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Hg bioaccumulation in marine copepods around hydrothermal vents and the adjacent marine environment in northeastern Taiwan
2013
The Hg concentration in seawater and copepod samples collected from the area around hydrothermal vents at Kueishan Island and the adjacent marine environment in northeastern Taiwan were analyzed to study Hg bioaccumulation in copepods living in polluted and clean marine environments. The seawater collected from the hydrothermal vent area had an extremely high concentration of dissolved Hg, 50.6–256ngl−1. There was slightly higher Hg content in the copepods, 0.08–0.88μgg−1. The dissolved Hg concentration in the hydrothermal vent seawater was two to three orders of magnitude higher than that in the adjacent environment. The bioconcentration factor of the studied copepods ranged within 103–106, and showed higher dissolved concentration as the bioconcentration factor was lower. A substantial abundance, but with less copepod diversity was recorded in the seawater around the hydrothermal vent area. Temora turbinata was the species of opportunity under the hydrothermal vent influence.
显示更多 [+] 显示较少 [-]Effects of elevated pCO2 on reproductive properties of the benthic copepod Tigriopus japonicus and gastropod Babylonia japonica
2013
We investigated the effects of elevated pCO2 in seawater both on the acute mortality and the reproductive properties of the benthic copepod Tigriopus japonicus and gastropod Babylonia japonica with the purpose of accumulating basic data for assessing potential environmental impacts of sub-sea geological storage of anthropogenic CO2 in Japan. Acute tests showed that nauplii of T. japonicus have a high tolerance to elevated pCO2 environments. Full life cycle tests on T. japonicus indicated NOEC=5800μatm and LOEC=37,000μatm. Adult B. japonica showed remarkable resistance to elevated pCO2 in the acute tests. Embryonic development of B. japonica showed a NOEC=1500μatm and LOEC=5400μatm. T. japonicus showed high resistance to elevated pCO2 throughout the life cycle and B. japonica are rather sensitive during the veliger stage when they started to form their shells.
显示更多 [+] 显示较少 [-]Anthropogenic marine debris in the coastal environment: A multi-year comparison between coastal waters and local shores
2013
Anthropogenic marine debris (AMD) is frequently studied on sandy beaches and occasionally in coastal waters, but links between these two environments have rarely been studied. High densities of AMD were found in coastal waters and on local shores of a large bay system in northern-central Chile. No seasonal pattern in AMD densities was found, but there was a trend of increasing densities over the entire study period. While plastics and Styrofoam were the most common types of AMD both on shores and in coastal waters, AMD composition differed slightly between the two environments. The results suggest that AMD from coastal waters are deposited on local shores, which over time accumulate all types of AMD. The types and the very low percentages of AMD with epibionts point to mostly local sources. Based on these results, it can be concluded that a reduction of AMD will require local solutions.
显示更多 [+] 显示较少 [-]Chemical fingerprinting of petroleum biomarkers in Deepwater Horizon oil spill samples collected from Alabama shoreline
2013
Mulabagal, V. | Yin, F. | John, G.F. | Hayworth, J.S. | Clement, T.P.
We compare the chromatographic signatures of petroleum biomarkers in Deepwater Horizon (DH) source oil, three other reference crude oils, DH emulsified mousse that arrived on Alabama’s shoreline in June 2010, and seven tar balls collected from Alabama beaches from 2011 to 2012. Characteristic hopane and sterane fingerprints show that all the tar ball samples originated from DH oil. In addition, the diagnostic ratios of various hopanes indicate an excellent match. Quantitation data for C30αβ-hopane concentration levels show that most of the weathering observed in DH-related tar balls found on Alabama’s beaches is likely the result of natural evaporation and dissolution that occurred during transport across the Gulf of Mexico prior to beach deposition. Based on the physical and biomarker characterization data presented in this study we conclude that virtually all fragile, sticky, brownish tar balls currently found on Alabama shoreline originated from the DH oil spill.
显示更多 [+] 显示较少 [-]Effects of varying estuarine conditions on the sorption of phenanthrene to sediment particles of Yangtze Estuary
2013
Shang, Jing | Chen, Jing | Shen, Zhenyao | Wang, Ying | Ruan, Aidong
The sorption of phenanthrene on the Yangtze Estuary sediment was studied under varying conditions of particle size, sediment organic contents, salinity, and dissolved organic matter (DOM) concentrations. Small sediment particles showed higher trapping capacity for phenanthrene due to the higher organic contents associated. The organic carbon-based partition coefficient of phenanthrene to the Yangtze Estuary sediment was obtained as 7120L/kg, lower than the values for other soils or sediments reported in previous studies. The magnitude and direction of the salt effect were complicated by the specific DOM studied. The sediment sorption capacity was greatly increased in saline water in the absence of DOM but decreased in the presence of DOM. Given the conditions in the Yangtze Estuary, the equilibrium sorption of phenanthrene would be decreased with increasing salinity. Overall, the nature and content of both sediment-bound and dissolved organic matter dominate the sorption of hydrophobic organic contaminants in the estuary.
