The present study investigates the influence of individual and combined hydrogen peroxide and thermal pre-treatment of waste activated sludge on anaerobic digestion. For so doing, it employs anaerobic batch reactors in the mesophilic conditions. For comparison, soluble fractions of organic matter, biogas production, biochemical methane potential, removal of chemical oxygen demand (COD), and volatile solids (VS) have been measured during the anaerobic digestion process in systems with and without pre-treatment. Hydrogen peroxide pre-treatment has been tested in two concentrations of 30 g H2O2/kg VS and 60 g H2O2/kg VS and thermal pre-treatment has been performed at two temperatures of 75℃ and 90℃. According to the results, the solubalisation of organic matter considerably improves, when combined hydrogen peroxide and thermal pre-treatment is employed. As a result, in comparison to the control reactor, higher amounts of biogas (71%) and methane (81%) have been produced in the bioreactor, pre-treated with combined hydrogen peroxide (30 g H2O2/kg VS) and heat (90 ℃). In addition, the removal efficiency of COD and VS from the digested sludge has been enhanced in the pre-treated reactors (up to 39% and 92%, respectively) in comparison to the control reactor. The improved methane yield, COD, and VS are of paramount importance, not only because higher amounts of renewable energy are obtained from the anaerobic digestion process, but because sludge transport costs are reduced and the digested sludge obtains a higher potential application to agricultural lands.

Filter cake is one of the main waste products of zinc processing industries and it contains a high amount of toxic heavy metals. In this research in order to reduce heavy metals leachability in filter cake, Portland cement, natural pozzolan, diammonium phosphate (DAP), triple superphosphate (TSP), lime, zinc oxide and ground granulated blast furnace slag (GGBFS) have been used. This research’s results suggest that even though leachability of lead in the filter cake is quite low, it should be noted that limestone doubles the solubility level of Pb due to the mineralogical nature of the waste, by converting its sulphate form (PbSO4) to its carbonate form (PbCO3), which is more soluble. TSP was the only additive capable of reducing the leachability of metal elements in the filter cake as well as stabilizing the amounts of Pb and Cd in TCLP extracts within the limit. Although all additives were able to reduce Cd leachability, TSP and ZnO had the most remarkable efficiency. According to XRD results, the main factor in lead stabilization using TSP was a reduction in the amount of PbSO4 (with high Ksp) and an increase in PbS (with low Ksp), which ultimately reduced lead leachability. The Pozzolan which was used for the first time as a stabilizer demonstrated a good performance in reducing the leachability of Cd, Ni and Cu. In addition, due to the pseudo-cementitious properties of Pozzolan, it can reduce leachability of metal elements, along with other additives such as cement, by increasing the solidification efficiency.

The need for oil and natural gas as a major source of energy is vital. On the one hand, it has affected the political and economic equations at the international, regional and national level. On the other hand, it has had negative effects on sociocultural, legal, and environmental aspects as well as on the physical and mental health of human beings. Therefore, the need to provide an environmental policy that addresses the various dimensions of the oil and gas industry will be necessary. The present paper aims to set up a conceptual model of environmental policy for sustainable development in the oil and gas industries of the Kurdistan Region through the use of these 6 components: political, economic, sociocultural, technological, legal and environmental. It will also be using the techniques of PESTLE, SWOT, SPACE, FANP, FDEMATEL, and simulation with the VENSIM software. The results show the weights of the criteria respectively are Political; 1.59, Economic; 0.78, Sociocultural; 0.00, Legal; -0.99, Technological; -0.61 and Environmental; -0.70. So that all components are important, but that political and economic factors have a significant influence on environmental policies and oil and gas industries. Sociocultural components have a neutral role and the technological, legal and environmental components are impressible. Finally, fifteen strategies for the formulation of an effective environmental policy in the oil and gas industry were presented.

