In this study, we report for the first time a novel type of sorbent that can be used for mercury adsorption from the air-based off-gasses—vermiculite impregnated with alkali polysulfides and thiosulfates. In contrast to other sorbents, vermiculite exhibits superior thermal stability in air and low adsorption capacity for organic vapors. This allows for a more favorable design of the soil remediation unit—direct coupling of thermal desorber with catalytic oxidizer using air as a carrier gas. In the bench-scale test at 180 °C, the sulfur/vermiculite sorbent exhibited significantly higher efficiency for the adsorption of mercury vapor from the off-gasses than the commercial sulfur/activated carbon sorbent at its highest operating temperature (120 °C). The average mercury concentration in the adsorber off-gas decreased from 1.634 mg/m³ for the sulfur/activated carbon to 0.008 mg/m³ achieved with impregnated vermiculite. The total concentration of organic compounds in the soil after thermal desorption was below the detection limit of the employed analytical method.

In freshwater ecosystems, wetlands are generally distinguished from deep-water ecosystems by 2-m water level as boundary. However, the difference of sediment microbial communities between wetlands and deep-water ecosystems is still unclear. We combined 16S rRNA gene sequencing and community metabolic prediction to compare sediment microbial communities and predicted metabolic genes of wetlands (natural and constructed wetlands) and deep-water ecosystems (river and lake) along with environmental factors in summer and autumn in Dongping Lake Basin. Results showed that the deep-water ecosystems had significantly higher community richness than the wetlands in autumn in the freshwater basin, which was mostly related to the pH of sediments. However, no significant difference in community richness was found in summer. Besides, the composition of both predicted metabolic genes and microbial communities was significantly affected by dissolved organic carbon (DOC) and dissolved oxygen (DO). The wetlands exhibited high predicted gene abundances related to xenobiotic biodegradation possibly due to the high DOC or DO level. Compared with the wetlands, most of the deep-water ecosystems exhibited high predicted gene abundances related to element (carbon, nitrogen, and sulfur) metabolism possibly due to the low DOC and DO levels in the freshwater basin. This study can expand the knowledge of ecological function distribution and detoxification mechanism of microbial communities in freshwater ecosystems.

Effective identification of the risks of grassland circulation is an important prerequisite for improving the management of the grassland rental market. In this study, the potential risks in the game among the subjects of grassland transfer are analyzed through the lens of repeated game theory. With the help of interpretive structural modeling, we analyze the relationships and hierarchy among the risk factors in grassland circulation. We find that social, economic, and ecological risks are the main potential risks of grassland circulation, and there are strong correlations among risk factors. A risk hierarchy analysis shows that social risk is at the upper level, economic risk is at the middle level, ecological risk is at the bottom level, and there are cross-layer effects among the various risk levels. Contract risk, social security risk, and wealth gap risk are the core risk factors that trigger the risks associated with grassland transfer. Therefore, the first priority of the pasture manager (i.e., the government) should be to regulate the grassland circulation market and strengthen supervision and punishment of defaulting subjects. Second, a social security system in which the herdsmen and the government are both invested should be established. Third, the government should strengthen the construction of a “rule of law” system instead of “rule of man,” to avoid the loss of government credibility caused by rent-seeking.

Water supplies in coastal aquifers throughout the world are often threatened by salinization due to seawater intrusion and anthropogenic activities. In the Kalpitiya Peninsula in Sri Lanka, agricultural and domestic water supplies entirely depend on groundwater resources extracted from unconfined Holocene sandy aquifers. To differentiate the effects of seawater intrusion and agriculture on the coastal aquifers of this 160 km² peninsula, 43 groundwater samples were collected. These samples were analyzed for major ions, trace elements, and stable isotopes of water (δ¹⁸O and δ²H). The solute compositions were dominated by Cl⁻, [Formula: see text], and [Formula: see text], which were mostly balanced by Ca²⁺, Na⁺, and Mg²⁺. Among the four main water types, Na⁺-Cl⁻ and Ca²⁺-[Formula: see text] classifications were predominant in the investigated aquifers. Modifications of the groundwater due to evaporation during irrigation activities, but also due to seawater intrusion seem most plausible as indicated by the correlation of δ¹⁸O with δ²H (δ²H = 5.51 * δ¹⁸O-3.08, r = 0.93) deviating from the local meteoric water line. Particularly in the southern part of the peninsula, Mg²⁺/Ca²⁺ ratios and stable isotopes of water attributed salinization of groundwater to agricultural activities. However, especially in the north, seawater intrusions were also evident. Established mass balance calculations revealed that local groundwater had seawater admixtures of up to 12%. Our results indicate that integrated water management is essential and water resources should critically monitor in the Kalpitiya Peninsula in order to avoid over-exploitation and further seawater inflows.

