The fluorescence EEM technique, PARAFAC modeling, and hydrocarbon composition were used to characterize oil components and to examine the chemical evolution and degradation pathways of Macondo crude oil under controlled laboratory conditions. Three major fluorescent oil components were identified, with Ex/Em maxima at 226/328, 262/315, and 244/366nm, respectively. An average degradation half-life of ∼20d was determined for the oil components based on fluorescence EEM and hydrocarbon composition measurements, showing a dynamic chemical evolution and transformation of the oil during degradation. Dispersants appeared to change the chemical characteristics of oil, to shift the fluorescence EEM spectra, and to enhance the degradation of low-molecular-weight hydrocarbons. Photochemical degradation played a dominant role in the transformation of oil components, likely an effective degradation pathway of oil in the water column. Results from laboratory experiments should facilitate the interpretation of field-data and provide insights for understanding the fate and transport of oil components in the Gulf of Mexico.

Microorganisms have developed copper-resistance mechanisms in order to survive in contaminated environments. The abundance of the copper-resistance genes cusA and copA, encoding respectively for a Resistance Cell Nodulation protein and for a P-type ATP-ase pump, was assessed in copper and non-copper-impacted Chilean marine sediment cores by the use of molecular tools. We demonstrated that number of copA and cusA genes per bacterial cell was higher in the contaminated sediment, and that copA gene was more abundant than cusA gene in the impacted sediment. The molecular phylogeny of the two copper-resistance genes was studied and reveals an impact of copper on the genetic composition of copA and cusA genes.

Franciscana dolphin is an endemic cetacean in the southwestern Atlantic Ocean and is classified as Vulnerable A3d by the International Union for Conservation of Nature. Cadmium accumulation was assessed in two geographic groups from Argentina; one inhabits the La Plata River estuary, a high anthropogenic impacted environment, and the other is distributed in marine coastal, with negligible pollution. Despite the environment, marine dolphins showed an increase of renal Cd concentrations since trophic independence; while in estuarine dolphins was from 6years. This is associated with dietary Argentine anchovy which was absent in the diet of estuarine dolphins, being a trophic vector of cadmium in shelf waters of Argentina. Cluster analysis also showed high levels of cd in association with the presence of anchovy in the stomach. The difference in the fine scale distribution of species influences dietary exposure to Cd and, along with other data, indicates two stocks in Argentina.

Breakwaters are widely used in coastal development. Breakwaters can alter habitats by undermining shallow coastal ecosystems, especially coral reefs. However, recent studies indicate that mature breakwaters can have well-developed corals and coral-associated fishes. Breakwaters with colonized corals may act as surrogates of natural coral reefs against the global coral crisis. Here, we examined the composition of corals, fishes, and benthic biota/abiota between natural reefs and mature breakwaters to evaluate the possibility of breakwaters supplementing natural reefs. We found equal or higher coral cover, fish abundance, and species richness on breakwaters. Conversely, differential coral growth forms and fish assemblages on mature breakwaters suggested the irreplaceability of natural reefs. Corals and coral reef fishes on mature man-made structures, however, may improve the resistance and resilience of coral reefs. Conclusively, despite high coral cover on mature man-made structures appropriate management (e.g., marine reserves) is still necessary to sustain the coral reefs.

Three optimization methods are employed to allocate Marine Environmental Carrying Capacity (MECC) in the Xiamen Bay. The hydrodynamic and pollutant fields are first simulated by the Princeton Ocean Model. Taking phosphorus as an index of the water quality, the response fields are then calculated. These response fields represent the relationship between the concentration of the sea zone and the pollution sources. Finally, MECC is optimized and distributed in the Xiamen Bay by three optimization methods. The results show classical linear optimization can only maximize the satisfaction level for one of the stake holders’, e.g., dischargers or environmental protection bureau, satisfaction level. However, the fuzzy and grey fuzzy optimizations can provide a compromise, and therefore a fairer result, by incorporating the conflicting goals of all of the different stakeholders. Compared with fuzzy optimization, the grey fuzzy optimization provides a more flexible choice for the decision-makers.

EU ocean policies increasingly incorporate regional measures. Under the long standing Common Fisheries Policy, such measures aim at improving and reforming existing policy, either by taking into account region specific social or ecologic requirements or by establishing procedures and institutions to achieve a regional fit. By contrast, the EU’s emerging integrated Marine Environmental Policy was designed to draw heavily on regional procedural and institutional mechanisms from the outset. The developing regional measures raise the question whether they contribute to improving institutional structures governing the use and conservation of EU waters. This article analyzes the existing and future regional measures of the two policies and their varying purposes and scopes. It develops a typology for categorizing the regional aspects and examines the effects of regional measures on EU institutions and the theoretical EU integration debate.

