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Determination of organohalogenated contaminants in liver of harbour porpoises (Phocoena phocoena) stranded on the Belgian North Sea coast
2002
Covaci, Adrian | Van de Vijver, Kristin Inneke | De Coen, Wim | Das, Krishna | Bouquegneau, Jean-Marie | Blust, Ronny | Schepens, Paul | MARE - Centre Interfacultaire de Recherches en Océanologie - ULiège
peer reviewed
显示更多 [+] 显示较少 [-]A field method using microcosms to evaluate transfer of Cd, Cu, Ni, Pb and Zn from sewage sludge amended forest soils to Helix aspersa snails.
2002
Scheifler, R | Ben Brahim, M | Vaufleury, Annette Gomot-De | Carnus, J-M | Badot, P-M | Laboratoire Chrono-environnement (UMR 6249) (LCE) ; Centre National de la Recherche Scientifique (CNRS)-Université de Franche-Comté (UFC) ; Université Bourgogne Franche-Comté [COMUE] (UBFC)-Université Bourgogne Franche-Comté [COMUE] (UBFC) | Centre de Sfax ; Centre de Sfax | Institut National de la Recherche Agronomique (INRA)
International audience | Juvenile Helix aspersa snails exposed in field microcosms were used to assess the transfer of Cd, Cu, Ni, Pb and Zn from forest soils amended with liquid and composted sewage sludge. Zn concentrations and contents were significantly higher in snails exposed to liquid and composted sludge after 5 and 7 weeks of exposure, when compared with control. Trends were less clear for the other metals. Present results show that Zn, among the cocktail of metallic trace elements (MTE) coming from sewage sludge disposal, represents the principal concern for food chain transfer and secondary poisoning risks. The microcosm design used in this experiment was well suited for relatively long-term (about 2 months) active biomonitoring with H. aspersa snails. The snails quickly indicated the variations of MTE concentrations in their immediate environment. Therefore, the present study provides a simple but efficient field tool to evaluate MTE bioavailability and transfer.
显示更多 [+] 显示较少 [-]Phosphorus sorption in subsurface constructed wetlands: investigations focused on calcareous materials and their chemical reactions
2002
Molle, Pascal | Lienard, A. | Grasmick, A. | Iwema, A.
Phosphorus removal from wastewater has been of growing interest for some decades to avoid eutrophication in surface water. In subsurface constructed wetlands precipitation and adsorption are the main mechanisms responsible of P uptake. The use of calcareous media is attractive because of p-ca interactions. Two media (calcite and recycled crushed concrete (rcc)) were examined in batch and continuous systems. They show attractive sorption capacities using batch experiments, however experiments carried out in open reactors pointed out some limitation in retention capacities and effluent quality. rcc was sensitive to a strong dissolution leading to a quick phosphorus precipitation but induced high conductivity and ph values in the treated water. Calcite efficiency depended on the material dissolution rate, directly linked to the carbonate equilibrium of the solution. Microscopic observations of the calcite surface show crystal making of phosphorus precipitate. Crystal growth seems to be the main P uptake once materials surfaces are covered. No experimental condition allows to reach an effluent concentration below 2 mgp.l-1.
