupling effects of agricultural carbon emissions and the underlying driving factors were explored using a coupling development degree model, the Tapio decoupling assessment model, and a logarithmic mean Divisia index (LMDI) decomposition model. The results were as follows: (1) at the regional scale, the degree of coupling development between agricultural carbon emissions and agricultural economic growth is high in the central region of China and low in the western region. At the provincial scale, the coupling effects of agricultural carbon emissions exhibited four levels: minimal, low, moderate, and high coupling. (2) With the exceptions of Beijing, Zhejiang, Fujian, Guangdong, Inner Mongolia, and Shanghai, the relationships between agricultural carbon emissions and agricultural economic growth in the other 24 provinces were in a weak decoupling state. (3) The effects of agricultural development scale and agricultural technical progress were the major driving factors associated with increases and decreases in agricultural carbon emissions, respectively.

This study evaluates nanofiltration as a feasible process to reach low concentrations of chromium in drinking water and provides means for the selection of the most suitable membrane based on the specific treatment needs. Chromium removal is concerning since new stringent limits (10 μg/L) for hexavalent Cr concentration in potable water were recently adopted in various countries. Three commercial nanofiltration membranes were tested against this threshold value: two membranes made of semi-aromatic polyamide and the third having a sulfonated polyethersulfone asymmetric film as the selective layer. The rejection observed as a function of chemical composition in the feed solution suggests that electrostatic effect is an important mechanism of chromium(VI) removal for the membranes with higher surface charge and lower film density. The performance of such membranes is strongly affected by the presence of salts, especially divalent cations, which reduce both Cr(VI) rejection and the permeate flux. The removal of Cr(VI) by denser membranes is dominated by solution-diffusion and is not influenced by feed ionic strength. The exposure of membranes to high chromium concentrations and to hypochlorite, typically employed as an oxidizing agent in water treatment plants, was also investigated. An analysis of the operational membrane life is thus discussed, based on the loss in performance due to active film degradation. All three membranes showed adequate rejection of chromium from tap and well water of diverse chemical composition, suggesting that nanofiltration is an effective process to remove chromium for the production of safe drinking water. However, membranes with different properties should be adopted depending on specific feed water composition and on the productivity required from the system. A final analysis is presented to help with the choice of the most suitable nanofiltration membrane based on initial and target Cr(VI) concentration in feed and product water, respectively.

Contamination from polycyclic aromatic hydrocarbons (PAHs) and polychlorinated biphenyls (PCBs) in the shallow water areas of the Venice Lagoon (415 km²) was investigated in the surface (0–5 cm) and sub-surface (5–10 cm) sediments by collecting cores from 380 sites. The concentrations of 14 PAHs (USEPA priority pollutants) and seven PCB indicator congeners were analysed with high-performance liquid chromatography (HPLC) and capillary gas chromatography (GC), respectively. PAH and PCB concentrations ranged from 2.75 to 9980 ng g⁻¹ d.w. and from 0.01 to 60.1 ng g⁻¹ d.w., respectively. Their concentrations never exceeded the probable effect level (PEL) stipulated in the respective quality guidelines. In addition, the average total PAH levels expressed as B[a]P toxicity equivalents (total TEQ) were lower in the sediments of the Venice Lagoon than in other literature-reported zones in the Mediterranean. PAH profiles and ratios showed that they originated not only largely from high-temperature pyrolytic processes attributable primarily to the burning of fossil fuels but also partly from petroleum spillage. Comparison of tetra-to-hepta PCB congeners enabled the PCB profiles observed in the lagoon environment to be characterised as Aroclor 1254 and 1260 (1:1). Compared to other marine coastal areas and harbours in the Mediterranean, the Venice Lagoon sediments showed a low mean value but a wide range of concentrations. The estimation of PAH and PCB inventories indicated the low contribution of atmospheric deposition relative to local sources.

Bor, Krivelj, and Bela Rivers belong to the watershed of Timok River, which is a tributary of transboundary Danube River. These rivers receive metal-rich acidic wastewater from metallurgical facilities and acid mine drainage (AMD) from mine wastes around Bor copper mines. The aim of this study was to determine the mobility and natural attenuation of metals and arsenic in rivers from Bor copper mines to Danube River during the year 2015. The results showed that metallurgical facilities had the largest impact on Bor River by discharging about 400 t of Cu per year through highly acidic wastewater (pH = 2.6). The highest measured concentrations of Cu in river water and sediments were 40 mg L⁻¹ and 1.6%, respectively. Dissolution of calcite from limestone bedrock and a high concentration of bicarbonate ions in natural river water (about 250 mg L⁻¹) enhanced the neutralization of acidic river water and subsequent chemical precipitation of metals and arsenic. Decreases in the concentrations of Al, Fe, Cu, As, and Pb in river water were mainly due to precipitation on the river bed. On the other hand, dilution played an important role in the decreases in concentrations of Mn, Ni, Zn, and Cd. Chemically precipitated materials and flotation tailings containing Fe-rich minerals (fayalite, magnetite, and pyrite) were transported toward Danube River during the periods of high discharge. This study showed that processes of natural attenuation in catchments with limestone bedrock play an important role in reducing concentrations of metals and arsenic in AMD-bearing river water.

