The presence of phenols, such as nonylphenol (NP), bisphenol (BPA), and octylphenol (OP), in the environment have been receiving increased attention due to their potential risks to human health and environment. The use of reclaimed water for irrigation may be one of the sources of these phenols in the agricultural system. A field experiment was conducted to assess the effects of reclaimed water irrigation on phenol contamination of agricultural topsoil and products in the North China Plain between 2015 and 2016. Three irrigation treatments were applied to all crops: reclaimed water irrigation, groundwater irrigation and alternative irrigation with reclaimed water and groundwater (1:1, v/v). The results showed that the concentrations of NP, BPA, and OP in the topsoil were 0.02–0.54, 0.004–0.06, and ND–9.9 × 10⁻³ mg/kg, respectively; the corresponding values in agricultural products were 0.007–0.70, 0.004–0.24, and ND–1.08 mg/kg, respectively. The concentration of NP in the topsoil and agricultural products and that of BPA in the agricultural products were all less than the recommended limits. The yields of wheat, maize, vegetables were 4.35–7.08, 1.03–6.46, and 10.9–67.0 t/ha, respectively. The bioaccumulation factors (BCFs) of OP, NP, and BPA for cereals were 0.7–4.77, 0.16–4.59, and 1.3–23.9, respectively; the corresponding values in vegetables were 0.0–4.53 (except cucumber and eggplant), 0.38–12.6, and 0.57–24.3, respectively. No significant differences in phenol concentrations, BCFs, or yields of wheat and vegetables were observed among the three irrigation treatments. In conclusion, compared with groundwater irrigation, reclaimed water irrigation in this experiment did not significantly affect phenol concentrations in the topsoil and agricultural products as well as BCFs and yields of wheat and vegetables. However, because the quality of reclaimed water may vary across collected areas, additional experiments are warranted to analyze the effects of reclaimed water irrigation on the risk of phenol contamination.

Daunting amounts of microplastics are present in surface waters worldwide. A main category of microplastics is synthetic microfibers, which originate from textiles. These microplastics are generated and released in laundering and are discharged by wastewater treatment plants or enter surface waters from other sources. The polymers that constitute many common synthetic microfibers are mostly denser than water, and eventually settle out in aquatic environments. The interaction of these microfibers with submerged aquatic vegetation has not been thoroughly investigated but is potentially an important aquatic sink in surface waters. In the Laurentian Great Lakes, prolific growth of macrophytic Cladophora creates submerged biomass with a large amount of surface area and the potential to collect and concentrate microplastics. To determine the number of synthetic microfibers in Great Lakes Cladophora, samples were collected from Lakes Erie and Michigan at multiple depths in the spring and summer of 2018. After rinsing and processing the algae, associated synthetic microfibers were quantified. The average loads of synthetic microfibers determined from the Lake Erie and Lake Michigan samples were 32,000 per kg (dry weight (dw)) and 34,000 per kg (dw), respectively, 2–4 orders of magnitude greater than loads previously reported in water and sediment. To further explore this sequestration of microplastics, fresh and aged Cladophora were mixed with aqueous mixtures of microfibers or microplastic in the laboratory to simulate pollution events. Microscopic analyses indicated that fresh Cladophora algae readily interacted with microplastics via adsorptive forces and physical entanglement. These interactions mostly cease upon algal senescence, with an expected release of microplastics in benthic sediments. Collectively, these findings suggest that synthetic microfibers are widespread in Cladophora algae and the affinity between microplastics and Cladophora may offer insights for removing microplastic pollution.Macroalgae in the Laurentian Great Lakes contain high loads of synthetic microfibers, both entangled and adsorbed, which likely account for an important fraction of microplastics in these surface waters.

Knowledge of the concentration of the bioavailable forms of mercury in the soil is necessary, especially, if these soils contain above-limit total mercury concentrations. The bioavailability of mercury in soil samples collected from the vicinity of abandoned cinnabar mines was evaluated using diffusive gradients in the thin films technique (DGT) and mercury phytoaccumulation by vegetables (lettuce, spinach, radish, beetroot, carrot, and green peas). Mercury was accumulated primarily in roots of vegetables. The phytoaccumulation of mercury into edible plant parts was site-specific as well as vegetable species-specific. The mercury concentration in edible parts decreased in the order: spinach leaf ≥ lettuce leaf ≥ carrot storage root ≥ beetroot storage root > radish storage root > pea legume. The translocation index as well as the target hazard quotient indicate the possible usability of soils from the vicinity of abandoned cinnabar mines for planting pod vegetables (peas). A strong positive correlation (r = 0.75 to 0.92, n > 30, p < 0.05) was observed between mercury concentration in secondary roots, the storage roots, leaves of vegetables and the flux of mercury from soil to the DGT units, and the effective concentration of mercury in soil solutions.

