Results from a comprehensive oil weathering and dispersant effectiveness study of the MC252 crude oil have been used to predict changes in oil properties due to weathering on the sea surface and to estimate the effective “time window” for dispersant application under various sea conditions. MC252 oil is a light paraffinic crude oil, for which approximately 55wt.% will evaporate within 3–5days when drifting on the sea. An unstable and low-viscosity water-in-oil (w/o) emulsion are formed during the first few days at the sea surface. This allows a high degree of natural dispersion when exposed to breaking wave conditions. Under calm sea conditions, a more stable and light-brown/orange colored water-in-oil (w/o) emulsion may start to form after several days, and viscosities of 10,000–15,000mPas can be achieved after 1–2weeks. The “time window” for effective use of dispersants was estimated to be more than 1week weathering at sea.

Large-scale algal blooms of the dinoflagellate Prorocentrum donghaiense have occurred frequently in the East China Sea (ECS) in recent decades. However, its impacts on the zooplankton in situ are still under not well understood. During a spring P. donghaiense bloom (April–May 2013) along the northern coast of Fujian Province (120°–121°30″E, 26°30″–28°N), we found that the bloom decreased the abundance of copepods and had no significant effect on chaetognaths and small jellyfish. However, the abundance of small jellyfish increased over the course of the study. The zooplankton community changed from being copepod and small jellyfish- to small jellyfish-dominated during the bloom. In the bloom areas, the copepod Calanus sinicus showed higher mortality and lower egg production rates (EPR) than those in the non-bloom areas. The results suggested that P. donghaiense blooms had detrimental effects on the structure of zooplankton community and the recruitments of C. sinicus.

We determined changes of 28 alkanes and 43 different PAHs in 418 wetland soil samples collected on ten sampling trips to three Louisiana estuaries before and after they were oiled from the 2010 Deepwater Horizon disaster. There was a significant decline in 22 of the 28 alkane analytes (0.42%day−1), no change in 6, over 2.5years. The concentration of five aromatic petroleum hydrocarbons (PAHs) increased (range 0.25–0.70%day−1), whereas the total PAH pool did not change. Of these five, naphthalene and C-1-naphthalenes are suggested to be of higher toxicity than the other three because of their relatively higher volatility or solubility. The relative proportions of alkane analytes, but not PAHs, does not yet resemble that in the pre-oiled marshes after 3years, The trajectories of nine indicators for degradation/weathering were either inconclusive or misleading (alkanes) or confirmed the relatively meager degradation of PAHs.

Atmospheric nucleation is now recognized to be an important source of ambient particles. In this study, ground–based measurements using a tower were used to observe new particle formation in the Morgan Monroe State Forest (MMSF) in Southwestern Indiana in May 2008. Nucleation was observed at MMSF on a number of days through examination of the particle size distributions. Most of these events were nucleation and growth events that are typical of regional nucleation phenomena. The particle size and sulfuric acid concentration data were used to investigate the mechanism for the observed nucleation events. Four of the ten observed nucleation events were clearly the result of activation of pre–existing clusters. The others seem likely to be the result of classical ternary nucleation.

The estimated risks of being impacted by oil spills in the coastal waters were used to improve the oil spill contingency plan of Thailand. Functional roles of local agencies are integrated into the plan. Intensive measures are suggested for the coastal provinces located in high-very high risk zones, whereas light and moderate measures are suggested for the coastal provinces located in low and moderate risk zones, respectively. The estimated percentage risks due to simulated oil slicks hitting the coast and/or important resources (PRoilspill) were used to guide the year-round water activities that should be carefully handled at a certain radius with a low-moderate PRoilspill, whereas they should be avoided at a certain radius with a high-very high PRoilspill. Important measures before, during, and post periods of an oil spill incident are suggested to prevent and monitor oil spill incidents and mitigate their impacts on the environment.