Ahvaz can be regarded as one of the most polluted cities in the world in terms of air pollution. Successive years of drought and weather conditions in recent years have resulted in particulate matter (PM10) concentration in Ahvaz. In this study, using probability distribution techniques, an appropriate threshold to identify the PM10 maximum extreme concentrations (MEC) has been detected. Based on log-logistics probability distribution, which has the best fit to the data of PM10 concentration in Ahvaz, the 0.99 percentile threshold which is specified by 1516 μg/m³ is known as the primary PM10 concentrations in Ahvaz air. Based on the mentioned threshold, 24 days in which the PM10 concentration was equal to or more than the threshold were selected for synoptic analysis. Analysis of the circulation of weather types showed that two weather types circulations at 500 hPa level provide the climatic conditions for the occurrence of (MEC) caused by PM10 concentration ≥1516 μg/m³ in Ahvaz in the first type (which is for hot days). Under such condition, the closed high pattern of 500 hPa level is accompanied by the ground low pressures. In the second type (which is for cold and transitional days) the closed high pattern of 500 hPa level is accompanied by the ground high pressures. In addition, this study showed that the (MEC) of PM10 in both models fed with several different sources at different levels and due to being multi-source, storms can create MEC.

The present investigation has been conducted to assess the status of physico-chemical parameters as well as the concentrations of some selected heavy metals to understand the present scenario of water quality at Perak River basin, Malaysia. The temperature, turbidity, pH, EC and DO values of all the examined samples have been within the range of 25.0 to 30.5 0C, 39.5 to 168.00 NTU, 6.8 to 7.33, 30.3 to 113.8 μs/cm and 3.62 to 7.01 mg/L, respectively. The concentrations of trace metallic constituents have been determined by means of Inductively Coupled Plasma-Optical Emission Spectrometry (ICP-OES), giving the following ranges: Cr: 0.01 to 0.052 mg/L; Pb: 0.01 to 0.03 mg/L; Zn: 0.11 to 0.92 mg/L; Fe: 1.38 to 5.55 mg/L; Mn: 0.10 to 0.25 mg/L and Ca: 2.55-23.23 mg/L, respectively. The concentrations of heavy metals at downstream of Perak River water were higher than the concentrations of upstream. The order of heavy metallic constituents in the water samples was Fe > Zn > Mn > Cr > Pb. R mode Cluster Analysis (CA) suggests that multiple anthropogenic activities like urban runoff, agricultural runoff, discharges of vehicles washing and workshops, land use changes, unplanned settlements, domestic effluents, wastewater of livestock husbandry farms etc., are influencing the physico-chemical parameters and heavy metals concentrations of Perak River water. The present study is highly significant for providing baseline information of potential hazardous level of heavy metals to human health, environment, and sustainable water resources management for economically and environment friendly uses of Perak River.

Environmental assessments are essential in order to align the process of country's progress towards sustainable development. It is important for the project to be implemented in direction of sustainable development, which is to carry out a project in such a way that in both short and long term, the greatest advantages and the least harm are inflicted on the environment, economy, communities, and culture. Environmental assessment of gas pipelines is classified as a linear projects; therefore, the design and implementation of an appropriate method in accordance with the project's linearity, due to the use of GIS tools and multi-criteria decision-making methods, can be a good innovation for this study, in comparison to previous similar projects. The purpose of this study is to identify the best option for gas pipelines. Once the project's study scope is specified, the study based the sensitive environmental parameters of the area (based on the requirements of environmental impact assessment reports) on two methods of Analyzing Hierarchical Process (AHP) and overlaying methods for sub-parameters, ranking and prioritizing the area of evaluation. Based on the results, the first and second priorities belong to the parameter of distance and position in the protected areas with a weight of 29.9% and hydrology with a weight of 24.7%, followed by slope, vegetation, land use, and fault, which are ranked third to seventh, respectively. After identifying the best map option, the study extracts the critical points for the construction of pipelines, identifies the negative effects of the project, and presents the environmental impacts and preventive measures, reduction and compensation of negative effects in both construction and operation phases, along with a summary of the Environmental Management Program (EMP).

The present study focuses on effects of initial pH on dibenzothiophene (DBT) desulfurization via 4S pathway by growing cells of Ralstonia eutropha. For so doing, temporal changes of biomass concentration, glucose as a sole carbon source, pH value, and 2-hydroxybiphenyl (2-HBP) formation have been monitored during the bioprocess. The biomass concentration has been modeled by the logistic equation and results show that the values of maximum specific growth rate (μmax) and maximum cell concentration (Xmax) have increased in line with the rise of initial pH from 6 to 9. This confirms the effect of pH on the energetics of cell growth via altering the proton gradient and manipulating ATP-related metabolic pathways. By considering the Pirt’s maintenance concept, the bioenergetic aspects of DBT desulfurization process are affected by changes in pH, where the maximum specific DBT conversion rate (0.0014 mmol/gcell.h) has been obtained at initial pH of 8. Additionally, the kinetic modeling of the 2-HBP formation through the Luedeking-Piret model indicates that the DBT desulfurization rate is linearly related to the cell growth rate, instead of biomass concentration. The growth associated and non-growth associated 2-HBP formation constants have been obtained 3.82 mg2-HBP/gcell and 0.06 mg2-HBP/gcell.h, respectively at an initial pH of 8.

