In this investigation, bentonite clay (BC) and bentonite clay@MnFe2O4 composite (BCMFC) were applied as efficient adsorbents for adsorbing Cr(III) and Cr(VI) ions from aqueous media. Different analyses such as FTIR, SEM, EDX, Map, BET, and XRD were used to characterize the adsorbents. The results showed that the removal efficiency of Cr(III) and Cr(VI) using BC were found to be 95.21 and 95.74%, while the corresponding values to the BCMFC were 97.37 and 98.65%, respectively. Also, the equilibrium and kinetic studies showed that the Freundlich isotherm model and the quasi-second-order kinetic model could better describe the equilibrium and kinetic behaviors of the adsorption process. The maximum adsorption capacity of the BC for the adsorption of Cr(III) and Cr(VI) ions were evaluated as 151.5 mg/g (25oC, pH 6, 90 min, and 1 g/L) and 161.3 mg/g (25oC, pH 3, 90 min, and 1 g/L), respectively, while the BCMFC showed the maximum capacities of 175.4 mg/g (25oC, pH 6, 60 min, and 1.5 g/L) and 178.6 mg/g (25oC, pH 3, 60 min, and 1.5 g/L) for Cr(III) and Cr(VI) ions, respectively, which were remarkable amounts. In addition, the thermodynamic study indicated that the adsorption process was physical, spontaneous, and exothermic. High removal efficiency, high chromium adsorption capacity, and low-cost magnetic adsorbent were significant features of the BCMFC for removal of Cr (III) and Cr (VI).

Metals are widely used in modern society harming the environment; their toxicity cause environmental adverse effects to many organisms including zooplankton. This contribution employed: (a) acute and chronic toxicity tests, (b) epifluorescence image analysis, and (c) atomic absorption techniques, to analyze toxicity of four trace (copper, iron, nickel, and zinc), and one non-trace metals (mercury) on the freshwater rotifer Euchlanis dilatata. This work integrated results of Bioconcentration Factors (BCF’s), sites of entry and accumulation and to determine mechanisms of uptake and toxicity of these five metals of the freshwater rotifer Euchlanis dilatata. This integral analysis enhanced our understanding of knowledge on: (a) the toxicity mechanisms, (b) sites of metal entry and concentration inside the rotifer, (c) bioconcentration and body burdens. As expected, Hg the non-trace metal used here, was the most toxic. Our results suggest that the toxicity is ameliorated in the rotifer by selecting feeding avoiding the most toxic particles and reducing adverse effects on reproduction, until mortality per se reduces reproduction. The chronic effect on ingestion rate was quite sensitive for all metals whereas reproduction was slightly affected. The combination of acute and chronic tests and determination of BCF’s for each metal allowed calculation of the acute and chronic body burdens. Body burdens again confirmed that mercury was the most toxic metal of the five employed here.

The purpose of this study was to examine the accumulation potential of spontaneously developed Tussilago farfara populations colonizing sites with different levels of anthropogenic pollution. Physical characteristics of the soil are presented, together with the concentrations of macroelements and microelements (Ca, Mg, Fe, S, Al, Pb, Zn, Cu, Cd, Mn, As, Sb, Ag, Ti, and Sr) in both soil and plants. The biological concentration, accumulation, and translocation factors were used to assess the potential for heavy metal accumulation. Considerable differences were found among assessions from unevenly contaminated habitats, particularly in comparison with an unpolluted site. In line with the ore’s characteristics, substrate samples from polluted sites were heavily contaminated with Pb, Zn, As, and Sb. Increased levels of microelements were also detected in plant samples from flotation tailings. Despite active absorption of Zn, Cu, Cd, Mn, and Sr by the plants from mining sites, the detected quantities of these elements in all samples were below the hyperaccumulation threshold. However, the obtained results indicate that the use of T. farfara from such sites in traditional medicine could pose a risk to human health due to accumulation of several toxic elements in the plant’s aboveground tissues. Additionally, as a successful primary colonizer and stabilizer of technogenic substrates, T. farfara has an important role in the initial phases of revegetation of highly contaminated sites.