Investigation of probable toxic effects of acetamiprid (ACMP) on kidney and comparative analysis of the probable protective effects of vitamin E and melatonin were conducted in the present study. The ethics committee approval was obtained from Inonu University Medical Faculty Ethics Committee. Fifty Balb-c mice were randomly assigned to control, corn oil, ethyl alcohol, ACMP, ACMP + melatonin, ACMP + vitamin E, and ACMP + melatonin + vitamin E groups. At the end of the experiments, rat kidney tissues were incised under anesthesia. Blood samples and kidney tissues were examined. After 21 days of ACMP administration, it was observed that malondialdehyde (MDA), total oxidant status (TOS), BUN, creatinine, IL-6, IL-1β, and TNF-α levels, histopathological damage, and Caspase-3 immunoreactivity scores increased, and glutathione (GSH), superoxide dismutase (SOD), catalase (CAT), and total antioxidant status (TAS) levels decreased, and histopathological damages were observed. Melatonin and vitamin E administration led to improvements in oxidative stress parameters, renal functions, inflammatory markers, and histopathological findings. ACMP administration led to nephrotoxicity in rat kidney tissues. Although melatonin and vitamin E administrations were effective on ACMP nephrotoxicity separately, co-administration of both was quite effective. Concomitant use of melatonin and vitamin E could be effective on prevention of toxicity.

The occurrence of nanoplastic particles (NPs) in the environment has raised concerns about the ecotoxicological risk to aquatic ecosystems. The purpose of this study was to examine the bioavailability and toxicity of 50- and 100-nm transparent polystyrene NPs to the cnidarian Hydra attenuata. The hydras were exposed to increasing concentrations of 50- and 100-nm NPs (1.25, 2.5, 5, 10, 20, 40, and 80 mg/L) for 96 h at 20 °C followed by a 24-h depuration step. Hydras were analyzed for morphological changes, bioaccumulation of NPs using a novel assay for polystyrene NPs, oxidative stress (lipid peroxidation), polar lipids, lipid-like liquid crystals (LCs), and viscosity changes in the post-mitochondrial fraction. The results revealed that the organisms accumulated detectable amounts of NP in a concentration-dependent manner for both the 50- and 100-nm NP that persisted after 24 h in clean media. Changes in morphology were observed with a 50% effect concentration of 3.6 and 18 mg/L for the 50- and 100-nm-diameter NPs respectively. However, based on the particle concentration, the 100 nm proved to be 1.7 times more toxic than the 50-nm NPs. Exposure to NPs led to decreased biomass, lipid peroxidation (LPO), increased polar lipid levels, viscosity, and formation of LCs at the intracellular level. In the more toxic NP (100 nm), NPs in tissues were correlated with LCs, polar lipids, and LPO levels. It appears that the formation of organized LCs and polar lipids of NPs in cells was involved with NP toxicity and could represent a yet unidentified, detoxifying/bioactivation mechanism against colloidal plastics in cells. In conclusion, NPs are bioavailable to hydra and lead to LPO and lipid mobilization in hydra. The capacity of increasing lipid mobilization and LCs could determine the size-dependence toxicity of NPs.

Multivariate statistical techniques and geostatistical methods are among the important tools used in surface water quality management. They are widely used in interpreting data, identifying the pollution sources, understanding the spatial variation of parameters, and determining the places of monitoring stations. Therefore, in this study, spatial variation of water quality and pollutants in the Anzali Wetland water (Iran) was evaluated using multivariate statistical and Kriging methods. The values of different water quality parameters measured in six stations in the wetland water were subjected to cluster analysis (CA) and principal component analysis (PCA). Cluster analysis reduced the number of stations from six to four. The results of PCA showed that industrial and agricultural pollution sources could be responsible for the Anzali Wetland water quality. Then, the spatial variation maps of the PCA scores were generated using Kriging geostatistical method in the geographical information system (GIS) to investigate the pollution sources affecting the wetland parts. These maps illustrated that a great part of the wetland body was under the effect of agricultural sources, while the industrial sources affected the outlet and central parts. Finally, a comparison between two models (multiple linear regression (MLR) and Kriging) was made to assess their ability in predicting water quality parameters in the study area. The results showed the improvement of prediction using MLR, which was by 25%–97%, compared with Kriging. The results of the present study can be effectively used in the planning and implementation of future monitoring networks in the Anzali Wetland and other similar aquatic systems.

