A scheme of selective removal of metal ions from chromium-containing synthetic solutions with the following chemical composition, Cr (VI)-Fe (III), Cr (VI)-Fe (III)-Ni (II), Cr (VI)-Fe (III)-Ni (II)-Zn (II), and Cr (VI)-Fe (III)-Ni (II)-Zn (II)-Cu (II)) by Shewanella xiamenensis biofilm immobilized on a zeolite support, was proposed. Three biological processes, biosorption, bioaccumulation, and longtime bioreduction, were applied for metal removal. The process of Zn (II), Ni (II), and Cu (II) showed to be pH dependent. The maximum removal of Ni (II) was achieved during a 1-hour biosorption process at pH 5.0–6.0, of Zn (II) at pH 5.0, and of Cu (II) at pH 3.0. Chromium (VI) and Fe (III) ions were more efficiently removed by bioaccumulation. Chromium (VI) removal in the studied systems varied from 16.4% to 34.8 and of iron from 55.8 to 94.6%. In a long-term bioreduction experiment, it was possible to achieve complete reduction of Cr (VI) to Cr (III) ions by Shewanella xiamenensis in 42 days and by Shewanella xiamenensis biofilm on zeolite in 35 days. Shewanella oneidensis can be effectively used to remove metal ions from chemically complex effluents.

Swine farms are one of the important sources of antibiotics in the environment. In this study, 42 samples of compound feed and feces of swine collected at different growth stages from intensive farms were evaluated for the occurrence and concentrations of three tetracyclines (TCs, namely oxytetracycline, chlortetracycline, and doxycycline) and three sulfonamides (SAs, namely sulfadiazine, sulfadimidine, and sulfamethoxazole). To check for other additional sources of antibiotic administration, ratios (R) of the measured and the predicted levels of each antibiotic excreted via feces were also estimated. Our results showed that the maximum concentration of TCs was 376,210 μg kg⁻¹ and 541,020 μg kg⁻¹ in the feeds and feces, respectively, both for oxytetracycline. In contrast, the highest concentration of SAs were 16.98 μg kg⁻¹ for sulfadimidine in the feeds and 14.70 μg kg⁻¹ for sulfadiazine in the feces. The concentrations of ΣTCs (sum of the three tetracyclines) in swine feeds and feces were found to be 1–4 orders of magnitude higher than those of ΣSAs (sum of the three sulfonamides). Approximately 36% of the R values were found to be greater than one, indicating other sources of administration such as injection and/or oral administration (via drinking water) may also contribute to the presence of antibiotics in feces. Most of the higher R values were found in starter pigs, which were generally administrated with antibiotics by multiple routes to prevent disease and promote swine growth. Our study suggests that comprehensive measures may be undertaken to control antibiotic use in intensive swine farms.

In this study, the toxic effects of potassium bromate (KBrO₃) were tested on Allium cepa L. meristematic cells. In order to determine the toxic effect and dose relationship, KBrO₃ toxicity was investigated at doses of 25, 50, and 100 mg/L. The toxic effects were evaluated by using cytogenetic, biochemical, anatomical, and physiological parameters, and serious damages were observed depending on the dose. Significant reductions in germination percentage, weight gain, and radicle length were observed in all KBrO₃-treated groups compared with the control. Mitotic activity decreased in meristematic cells after KBrO₃ application. and mitotic index was decreased by 1.8 times in 100 mg/L KBrO₃-treated group compared with the control group. The frequencies of micronucleus and chromosomal abnormalities tested as cytogenetic parameters were significantly higher in the group treated with 100 mg/L KBrO₃ than those in the control group. Fragment and sticky chromosome were the most common types of chromosomal abnormalities. Lipid peroxidation measured in terms of MDA content increased with increasing doses of KBrO₃. The activities of catalase and superoxide dismutase as antioxidant enzymes were importantly changed in KBrO₃-treated groups. Anatomical changes such as cell deformation, substance accumulation, cell wall thickening, and flattened nucleus were determined after KBrO₃ application, and it was observed that these changes reached a maximum level at 100 mg/L dose of KBrO₃. As a result, KBrO₃ treatments were been found to cause physiological, biochemical, cytogenetic, and anatomically toxic effects in meristematic cells of A. cepa, a eukaryotic model organism. The versatile toxicity induced by KBrO₃ increased depending on the dose and reached a maximum level at 100 mg/L.