The coral reef ecosystems of Nanwan Bay, Southern Taiwan are undergoing degradation due to anthropogenic impacts, and as such have resulted in a decline in coral cover. As a first step in preventing the continual degradation of these coral reef environments, it is important to understand how changes in water quality affect these ecosystems on a fine-tuned timescale. To this end, a real-time water quality monitoring system was implemented in Nanwan Bay in 2010. We found that natural events, such as cold water intrusion due to upwelling, tended to elicit temporal shifts in coral spawning between 2010 and 2011. In addition, Degree Heating Weeks (DHWs), a commonly utilized predictor of coral bleaching, were 0.92 and 0.59 in summer 2010 and 2011, respectively. Though this quantity of DHW was below the presumed stress-inducing value for these reefs, a rise in DHWs in the future may stress the resident corals.

The present study investigated the concentration, distribution and speciation of metals (Fe, Mn, Cu, Pb, Co, Zn and Cr) in sediments of Mumbai region. Pearson’s correlation matrix and cluster analyses showed good association of metals with grain size and organic matter. Factor analysis applied to the speciation data helped to identify the role of different sediment fractions in metal retention. The environmental risks of metals, evaluated by sediment quality guidelines, revealed some contamination in the region. However, the Individual and Global Contamination Factors and the Risk Assessment Code, suggested low risk to the aquatic environment, except of Mn in the creek sediments.

The present study examined the relationships between soil characteristics, microbial community structure and function in the forests artificially planted with exotic Sonneratia apetala at stand ages of 1-, 2-, 7-, 10- and 14-years and Sonneratia caseolaris of 1-, 4-, 7-, 10- and 14-years in Futian National Nature Reserve, Shenzhen Bay, China. The 7-years old forests of both Sonneratia species reached peak growth and had the highest content of nitrogen and phosphorus, enzymatic activities, including dehydrogenase, cellulase, phosphatase, urease and ß-glucosidase, except arylsulphatase which increased continuously with stand ages. The microbial community structure reflected by phospholipid fatty acid (PLFA) profiles also reached the maximum value in the 7-years old forests and soil bacterial PLFAs in both forests were significantly higher than fungal PLFAs. The canonical correlation analysis revealed that differences in microbial structural variables were significantly correlated to the differences in their functional variables, and the highest correlation was found between the soil enzymatic activities and the content of carbon and nitrogen.

The effects of BDE-47 on the growth and antioxidative responses of the seedlings of Kandelia obovata (Ko) and Avicennia marina (Am) were compared in an 8-week hydroponic culture spiked with different levels of BDE-47, 0.1, 1, 5 and 10mgl−1. The two highest BDE-47 levels significantly suppressed the growth and increased the activities of three antioxidative enzymes, superoxide dismutase (SOD), peroxidase (POD) and catalase (CAT), of Ko in week 1. However, SOD and POD activities at high levels of BDE-47 became lower than the control in week 8. On the contrary, growth of Am was not affected at all contamination levels, and the activities of three enzymes were enhanced by BDE-47 in weeks 1 and 4, but such stimulatory effect became insignificant in week 8. Avicennia was more tolerant to BDE-47 toxicity than Kandelia, as its antioxidative enzymes could better counter-balance the oxidative stress caused by BDE-47.

This study was conducted to determine the composition of surfactants in the sea-surface microlayer (SML) and atmospheric aerosol around the southern region of the Peninsular Malaysia. Surfactants in samples taken from the SML and atmospheric aerosol were determined using a colorimetric method, as either methylene blue active substances (MBAS) or disulphine blue active substances (DBAS). Principal component analysis with multiple linear regressions (PCA–MLR), using the anion and major element composition of the aerosol samples, was used to determine possible sources of surfactants in atmospheric aerosol. The results showed that the concentrations of surfactants in the SML and atmospheric aerosol were dominated by anionic surfactants and that surfactants in aerosol were not directly correlated (p>0.05) with surfactants in the SML. Further PCA–MLR from anion and major element concentrations showed that combustion of fossil fuel and sea spray were the major contributors to surfactants in aerosol in the study area.