It is important to maintain the sustainable development of water resources. Objective assessment on water resource carrying capacity (WRCC) is beneficial to the formulation of scientific and reasonable water management practices. In view of the problem that evaluation indicators of WRCC cannot describe the fuzziness and randomness, a cloud model was introduced into regional WRCC assessment. This study selected a typical karst area (Guiyang) as the research object to study WRCC by using cloud model with combination weighting method. WRCC was assessed from the following five dimensions: water environment subsystem, social subsystem, economic subsystem, ecological subsystem, and humanities (water resource management and policy regulation) subsystem. In addition, evaluation results after normalizing all of indicators data were also calculated. And these two kinds of evaluation results were compared with that of technique of order preference similarity to the ideal solution (TOPSIS), finding that evaluation results of cloud model were consistent with that of TOPSIS method. The cloud model realizes the transformation from qualitative evaluation to quantitative evaluation, which overcome insufficiencies of traditional evaluation methods in considering fuzziness and randomness. Results showed that during the period of 2008–2017, the state of WRCC in Guiyang was improving year by year, increasing from the serious overload carrying capacity level in 2008 to the strong carrying capacity level in 2017 (serious overload-overload-critical-weak carrying capacity–strong carrying capacity). However, some certain evaluation indicators are still in danger situation, such as population natural growth rate and use of the fertilizer per unit cultivated area, which needs to be further enhanced and improved. Moreover, the contradiction among economic development, population growth, and water resources is becoming increasingly apparent. To ensure the effective utilization of water resources in Guiyang, reasonable policies and measures should be formulated and put into effect. Research results could provide certain reference for the sustainable development of regional water resources.

Necroptosis is a regulated cell death that is governed by mixed lineage kinase domain-like, receptor-interacting serine-threonine kinase 3 and commonly displays with necrosis morphological characteristics. This study examined the molecular mechanisms involved in the chemical-induced necroptosis where a systematic evaluation of experimental studies addressing this issue is missing. We strictly reviewed all scientific reports related to our search terms including “necroptosis” or “programmed necrosis”, “environmental chemicals” or “air pollutants” or “pesticides” or “nanoparticles” and “Medicines” from 2009 to 2019. Manuscripts that met the objective of this study were included for further evaluations. Studies showed that several pathological contexts like cancer, neurodegenerative disorders, and inflammatory diseases were related to necroptosis. Furthermore, multiple chemical-induced cytotoxic effects, such as DNA damage, mitochondrial dysregulation, oxidative damage, lipid peroxidation, endoplasmic reticulum disruption, and inflammation are also associated with necroptosis. The main environmental exposures that are related to necroptosis are air pollutants (airborne particulate matter, cadmium, and hydrogen sulfide), nanoparticles (gold, silver, and silica), pesticides (endosulfan, cypermethrin, chlorpyrifos, and paraquat), and tobacco smoke. To sum up, air pollutants, pesticides, and nanoparticles could potentially affect human health via disruption of cell growth and induction of necroptosis. Understanding the exact molecular pathogenesis of these environmental chemicals needs further comprehensive research to provide innovative concepts for the prevention approaches and introduce novel targets for the amelioration of a range of human health problems.

Facing increasingly serious environmental problems, technological innovation has become the key for industrial enterprises to coordinate energy conservation and emission reduction constraints and achieve steady growth of the industrial economy. Considering the impact of energy consumption and environmental pollution on the technological innovation efficiency of industrial enterprises, this paper incorporates industrial energy consumption, pollution control, and wastewater and exhaust emissions into the technical inefficiency equation. Based on the panel data of industrial enterprises in 30 provinces and autonomous regions in China from 2009 to 2016, the stochastic frontier analysis (SFA) model is used to study the effect of energy consumption and environmental pollution on technological innovation efficiency of industrial enterprises. The research results show that reducing energy consumption and increasing pollution treatment investment both have a significant driving effect on the improvement of industrial enterprises’ technological innovation efficiency. Industrial wastewater and exhaust emissions have the opposite effect; unreasonable input mode of pollution control and personnel allocation have hindered the improvement of industrial enterprises’ technological innovation efficiency. The average annual trend of technological innovation efficiency in industrial enterprises shows a curve of first rising, then falling, and rising again. The average values of Chongqing, Zhejiang, and Hunan rank in the top three, and the average values of Qinghai, Heilongjiang, and Inner Mongolia rank the bottom three. The average values of other provinces are higher than 0.9, and the difference is small. A suitable incentive mechanism should be established for industrial enterprises to save energy and reduce emissions and strengthen pollution control, improve the training program for environmental protection technical personnel, and provide important support for improving the green competitiveness of industrial enterprises.

Currently, in situ capping is a typical popular geoengineering method for eutrophication control. It is crucial to better understand the effect of microenvironment change due to capping, such as amended calcium peroxide material (ACPM) and Phoslock®, on phosphorus (P) adsorption and immobilization under the addition of external P. The microenvironment in sediment was presented by the concentration of O₂, NH₄⁺, and Fe²⁺ and microbial activity. The P removal and immobilization were also analyzed. The results show that the stronger oxidation in the microenvironment under the capping with ACPM was due to the higher reduction of NH₄⁺ and Fe²⁺ and the higher increase of microbial activity, compared to Phoslock®. Although, under the capping of ACPM, less amount of external P was removed and there was a faster release of sedimentary P, compared to Phoslock®, ACPM improved the transformation of P from mobile P fractions to inert P fractions. In addition, sedimentary P under the capping of ACPM presents less release than that under the capping of Phoslock® during the anaerobic incubation. However, the settlement of suspended solids decreased the function of capping. All these results indicated that the mechanism of P removal and immobilization was different under the capping of ACPM and Phoslock®.