The presence of nanoplastics (NPs) in various products and from the weathering of released plastic materials are of concern for the environment’s safety. The purpose of this study was to examine the biophysical effects of polystyrene NPs on freshwater mussels. Mussels were exposed to a range of concentrations of NPs (0.1, 0.5, 1, and 5 mg/L) for 24 h and allowed to depurate for 12 h in clean aquarium water. The digestive gland was isolated and analyzed for NPs, lipids, viscosity, protein aggregation, anisotropic changes (liquid crystals: LCs), and the oscillatory modulation in viscosity during the formation of self-organizing enzyme complex of fumarase, malate dehydrogenase, and citrate synthase. The results revealed that mussels accumulated NPs in the digestive gland and their levels were significantly correlated with lipids levels, LCs, the increase in the malate dehydrogenase/citrate synthase activity ratio, and oscillations in viscosity. Protein aggregation was also found to be correlated with lipid levels. The data suggests that the presence of NPs in the digestive gland involves changes in lipid content and LC formation and perturbs the normal oscillations in viscosity during sequential enzyme reactions of the above enzymes. It is concluded that the uptake of NPs in cells could disrupt the internal organization of cells which can interfere with the normal association of enzymes involved in energy metabolism.

In this work, we used TiO₂ nanobelts and P25 particles as titanium sources to combine with β-Bi₂O₃ to form β-Bi₂O₃/TiO₂ and β-Bi₂O₃/P25 composites. The prepared samples were characterized by X-ray diffraction analysis (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), infrared spectroscopy (IR), X-ray photoelectron spectroscopy (XPS), and UV-vis absorbance spectroscopy and fluorescence spectroscopy. The structure and performance of two composites were comparatively investigated, and the β-Bi₂O₃ molar ratios in them were optimized and their roles in them were studied. The results showed that the TiO₂ nanobelts and commercial TiO₂ (P25) particles combined with β-Bi₂O₃ nanosheets. The optimal molar ratios of Bi to Ti element in two kinds of composites are 1:1. The β-Bi₂O₃ in P25/β-Bi₂O₃ makes more contribution to the improvement of photocatalytic activity of them than that in β-Bi₂O₃/TiO₂ because P25 particles are distributed on β-Bi₂O₃ nanosheet more uniformly. The photocatalytic activities of β-Bi₂O₃/TiO₂ (0.02275 min⁻¹) and β-Bi₂O₃/P25 (0.02382 min⁻¹) are 3.72 times and 3.90 times than that of pure β-Bi₂O₃ (0.0061 min⁻¹) for EE2 removal. The enhanced photocatalytic activities of two kinds of composites are ascribed to photo-induced interfacial charge transfer on the heterojunction between β-Bi₂O₃ and TiO₂ or P25. From the economic view, β-Bi₂O₃/P25 composites are better than β-Bi₂O₃/TiO₂ because TiO₂ nanobelts in the β-Bi₂O₃/TiO₂ composite are obtained from P25 via extra hydrothermal treatment in strong alkaline environment. The free radical capture experiment indicated that the dominant reactive species are h⁺ and •O⁻₂ for EE2 removal by TiO₂/β-Bi₂O₃ and P25/β-Bi₂O₃ composites.

Heavy metals (Sc, Cr, Co, Ni, Cu, Ga, Ge, Nb, Mo, Cd, In, Hf, Ta, W, Tl, Pb, Bi, Th, and U) in the surface sediments of the Ganges-Brahmaputra-Meghna (GBM) river system of the Bengal Basin (BB) were measured to evaluate the heavy metal contamination and anthropogenic influence. The average concentration levels of most of the heavy metals (except Mo and Tl) were above the average crustal and shale values. Contamination indices, including the contamination factor, pollution load index, enrichment factor, and geo-accumulation index, and multivariate statistical analyses indicated that the GBM is slightly polluted by heavy metals with some considerable pollution from Bi, Th, Ta, Cd, Nb, Pb, In, and U. Among the four individual rivers, the Brahmaputra River and Ganges-Brahmaputra (GB) confluence river sediments contain higher heavy metal concentrations than do the Ganges and Meghna Rivers, which may be caused by the effects of local municipal discharge, industrial or urban wastes, and ferry crossing activities.