Phthalates have been blended in various compositions as plasticizers worldwide for a variety of purposes. Consequently, humans are exposed to a wide spectrum of phthalates that needs to be researched and understood correctly. The goal of this review is to focus on phthalate’s internal exposure pathways and possible role of human digestion on liver toxicity. In addition, special focus was made on stem cell therapy in reverting liver toxicity. The known entry of higher molecular weight phthalates is through ingestion while inhalation and dermal pathways are for lower molecular weight phthalates. In human body, certain phthalates are digested through phase 1 (hydrolysis, oxidation) and phase 2 (conjugation) metabolic processes. The phthalates that are made bioavailable through digestion enter the blood stream and reach the liver for further detoxification, and these are excreted via urine and/or feces. Bis(2-ethylhexyl) phthalate (DEHP) is a compound well studied involving human metabolism. Liver plays a pivotal role in humans for detoxification of pollutants. Thus, continuous exposure to phthalates in humans may lead to inhibition of liver detoxifying enzymes and may result in liver dysfunction. The potential of stem cell therapy addressed herewith will revert liver dysfunction and lead to restoration of liver function properly.

Phytoremediation with biochar addition might alleviate pollutant toxicity to soil microorganism. It is uncertain to what extent biochar addition rate could affect activities of enzymes related to soil nitrogen (N) mineralization and alter fungal community under the phytoremediation. This study aimed to reveal the effects of Medicago sativa L. (alfalfa) phytoremediation, alone or with biochar additions, on soil protease and chitinase and fungal community and link the responses of microbial parameters with biochar addition rates. The alfalfa phytoremediation enhanced soil protease activities, and relative to the phytoremediation alone, biochar additions had inconsistent impacts on the corresponding functional gene abundances. Compared with the blank control, alfalfa phytoremediation, alone or with biochar additions, increased fungal biomass and community richness estimators. Moreover, relative to the phytoremediation alone, the relative abundances of phylum Zygomycota were also increased by biochar additions. The whole soil fungal community was not significantly changed by the alfalfa phytoremediation alone, but was indeed changed by alfalfa phytoremediation with 3.0% (w/w) or 6.0% biochar addition. This study suggested that alfalfa phytoremediation could enhance N mineralization enzyme activities and that biochar addition rates affected the responses of fungal community to the alfalfa phytoremediation.

A basic environmental risk assessment was carried out for the top 10 dispensed pharmaceuticals in Melbourne, Australia, in contrast to the more commonly assessed measure of the most used drugs by physical mass. This allowed for the evaluation of compounds that had not previously been the subject of risk assessment. Estimations of the possible fate and behaviour of the target pharmaceuticals in sewage treatment plants were also made. The predicted removal rates of most drugs within standard sewage treatment were expected to be low, with the exception of the statins, which had high removal rates. Each pharmaceutical was predicted to be present in Melbourne wastewater at the nanogram per litre range or lower. All compounds were predicted to be of low toxicity risk, although it was not possible to model mixture effects. Atorvastatin and Irbesartan were also found to possess the potential to possibly bioaccumulate in the aquatic food chain but not to the extent that would require regulation or labelling.

In this work, we assessed the drying and composting effectiveness of helminth eggs removal from sewage sludge of a lagoon wastewater treatment plant located in Chichaoua city. The composting was run after mixing sludge with green waste in different proportions: M1 (½ sludge + ½ green waste), M2 ([Formula: see text] sludge + [Formula: see text] green waste), and M3 ([Formula: see text] sludge + [Formula: see text] green waste) for 105 days. The analysis of the dewatered sewage sludge showed a load of 8–24 helminth eggs/g of fresh matter identified as Ascaris spp. eggs (5–19 eggs/g) followed by Toxocara spp. (0.2 to 2.4 eggs/g); Hookworm spp. and Capillaria spp. (0.4–1 egg/g); Trichuris spp., Taenia spp., and Shistosoma spp. (< 1 egg/g) in the untreated sludge. After 105 days of treatment by composting, we noted a total reduction of helminth eggs in the order of 97.5, 97.83, and 98.37% for mixtures M1, M2, and M3, respectively. The Ascaris spp. eggs were reduced by 98% for M1 and M3 treatments and by 97% for M₂ Treatment. Toxocara spp., Hookworm spp., Trichuris spp., Capillaria spp., and Shistosoma spp. eggs were totally eliminated (100% decrease) and the Taenia spp. was absent from the first stage of composting. These results confirm the effectiveness of both dehydrating and composting processes on the removal of helminth eggs.

Several rare earth element (REE) mine projects around the world are currently at the feasibility stage. Unfortunately, few studies have evaluated the contamination potential of REE and their effects on the environment. In this project, the waste rocks from the carbonatites within the Montviel proterozoic alkaline intrusion (near Lebel-sur-Quévillon, Quebec, Canada) are assessed in this research. The mineralization is mainly constituted by light REE (LREE) fluorocarbonates (qaqarssukite-Ce, kukharenkoite-Ce), LREE carbonates (burbankite, Sr-Ba-Ca-REE, barytocalcite, strontianite, Ba-REE-carbonates), and phosphates (apatite, monazite). The gangue minerals are biotites, chlorite, albite, ankerite, siderite, and calcite. The SEM-EDS analyses show that (i) the majority of REE are associated with the fine fraction (< 106 μm), (ii) REE are mainly associated with carbonates, (iii) all analyzed minerals preferably contain LREE (La, Ce, Pr, Nd, Sm, Eu), (iv) the sum of LREE in each analyzed mineral varies between ~ 3 and 10 wt%, (v) the heavy REE (HREE) identified are Gd and Yb at < 0.4 wt%, and (vi) three groups of carbonate minerals were observed containing variable concentrations of Ca, Na, and F. Furthermore, the mineralogical composition of REE-bearing minerals, REE mobility, and REE speciation was investigated. The leachability and geochemical behavior of these REE-bearing mine wastes were tested using normalized kinetic testing (humidity cells). Leachate results displayed higher LREE concentrations, with decreasing shale-normalized patterns. Thermodynamical equilibrium calculations suggest that the precipitation of secondary REE minerals may control the REE mobility.