显示更多 [+] 显示较少 [-]Phosphorus sorption in subsurface constructed wetlands: investigations focused on calcareous materials and their chemical reactions
2002
Molle, Pascal | Lienard, A. | Grasmick, A. | Iwema, A. | Qualité des eaux et prévention des pollutions (UR QELY) ; Centre national du machinisme agricole, du génie rural, des eaux et forêts (CEMAGREF) | Laboratoire de Génie des Procédés et Sciences des Aliments ; Université Montpellier 2 - Sciences et Techniques (UM2) | Agence de l'eau Rhône Méditerranée Corse
[Departement_IRSTEA]GMA [TR1_IRSTEA]21 - TECHNEAU / EPURE | International audience | Phosphorus removal from wastewater has been of growing interest for some decades to avoid eutrophication in surface water. In subsurface constructed wetlands precipitation and adsorption are the main mechanisms responsible of P uptake. The use of calcareous media is attractive because of p-ca interactions. Two media (calcite and recycled crushed concrete (rcc)) were examined in batch and continuous systems. They show attractive sorption capacities using batch experiments, however experiments carried out in open reactors pointed out some limitation in retention capacities and effluent quality. rcc was sensitive to a strong dissolution leading to a quick phosphorus precipitation but induced high conductivity and ph values in the treated water. Calcite efficiency depended on the material dissolution rate, directly linked to the carbonate equilibrium of the solution. Microscopic observations of the calcite surface show crystal making of phosphorus precipitate. Crystal growth seems to be the main P uptake once materials surfaces are covered. No experimental condition allows to reach an effluent concentration below 2 mgp.l-1.
显示更多 [+] 显示较少 [-]Development of a multichannel UV-spectroradiometer for field measurements
2002
Hanken, T. | Tueg, H.
Design criteria and performances of reed bed filters for the treatment of washing parlour effluents
2002
Lienard, A. | Esser, D. | Houdoy, D. | Sabalcagaray, P.
Conçus initialement pour le traitement des eaux usées domestiques, les filtres plantés de roseaux ont été adaptés pour le traitement des effluents de lavage de salles de traite pour fournir une alternative au stockage et épandage. Pour simplifier les système en vue de réduire les coûts d'investissement, plusieurs sites expérimentaux ont été construits, modifiés si nécessaire et suivis. Placé à la suite d'une fosse toutes eaux de 3 à 9 m3, la configuration la plus aboutie consiste en 2 étages des filtres plantés à flux verticaux chacun étant composé de 2 filtres alimentés en alternance chaque semaine. La surface totale active correspond à 0.25m2 par vache laitière pour les eaux blanches seules (machine à traire et tank à lait) et 0.4m2 par vache lorsque s'y ajoutent les eaux vertes de lavage des quais et murs de la salle de traite. Les filtres du 1er étage occupent 65% de la surface totale. Observées dans 3 exploitations agricoles laitières, les concentrations obtenues atteignent une fourchette de 50 à 180 mg/L en DCO, 5 à 75 mg/L en DBO5 et 10 à 60 mg/L en MES. La nitrification qui est considérée comme un bon indicateur du potentiel d'oxydo-réduction dans le réacteur n'est certes pas complète mais beaucoup plus élevée que dans le cas de filtres à sable étudiés pour le même objectif alors que plusieurs d'entre eux ont colmaté. / Initially designed for the treatment of domestic wastewater, Vertical Flow Reed Bed Filters [VFRBF] have been adapted for washing parlour effluents to study the feasibility of the treatment of such effluents instead of their storage and land spreading. It was necessary to adapt the design of VFRBF to minimise the investment costs. Several experimental sites have been built, monitored and progressively adapted. Following a septic tank of 3 to 9 m3, the best design was considered to be: 2 stages of VFRBF in series each composed of 2 filters which are alternately fed on a weekly rhythm. The total active area is approximately equivalent to 0.25 m2 per milking cow for the washing effluent of the milking machine and milk-storage tank and 0.4 m2 per milking cow when the washing effluents from the floor and walls of the milking parlour are added to the previous ones. The 1st stage filters takes up 65 % of the total area. Based on a survey done in 3 farms, the concentrations achieved a range of 50 to 180 mgL-1 in COD, 5 to 75 mgL-1 in BOD5, 10 to 60 mgL-1 in SS. The nitrification, which can be considered as a good indicator of the redox potential within the filter media, was not complete but much more effective than in sand filters studied for the same purpose but some of them have clogged.