Optimal stockpiling is the best possible strategy to overcome the problem of peak oil periods of oil producer economies. We measured the properties of strategic petroleum oil reserve and general equilibrium and its peak oil effects. Measured the optimized scales of SPR through using oil price model, global oil market, and depletion effects of oil production classification. The peak oil period occurs from the interection between the geological era, proficiency in a practical skill, economy of consumers, and geopolitics, and the quality of deciding of demand and supply in which we have done a general dynamic balance model. Results reveal that peak oil time periods may lead towards diverse oil prices time profiles, economic development, and commodity flows. Interestingly, the macroeconomic effects of peak oil and the trajectories in objective function of two options maximize the households’ welfare and oil revenues and its effect on growth trajectories of oil-consuming countries. If an oil supply disruption happens, the rate of oil acquisition will be considerably decreased, though it may not be a good strategy to interrupt the activities of oil reserve with the aim of minimizing the overall costs.

Malachite green (MG) is a triphenylmethane dye that is widely used in aquaculture as a fungicide, bactericide, ectoparasiticide, and antiprotozoal. There is great debate regarding the potential for this compound to trigger adverse effects. Here, we review the previous findings and then evaluate the lethal and sublethal effects of MG in the species Hemichromis bimaculatus (jewelfish). The lethal concentration for 50% of the fish in 96 h was 1 mg/L. We observed a dose-dependent increase in the percentage of fish mortality as well as physical and behavioral changes. We further found that the highest tested sublethal dose significantly increased the DNA damage index identified using the comet assay (74.97 ± 13.8 at a significant level of P < 0.05 for the 0.75 mg/L concentration), but did not significantly alter the results of the micronucleus test. Although our results suggest that MG confers risks on exposed fish, the findings were significant only at the highest exposure concentration (0.75 mg/L). At lower concentrations (0.25 mg/L and 0.5 mg/L), no adverse effect was observed. The maximum MG concentration recommended for use in ornamental fish farming is 0.2 mg/L. Therefore, our results suggest that, specifically for the parameters analyzed in this work, MG does not have any adverse effect when users strictly adhere to the recommended concentration criteria for ornamental fish.

Mesoporous silica (MCM-48) was synthesized and used as a catalyst for supporting the nickel oxide photocatalyst. The loading of nickel oxide on MCM-48 results in a considerable reduction in the bandgap energy to 2.4 eV. MCM-48 was used as a catalyst and back-supporter for the nickel oxide to enhance its photocatalytic properties along with adsorption capacity. Therefore, the adsorption capacity of MCM-48/Ni₂O₃ was enhanced by 17.5% and 32.2% compared to Ni₂O₃ and MCM-48, respectively. Furthermore, the percentage of photocatalytic degradation was improved by approximately 68.2% relative to the free-standing Ni₂O₃. The MCM-48/Ni₂O₃ proved the chemisorption adsorption mechanism that happens in multilayer form through the heterogeneous surface. This through fixing such Ni₂O₃ particles over the nanoporous topography to provide more exposed hot adsorption and photocatalytic sites for the incident light photons. Therefore, supporting Ni₂O₃ catalytic particles onto MCM-48 produces a new category of photocatalytic systems with promising active centers for the efficient degradation of Congo red dye molecules.

We investigated the growth and physiological responses of the submerged aquatic plant species Vallisneria natans (Lour.) Hara to 80 mg L⁻¹ manganese (Mn) with different doses of ascorbic acid (AsA 0, 5, 10, 20, 50, 100, 200 mg L⁻¹) after 21 days of treatment. Mn stress significantly reduced the final leaf number and superoxide dismutase (SOD), catalase (CAT), and ascorbate peroxidase (APX) activities of V. natans, while increased the malondialdehyde (MDA), hydrogen peroxide (H₂O₂) and proline contents, and peroxidase (POD) activity, with no significant differences in plant relative growth rate (RGR) and photosynthetic pigment contents. With increasing doses of AsA supplementation (≤ 50 mg L⁻¹), the MDA content gradually decreased, while the proline, soluble protein, and photosynthetic pigment contents, antioxidase (except POD) activities, and RGR of V. natans increased. AsA levels ≥ 100 mg L⁻¹ exacerbated Mn toxicity in V. natans by significantly reducing the antioxidase activities and photosynthetic pigment contents and even triggering plant lethal effects. These results suggest that the Mn stress induced in this investigation could bring about oxidative stress and influence the growth of V. natans. Moreover, the optimal AsA dose that can alleviate Mn-induced oxidative stress was 41.37–50.25 mg L⁻¹ according to the regression analysis based on plant growth and enzymatic responses.