Chemicals such as triclosan are a concern because of their presence on daily products (soap, deodorant, hand sanitizers …), consequently this compound has an ubiquitous presence in the environment. Little is known about the effect of this bactericide on aquatic life. The aim of this study is to analyze triclosan exposure (24 h) to an in vitro model, zebrafish hepatocytes cell line (ZF-L), if it can be cytotoxic (mitochondrial activity, membrane stability and apoptosis) and if can activate ATP-binding cassette (ABC) proteins (activity, expression and protein/compound affinity). Triclosan was cytotoxic to hepatocytes when exposed to concentrations (1–4 mg/L). The results showed impaired mitochondria function, as well, plasma membrane rupture and an increase of apoptotic cells. We observed an ABC proteins activity inhibition in cells exposed to 0.5 and 1 mg/L. When ABCBs and ABCC2 proteins expression were analyzed, there was an increase of protein expression in both ABC proteins families on cells exposed to 1 mg/L of triclosan. On molecular docking results, triclosan and the fluorescent used as substrate (rhodamine) presented high affinity with all ABC proteins family tested, showing a greater affinity with ABCC2. In conclusion, this study showed that triclosan can be cytotoxic to ZF-L. Molecular docking indicated high affinity between triclosan and the tested pumps.

Rising of temperature in conjunction with acidification due to the anthropogenic climates has tremendously affected all aquatic life. Small changes in the surrounding environment could lead to physiological constraint in the individual. Therefore, this study was designed to investigate the effects of warm water temperature (32 °C) and low pH (pH 6) on physiological responses and growth of hybrid grouper (Epinephelus fuscoguttatus ♀ × Epinephelus lanceolatus ♂) juveniles for 25 days. Growth performance was significantly affected under warm water temperature and low-pH conditions. Surprisingly, the positive effect on growth was observed under the interactive effects of warm water and low pH exposure. Hybrid grouper exposed to the interactive stressor of warm temperature and low pH exhibited higher living cost, where HSI content was greatly depleted to about 2.3-folds than in normal circumstances. Overall, challenge to warm temperature and low pH induced protein mobilization as an energy source followed by glycogen and lipid to support basal metabolic needs.

Emerging per-/polyfluoroalkyl substances (PFASs), such as chlorinated polyfluorinated ether sulfonates (Cl-PFESAs), have been detected in human samples, yet investigation on their occurrence in pregnant women remains limited. Herein, ten legacy PFASs, branched perfluorooctanesulfonate (PFOS) and perfluorooctanoate (PFOA), two Cl-PFESAs, perfluoro-2-propoxypropanoic acid (HFPO-DA), and ammonium 4,8-dioxa-3H-perfluorononanoate (ADONA) were detected in serum samples from 480 pregnant women in Tianjin, China. The influencing effects of age, body mass index, gravidity, and parity were also evaluated. PFOS [geographic mean (GM): 7.05 ng/mL], 6:2Cl-PFESA (GM: 5.31 ng/mL), and PFOA (GM: 2.82 ng/mL) were the dominant PFASs in the serum of pregnant women, while neither HFPO-DA nor ADONA was detectable in any serum. The serum concentration of Cl-PFESAs and 6:2Cl-PFESA/PFOS ratio in the present study were 2–5 times higher than that in previous studies of pregnant women in China. Serum concentrations of Cl-PFESAs were significantly correlated with all detected PFAAs (Spearman’s Rho: 0.15–0.69, p < 0.01) excepting perfluoropentanesulfonate (PFPeS), indicating common exposure sources for Cl-PFESAs and PFAAs and some particular exposure source for PFPeS. Younger age and multi-parity were associated with lower serum concentrations of PFOS and several perfluoroalkyl sulfonates but not associated with Cl-PFESAs or PFOA, suggesting an increasing exposure to Cl-PFESAs and PFOA which neutralized the impact of age and parity. Overall, this study indicated a relatively high exposure level and composition of 6:2Cl-PFESA in pregnant women in the north coast of China, which highlights the need to investigate the exposure sources in this area.