Because of their direct contact with society, urban buses are prioritized targets for air quality improvement. In this study, a sample group of in-use urban old buses powered by compressed natural gas (CNG) and diesel engines was chosen for particle emission analysis. The CNG buses do not have any type of after-treatment, while diesel ones are equipped with a diesel particulate filter (DPF). To measure the lung deposited surface area (LDSA), a possible physical metric of exhaust particles’ toxicity, a diffusion charger-based analyzer was utilized. The measurements were done at different engine speeds in stationary conditions. The results revealed that although the particle mass emission of CNG buses remains at a low level, the number of emitted particles for 75% of the CNG buses (depending on their maintenance conditions) is 10 to 100 times more than the retrofitted diesel ones, with the range of 10⁶ to 10⁷ p/cm³. The rest 25% of the CNG buses were performing the same as the retrofitted diesel ones in terms of exhaust particle number in the range of 10⁵ p/cm³. In addition, the lowest LDSA parameter at low idle engine speed was measured to be 97.8 and 229.4 μm²/cm³ for a CNG and a DPF retrofitted diesel bus, respectively. This result indicates the same and even lower LDSA and surface area and thus the lower possible toxic potentiality of exhaust particles of CNG buses compared to diesel vehicles at DPF downstream. Investigation on the different behavior of the CNG buses in the emission of particles showed the correlation of some aging parameters such as lubricant oil aging mileage with the released particles and the importance of periodic maintenance interval. Graphical abstract

The emission of carbon dioxide (CO₂) is a serious environmental issue, especially in Beijing-Tianjin-Hebei region. Unlike previous studies that mainly consider the bilateral and direct connection between two sectors, this study identifies path-based key sectors by considering the cascading effect of a sector on other sectors on paths of the entire economic system. We first construct an embodied CO₂ emission flow network of Beijing-Tianjin-Hebei region, combining environmental input-output analysis and complex network theory. Then, the path-based key sectors are identified by traversing the path of each sector in the network based on cascading failure theory and hypothesis extraction method. On the one hand, the results show that a small number of sectors shoulder a large proportion of the embodied CO₂ emission flows from both path and sector perspectives. On the other hand, we identify some path-based key sectors that did not receive enough attention from the sector perspective. Additionally, the sum of the embodied CO₂ emission flows in about 30 steps accounts for 90% of the total embodied CO₂ emission flows on its supply chain path. To more effectively reduce carbon emission, sectors that connect these 30 steps should be concerned in some policy recommendations. The method proposed in this paper can complement existing methods and contribute to further reducing CO₂ emissions in the Beijing-Tianjin-Hebei region.

Acid pretreated biomass Lemna minor (BM-H₃PO₄) was used as support for CuO nanoparticles loading, to investigate the dye biosorption capacity and the photocatalytic performance under artificial visible light. The surface morphology, crystal structure, elemental composition, and the bandgap of modified biomass have been determined using FE-SEM, XRD, EDX, XPS, FTIR, and UV-DR analysis. The results showed that NH₂ and P-O functional groups of (BM-H₃PO₄) can attract the copper ions (Cu²⁺), which can facilitate the loading of CuO nanoparticles hence, smaller nanoparticles with an average diameter of 21 nm was obtained. It was also found that when the CuO was incorporated in BM-H₃PO₄ in a proper mass ratio of 0.4, the biosorption efficiency was enhanced to 3 times compared with BM-H₃PO₄ and reached a maximum of 91%, at a dye concentration of 20 mg/L, solution pH equal to 5, and an ambient temperature of 25 °C. Furthermore, CuO-modified BM-H₃PO₄ exhibits a better photocatalytic activity than pure CuO in the presence of H₂O₂ and visible light irradiation, where the dye was completely removed and mineralized after 240 min, evidenced by COD measurement. The photocatalytic regeneration also shows that the biosorption efficiency was maintained at 91% over 3 cycles, indicating the significant self-regenerative capacity of the biosorbent.