显示更多 [+] 显示较少 [-]The measurement of cholinesterase activities as a biomarker in chub (Leuciscus cephalus): the fish length should not be ignored | Les mesures de l'activité de la cholinesterase utilisé comme biomarqueur pour les chevaines (Leuciscus cephalus) : doit-on tenir compte de la taille du poisson ?
2002
Flammarion, Patrick | Noury, P. | Garric, Jeanne | Biologie des écosystèmes aquatiques (UR BELY) ; Centre national du machinisme agricole, du génie rural, des eaux et forêts (CEMAGREF)
[Departement_IRSTEA]GMA [TR1_IRSTEA]12 - MILEAU / EXPER | International audience | Biomarkers are early warning systems of the exposure of aquatic organisms to pollutants. Among them, the measurement of the cholinesterase (ChE) activities in fish muscle is a biomarker of the exposure to organophosphosphates and carbamates pesticides. As Such it has been used in numerous field studies both in marine and continental waters. Cyprinids (chub, Leuciscus cephalus) were sampled in river sites (France) in relatively clean and polluted areas. We performed the statistical analysis of the ChE activities and we generally observed a statistical relationship between ChE activities and fish length, the larger fish having the lower ChE activities. We concluded that the great majority of the significant differences in ChE activities between sites could be due in fact to differences in fish length between field samples. We stress the importance of taking into account the fish length whenever differences in ChE levels between field sites must be interpreted.
显示更多 [+] 显示较少 [-]Assessment of exceedance of critical levels for ozone in Slovak forest ecosystems
2002
Pavlendova, H. | Mindas, J. (Forest Research Institute, Zvolen (Slovak Republic))
For assessment of ozone risks to forests we used ozone thresholds and air quality guidelines set by several international organizations for protection of vegetation. We also used spatial modelling for estimation of basic ozone characteristics. Calculations of models were performed in the environment of the programme Idrisi 32. The spatial coverage of ozone monitoring network in the Slovak Republic has insufficient density. Ozone data come from two sources; SHMI/EMEP database of ozone concentrations from 4 monitoring stations and ozone database of FRI from 3 monitoring stations
显示更多 [+] 显示较少 [-]Impact of elevated O3 trembling aspen (Populus tremuloides MICHX.) leaf epicuticular waxes and elemental composition of leaves
2002
Mankovska, B. (Forest Research Institute, Zvolen (Slovak Republic)) | Karnosky, D. F. | Percy, K. | Ermakova, E. | Frontasyeva, M.
Foliage of three trembling aspen clones differing in O3 tolerance from Rhinelander, Kenosha and Kalamazoo were examined for 24 elements in the year 2001 and they were analyzed by INAA at reactor IBR-2, by AAS Varian 400 and by elemental analyzer LECO SC 132 and SP 228. In the fofliage of trembling aspen we found no statistically significant difference in the concentration of 22 elements except for K and Ni between clones. For the concentrations of elements between localities we found statistically significant difference for Al, Ba, Ca, Cd, Cl, Co, Cu, La, Mo, Na, Ni, Pb, Sm, Sr and Zn
显示更多 [+] 显示较少 [-]The Hungarian ILTER sites and their activities in 2002
2002
Kovacs-Lang, E. | Kertesz, M. | Toth, J. A.
The Hungarian ILTER Network consists of three sites representing the characteristic biomes in the country: lake Balaton ILTER site, Sikofut oak forest ILTER site, and the Kiskun sand forest-steppe ILTER site. Hungarian ecologists have developed broad multidisciplinary research projects, which can meet both the requirements of international research standards and the domestic needs of nature conservation and environment protection. Hungarian policy and decision makers have also recognised the importance of long-term ecological research. As a consequence different grants such as Hungarian R + D "Szechenyi", EU FWS Projects, OTKA and OTKA-NSF Projects, Joint grant of Ministry of Environment and the Hungarian Academy of Sciences were awarded in the last 2-3 years, what could create the basis of national and international research cooperations of Hungarian ILTER sites
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