显示更多 [+] 显示较少 [-]Inhibition of larval swimming activity of the coral (Platygyra acuta) by interactive thermal and chemical stresses
2013
This study examined the interactive effects of copper and elevated temperature and subsequent depuration on Platygyra acuta coral larvae. Larval mortality and motility were significantly affected by copper alone (70% and 100% inhibition respectively). Their respective lethal/inhibitory concentration (LC50/IC50) were 10–130% and 86–193% higher than those reported for other larvae. Temperature (ambient, 27°C and elevated, 30°C) alone and the combination of temperature and copper did not significantly affect both endpoints. This study provides the first quantitative data on depuration effect on resumption of larval motility after copper exposure, although no sign of larval recovery was observed. These findings suggest that the effects of copper pollution outweigh the thermal tolerance of coral larvae. High LC50 and IC50 recorded may be unique for corals from marginal reefs like Hong Kong which have already been exposed to high levels of copper pollution.
显示更多 [+] 显示较少 [-]Temporal evolution of lead isotope ratios in sediments of the Central Portuguese Margin: A fingerprint of human activities
2013
Stable Pb isotope ratios (206Pb/207Pb, 208Pb/206Pb), 210Pb, Pb, Al, Ca, Fe, Mn and Si concentrations were measured in 7 sediment cores from the west coast of the Iberian Peninsula to assess the Pb contamination throughout the last 200years. Independently of their locations, all cores are characterized by increasing Pb/Al rends not related to grain-size changes. Conversely, decreasing trends of 206Pb/207Pb were found towards the present. This tendency suggest a change in Pb sources reflecting an increased proportion derived from anthropogenic activities. The highest anthropogenic Pb inventories for sediments younger than 1950s were found in the two shallowest cores of Cascais and Lisboa submarine canyons, reflecting the proximity of the Tagus estuary. Lead isotope signatures also help demonstrate that sediments contaminated with Pb are not constrained to estuarine–coastal areas and upper parts of submarine canyons, but are also to transferred to a lesser extent to deeper parts of the Portuguese Margin.
显示更多 [+] 显示较少 [-]A baseline study of tropical coastal water quality in Port Dickson, Strait of Malacca, Malaysia
2013
Praveena, Sarva Mangala | Ahmad Zaharin Aris,
Tidal variation in tropical coastal water plays an important role on physicochemical characteristics and nutrients concentration. Baseline measurements were made for nutrients concentration and physicochemical properties of coastal water, Port Dickson, Malaysia. pH, temperature, oxidation reduction potential, salinity and electrical conductivity have high values at high tides. Principal Components Analysis (PCA) was used to understand spatial variation of nutrients and physicochemical pattern of Port Dickson coastal water at high and low tide. Four principal components of PCA were extracted at low and high tides. Positively loaded nutrients with negative loadings of DO, pH and ORP in PCA outputs indicated nutrients contribution related with pollution sources. This study output will be a baseline frame for future studies in Port Dickson involving water and sediment samples. Water and sediment samples of future monitoring studies in Port Dickson coastal water will help in understanding of coastal water chemistry and pollution sources.
显示更多 [+] 显示较少 [-]Characteristics of visibility and particulate matter (PM) in an urban area of Northeast China
2013
Zhao, Hujia | Che, Huizheng | Zhang, Xiaoye | Ma, Yanjun | Wang, Yangfeng | Wang, Hong | Wang, Yaqiang
The visibility data from 2010 to 2012 were obtained at Shenyang in Northeast China and the relations between visibility, PM mass concentration and meteorological variables were statistically analyzed. These results demonstrate that the monthly–averaged visibility over Shenyang was higher in March and September with values of approximately 19.0±4.3 km and 17.1±4.3 km, respectively. Low visibility over Shenyang occurred in January at approximately 11.0±4.7 km. Among the meteorological variables considered, wind speed was the main meteorological factor that influenced visibility and PM mass concentrations. The relation between visibility and PM indicates that fine particles are already a main source of pollutants, the existence of which is the most important factor in the deterioration of visibility in an urban area of Northeast China. The study also shows an obvious diurnal variation and weekend effects of visibility and PM, which are mainly caused by human activities. Results of this study highlight the significant impact of fine particles on air pollution and visibility in an urban area of Northeast China.
显示更多 [+] 显示较少 [-]Anatomy of a decision: Potential regulatory outcomes from changes to chemistry protocols in the Canadian Disposal at Sea Program
2013
Apitz, Sabine E. | Agius, Suzanne
Environment Canada currently assesses dredged material proposed for disposal at sea using a two-tiered assessment framework. Tier 1 determines sediment geophysical properties and concentrations of four regulated chemical constituents (Cd, Hg, PAH and PCB), and “other chemicals of interest” based on lower action levels; this is followed by biological assessment. EC is pursuing a “data mining” approach to evaluate potential refinements by compiling sediment chemistry and toxicity datasets, and subjecting them to a series of decision protocols. This paper reports on database development and initial use, and recommends potential changes to Tier 1 chemical protocols and further work to address other aspects of the framework. Major findings include the poor performance of Hg and Cd as sentinels for other metals, the significance of the list of analytes (vs. the specific SQGs used) in decisions, and the potential for chemical upper action levels to save the expense of unnecessary toxicity testing.
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