In this research, several biochemical variations in plant of Lemna minor L. were investigated to reflect Ag⁺ toxicity. Lemna minor L. changed colorless AgNO₃ to colloidal brown at doses equal to and greater than 1 mg L⁻¹. Optical and fluorescence microscopy revealed the presence of bright spots in roots of tested plant related to Ag/Ag₂O-NPs. Photosynthetic pigment contents of Lemna minor L. declined upon exposure to Ag⁺ with an evidently higher decrease in chlorophyll a than in chlorophyll b. Similarly, Ag⁺ treatment caused an evident reduction in the activities of superoxide dismutase (SOD), peroxidase (POD), and catalase (CAT). The reduction in antioxidase activity was significantly higher in POD than in SOD and CAT. Ag⁺ treatment resulted in a significant increment in the level of malondialdehyde (MDA) content as the judging criteria of cellular injury which showed sign of dose-related. The alterations occurred in RAPD profiles of treated samples following Ag⁺ toxicity containing loss of normal bands, appearance of new bands, and variation in band intensities compared with the normal plants. In addition, morphological character and biomass of Lemna minor L. subjected to increasing Ag⁺ concentrations were evaluated to reveal Ag⁺ toxicity. Our study demonstrated that Lemna minor L. have a high sensitivity to indicate fluctuation of water quality. It would be beneficial that modulating the genotype of Lemna minor L. to bear high proportion of contaminates.

Ever since China’s “housing reform” in 1998, the level of real estate investment in its cities has continued to rise, leading to the occupation of green space, rapid population concentration, and a severe mismatching of financial resources. At the same time, urban air quality has changed drastically for the worse, with PM2.5 becoming the primary air indicator of concern for many cities in recent years. The existing literature has obtained sufficient results on the influence factors of air pollution, but rarely presents the relationship between real estate investment and air pollution, especially using multiple cities as the sample. This paper thus examines the impact of real estate investment on air quality using a sample of 261 prefecture-level cities in China over the period 1999–2016 through several econometric models. First, the two-way fixed-effect model shows an inverted U-shaped relationship between PM2.5 concentration and real estate investment, but most cities have not yet crossed the turning point, and that real estate investment negatively impacts air quality. Second, the indirect effect of real estate investment on PM2.5 concentration comes from its non-linear impact on urban green coverage, population density, and industrial structure, which has been verified by Hayes and Preacher’s (Behav Res 45:627–660, 2010) mediation effect with non-linear forms. Third, heterogeneity analysis indicates that an inverted U-shaped relationship also exists in the subsamples, and that real estate investment in cities with more people, higher GDP, and greater development level is more likely to increase rather than mitigate air pollution. Therefore, cities should promote the green development of real estate and related industries by enhancing environmental awareness, guide the population flow toward the coordinated development between real estate investment and population distribution, and encourage environmentally friendly technological progress via a better rational allocation of financial resources.

Graphitic carbon nitride (g-C₃N₄) is paying attention lately owing to its interesting characteristics and substantial application in improving environmental and energy concerns. Nevertheless, the photocatalytic activity of g-C₃N₄ is constrained by the inertness of the surface and particle aggregation during photocatalytic activity. Herein, we report the preparation of g-C₃N₄ with honeycomb-like morphology (HC-C₃N₄) via thermal condensation of prepared SiO₂ templates and dicyandiamide. The etching out of the SiO₂ templates by NH₄HF₂ created hollow or macropores in the C₃N₄ matrix resulting in its structural changes. Similar, to the bulk C₃N₄, the HC-C₃N₄ exhibited higher photocatalytic CO₂ reduction in hydrocarbons. This improved photocatalytic achievement is associated with higher specific surface area, excellent visible light absorption capability, higher electron donor density, easy mass diffusion of materials for surface reaction, and effective segregation of photogenerated charge carriers. Furthermore, the HC-C₃N₄ honeycomb structure was deposited with Ni(OH)₂ clusters which showed remarkable CO₂ reduction activity of 1.48 μmolh⁻¹ g⁻¹ of CH₄ and 0.73 μmolh⁻¹ g⁻¹ of CH₃OH generation which is 3.5 and 4.3 times higher CO₂ reduction activity compared with bulk C₃N₄ clustered with Ni(OH)₂ particles. This comprehensive study demonstrated that HC-C₃N₄ nanostructured polymeric semiconductor is envisaged to have great potential in the application of a variety of fields such as photocatalysis, sensor technology, and nanotechnology.