This study investigated polycyclic aromatic hydrocarbons (PAHs) pollution in surface sediments within aquaculture areas in Peninsular Malaysia using chemometric techniques, forensics and univariate methods. The samples were analysed using soxhlet extraction, silica gel column clean-up and gas chromatography mass spectrometry. The total PAH concentrations ranged from 20 to 1841ng/g with a mean of 363ng/gdw. The application of chemometric techniques enabled clustering and discrimination of the aquaculture sediments into four groups according to the contamination levels. A combination of chemometric and molecular indices was used to identify the sources of PAHs, which could be attributed to vehicle emissions, oil combustion and biomass combustion. Source apportionment using absolute principle component scores–multiple linear regression showed that the main sources of PAHs are vehicle emissions 54%, oil 37% and biomass combustion 9%. Land-based pollution from vehicle emissions is the predominant contributor of PAHs in the aquaculture sediments of Peninsular Malaysia.

Fine particulate matter (PM2.5) composition data from the Speciation Trends Network (STN) site in San Jose, CA, were analyzed by positive matrix factorization (PMF) using U.S. Environmental Protection Agency (EPA) PMF version 5.0. These data were 24–h average mass concentrations and compositions obtained from samples taken every third day from October 2002 to February 2012. The eight identified sources include secondary sulfate, secondary nitrate, fresh sea salt, aged sea salt, diesel emission, road salt, gasoline vehicles, and wood combustion. The contributions to PM2.5 of these eight sources were 13.1%, 20.0%, 5.5%, 7.8%, 9.4%, 5.1%, 14.8, and 24.3%, respectively. The Ni–related industrial source, which was detected in previous PMF analysis, was not identified in our study and a sharp decrease in Ni concentrations was observed after the end of 2004. The contribution of road dust source decreased significantly after 2004 (Mann–Whitney test, p<0.01), which is probably the result of the city wide enhanced street sweeping programs starting in 2005. A 40% reduction in the wood combustion PM2.5 contribution between winter 2008 and winter 2009 was found. This decrease could be attributed to the San Francisco Bay Area Air Quality Management District (BAAQMD) wood burning rule implemented in July 2008. In the future, the effectiveness and benefits of the wood burning rule could be evaluated using the multi–wavelength aethalometer delta–c method.

Based on an understanding of energy, empirical formulas of hourly PAR (photosynthetically active radiation) under all sky conditions in North China were introduced and applied. An interesting and important phenomenon of the absorption of “water vapor factor” in 400–700 nm was studied and its real mechanism can be explained by the energy consumption of the substances (gas, liquid, solid–phase) through OH radicals during chemical and photochemical reactions. The PAR at the top of the atmosphere was estimated with good agreement. PAR losses in the atmosphere associated with “photochemical factor” and other materials in North China are spatial and seasonal dependence; their “annual” averages were 15.33 and 309.30 W m–2 in North China, respectively. The energy loss related to the “photochemical factor” should be considered in all kinds of basic processes in the atmosphere and model studies, including radiation transmission, photochemistry, air motion, and climate.

Particulate matter (PM) in Masterton, New Zealand, a rural community with a population of 20 000, was studied during the winter to gain an understanding of the carbonaceous species and their influence on PM concentrations. The average PM10 concentration during the winter was 21.0±14.8 µg m–3, of which 64% was PM2.5. PM2.5 concentrations were found to be the main cause of elevated PM10 concentrations, and were responsible for exceedances of the New Zealand National Environmental Standard for PM10. Carbonaceous species were 47 and 77% of the total PM10 and PM2.5, respectively. Organic carbon (OC) concentrations were always higher than elemental carbon (EC) concentrations. OC and EC concentrations showed excellent correlation with PM2.5 concentrations, suggesting that combustion processes were the dominant source of PM. Stable isotope analysis yielded δ13C values ranging from –24.9 to –27.6‰, which is indicative of wood combustion. Analysis of particle–phase PAHs by thermal desorption GC/MS yielded an average total PAH concentration of 38.9±25.9ng m–3, accounting for 0.3% of the PM2.5. Analysis of all of the results revealed that residential wood burning for domestic heating was the main source of PM pollution in Masterton. The results of this study suggest that a PM10 standard alone, particularly in areas where wood combustion is common, may not be providing an adequate level of protection for the exposed population.