The present study aims at developing a forecasting model to predict the next year’s air pollution concentrations in the atmosphere of Iran. In this regard, it proposes the use of ARIMA, SVR, and TSVR, as well as hybrid ARIMA-SVR and ARIMA-TSVR models, which combined the autoregressive part of the autoregressive integrated moving average (ARIMA) model with the support vector regression technique (ARIMA-SVR). The main concept of generating a hybrid model is to combine different forecasting techniques so as to reduce the time-series forecasting errors. The data used in this study are annual CO2, CO, NOx, SO2, SO3, and SPM concentrations in Iran. According to the results, the ARIMA-TSVR Model is preferable over the other models, having the lowest error value among them which account for 0.0000076, 0.0000065, and 0.0001 for CO2; 0.0000043, 0.0000012, and 0.000022 for NOx; 0.00032, 0.00028., and 0.0012 for SO2; 0.000021, 0.000014, and 0.00038 for CO; 0.0000088, 0.0000005, and 0.00019 for SPM; and 0.000021, 0.000019, and 0.0044 for SO3. Furthermore, the accuracy of all models are checked in case of all pollutants, through RMSE, MAE, and MAPE value, with the results showing that the hybrid ARIMA-TSVR model has also been the best. Generally, results confirm that ARIMA-TSVR can be used satisfactorily to forecast air pollution concentration. Hence, the ARIMA-TSVR model could be employed as a new reliable and accurate data intelligent approach for the next 35 years’ forecasting.

Management of solid wastes is considered as an economic and environmental issue in the building stone industry. The current study uses raw and calcined calcareous sludge, generated in the stone cutting factories, in order to remove sulfur dioxide. Sludge characterization has been performed, using X-ray fluorescence (XRF), X-ray diffraction (XRD), scanning electron microscopy (SEM), and energy-dispersive X-ray spectroscopy (EDX) analyses. The removal experiments of sulfur dioxide have conducted under different humid contents and adsorbent doses. The results showed that the higher the adsorbent dosage and humidity content, the greater the SO2 adsorption.. The calcination process at temperatures of 400, 500, 600, and 700℃ revealed that with rising calcination temperature and humidity content, the adsorbent capability is enhanced considerably. This method could be developed for the management of stone sludge produced from the stone cutting industry through its conversion into an effective and low-cost adsorbent for desulfurization process.

In this study, the lethal toxicity, behavioral responses and hematotoxicity of formulated chlorpyrifos on Clarias gariepinus was evaluated. C. gariepinus fingerlings were exposed to 0.2 mg/L, 0.25 mg/L, 0.3 mg/L, 0.35 mg/L and 0.4 mg/L of the active ingredient chlorpyrifos to determine the lethal concentrations and behavioral effects. C. gariepinus juveniles (38.84±7.67g) were then exposed to 0.0256 mg/L and 0.0128 mg/L for 14 days to study somatic indices and haematological effects. The 24h, 48h, 72h and 96h LC50 were estimated as 0.292 (0.210 – 0.376) mg/L, 0.275 (0.252 – 0.297) mg/L, 0.263 (0.242 – 0.282) mg/L, and 0.256 (0.235 – 0.275) mg/L respectively. Hyper activity, loss of equilibrium, erratic swimming, trembling, respiratory distress and poor startle response were observed in fingerlings in response to acute toxic stress of chlorpyrifos. Liver somatic index (LSI) of exposed juveniles increased significantly (p<0.05) compared with control, while there was no statistically significant difference in all the haematological parameters of the exposed fishes compared with the control (p<0.05). The results indicate that the chlorpyrifos formulation was highly toxic and induced behavioral changes in C gariepinus fingerlings, while sub-lethal concentrations induced inflammation in the liver but had no effect on haematological parameters of Clarias gariepinus juveniles. LSI was sensitive to the sub-lethal concentrations and could serve as indicators or exposure to organophosphate insecticides.