This study reports seasonal variations of meteorological parameters, atmospheric dust and dust-borne heavy metals concentrations measured, over a period of two years, next to two major airports (Dubai International Airport and Abu Dhabi International Airport) in the Gulf Cooperation Council (GCC) region. On-line monitoring stations were installed at each location next to dust samplers used to frequently collect PM2.5 and PM10 on Teflon filters for metal analysis. Clear seasonal variation in meteorological parameters were identified. The particulate matter concentrations depicted from the two locations were continuously monitored. The PM2.5 concentration ranged from 50 to 100 μg/m³ on normal days but reached 350–400 μg/m³ per day during mild storms. The PM10 levels ranged between 100 and 250 μg/m³ during normal days and spiked to 750 μg/m³ during mild storms. Energy Dispersive X-Ray Analysis (EDS) revealed the presence of significant amounts of alkali and alkaline earth metals, which pose potential harm to aircraft engines. ICP analysis showed the presence of heavy and toxic metals in concentrations that may pose harm to human health. Bulk sand samples from Abu Dhabi sites showed chemical similarities to the atmospheric dust samples. The concentrations of heavy metals, PM2.5, and PM10 are at levels that require further monitoring due to their impact on human health. The two years meteorological monitoring, with the seasonal variations, provided additional regional data in the Arabian Gulf. Furthermore, the study concluded that Sand and Dust storms (SDS) occur more frequently at the northern Arabian Gulf compared to its southern region. The chemical correlation between atmospheric dust and regional desert sand suggests the localized origin of the smaller dust particles that may form by breaking apart of the ground sand grains. As a result of the ongoing urbanization in the region, it is essential to collect additional data from various locations for a longer period of time.

The combined use of nano-TiO₂ with cementitious materials offers an environmentally-friendly way to combat the air pollution problem. However, a trade-off between a high efficiency and a robust weathering resistance has often to be made for most of the attempted nano-TiO₂ incorporation methods. This paper developed a simple and effective “spraying” method to coat nano-TiO₂ particles on the surface of concrete surface layers (CSL). The results showed that the NOₓ removal rate of the samples increased with an increase in both the concentrations of nano-TiO₂ solutions and the number of times of the spraying action. And the conditions for preparation of the Spray AB (the CSL were first sprayed with the 30 g L⁻¹ TiO₂-solution 20 times, followed by mechanical compaction, and for another 20 times after the compaction) were found to be optimal in terms of NOₓ removal performance and weathering resistance. The Spray AB was superior to the 5% TiO₂-intermixed samples with respect to photocatalytic NOₓ removal ability. Compared with TiO₂-dip-coated samples, the Spray AB samples had better and robust weathering resistance. A case study on the factory-fabricated green Eco-blocks (produced by the laboratory-developed spray method and the conventional intermix method) was performed. Examination and comparison on their respective photocatalytic NOₓ removal further verified the advantages of the spray method over the intermix method.

Freshwater salinization is a rapidly emerging ecological issue and is correlated with significant declines in aquatic biodiversity. It remains unclear how changing salinity regimes affect the physiology of sensitive aquatic insects. We used the parthenogenetic mayfly, Neocloeon triangulifer, to ask how ionic exposure history alters physiological processes and responses to subsequent major ion exposures. Using radiotracers (²²Na, ³⁵SO₄, and ⁴⁵Ca), we observed that mayflies chronically reared in elevated sodium or sulfate (157 mg L⁻¹ Na or 667 mg L⁻¹ SO₄) had 2-fold (p < 0.0001) and 8-fold (p < 0.0001) lower ion uptake rates than mayflies reared in dilute control water (16 mg L⁻¹ Na and 23 mg L⁻¹ SO₄) and subsequently transferred to elevated salinities, respectively. These acclimatory ion transport changes provided protection in 96-h toxicity bioassays for sodium, but not sulfate. Interestingly, calcium uptake was uniformly much lower and minimally influenced by exposure history, but was poorly tolerated in the toxicity bioassays. With qRT-PCR, we observed that the expression of many ion transporter genes in mayflies was influenced by elevated salinity in an ion-specific manner (general upregulation in response to sulfate, downregulation in response to calcium). Elevated sodium exposure had minimal influence on the same genes. Finally, we provide novel light microscopic evidence of histomorphological changes within the epithelium of the Malpighian tubules (insect primary excretory system) that undergoes cellular degeneration and necrosis secondary to calcium toxicity. We conclude that physiological plasticity to salinity stress is ion-specific and provide evidence for ion-specific toxicity mechanisms in N. triangulifer.

Hydrochar (HC) serves as a promising adsorbent to remove the cadmium from aqueous solution due to porous structure. The chemical aging method is an efficient and easy-operated approach to improve the adsorption capacity of HC. In this study, four chemical aging hydrochars (CAHCs) were obtained by using nitric acid (HNO₃) with mass fractions of 5% (N5-HC), 10% (N10-HC), and 15% (N15-HC) to age the pristine HC (N0-HC) and remove the Cd²⁺ from the aqueous solution. The results displayed that the N15-HC adsorption capacity was 19.99 mg g⁻¹ (initial Cd²⁺ concentration was 50 mg L⁻¹), which increased by 7.4 folds compared to N0-HC. After chemical aging, the specific surface area and oxygen-containing functional groups of CAHCs were increased, which contributed to combination with Cd²⁺ by physical adsorption and surface complexation. Moreover, ion exchange also occurred during the adsorption process of Cd²⁺. These findings have important implications for wastewater treatment to transform the forestry waste into a valuable adsorbent for Cd²⁺ removal from water.