En esta Monografia se trata el tema de la utilizacion del cloro y sus compuestos como medio de alcanzar los requisitos sanitarios que deben cumplir las aguas utilizadas en la industria alimentaria. Se explica la terminologia empleada en cloracion asi como la quimica del cloro en el agua y su comportamiento en funcion de Ph y temperatura. Se ejemplifican distintos sistemas de cloracion y finalmente se hace referencia a un posible programa de control de la cloracion en planta y a metodos analiticos para la evaluacion del cloro activo.

En esta Monografia se trata el tema de la utilizacion del cloro y sus compuestos como medio de alcanzar los requisitos sanitarios que deben cumplir las aguas utilizadas en la industria alimentaria. Se explica la terminologia empleada en cloracion asi como la quimica del cloro en el agua y su comportamiento en funcion de Ph y temperatura. Se ejemplifican distintos sistemas de cloracion y finalmente se hace referencia a un posible programa de control de la cloracion en planta y a metodos analiticos para la evaluacion del cloro activo.

Qualitative and quantitative analysis of organochlorine insecticide residues were conducted in water, sediment, aquatic plants and animals from 3 freshwater reservoirs. Ninety water samples, 90 sediment samples, 397 aquatic plants samples and 121 aquatic animals samples were collected during March-April and August-September 1989. There were about 14 kinds of aquatic plants, such as water hyacinth, water lettuce, algae and water lilly etc. Aquatic animals are fish, shrimps and snails, but most of them are fish. They are striped snake-head fish, carp and catfish etc. Total samples of 698 were analyzed by using gas chromatographic techniques at Agricultural Toxic Substances Division. The results indicated that 5 kinds of insecticides were found in most samples. They were lindane, heptachlor, aldrin, dieldrin, DDT and derivatives. Dieldrin was detected at higher concentration and found in all samples. The residue level of dieldrin ranged from 0.01-0.12 ppb in water, 0.005-0.036 ppm in sediment, 0.001-0.138 ppm in aquatic plants and 0.001-0.037 ppm in aquatic animals respectively. The accumulation of dieldrin residue in water and aquatic plant samples from all reservoirs are not different but the level of dieldrin residue in sediment samples from Bueng Boraphed is higher than the other 2 reservoris. However the levels of dieldrin residue in sediment, aquatic plant and aquatic animal samples higher than those in water samples respectively.

The effect of esterification on hydrolyzed rice starch was analyzed, for this aim rice starch was hydrolyzed and subsequently esterified with lauroyl chloride at three modification levels. Starch derivatives were characterized regarding their degree of substitution (DS), water solubility index, z-potential, gelatinization, and digestibility properties. DS of derivatives of rice starch laurate ranged from 0.042 to 1.86. It was determined that after esterification the water solubility index increased from 3.44 to 53.61%, the z-potential decreased from −3.18 to −11.27, and the content of slowly digestible starch (SDS) decreased from 26.22 to 5.13%. Different emulsions with starch concentrations ranging from 6 to 30 wt% were evaluated. The most stable emulsions were those having 20 and 30 wt% of rice starch laurate.

7 pages, 4 figures, 5 tables.-- PMID: 15382852 [PubMed].-- Printed version published Aug, 15, 2004. | An integrated study encompassing the distribution of organochlorine compounds (OC) in water, food web (chironomids, terrestrial insects, cladocerans, mollusks, and cyanobacteria), and fish (brown trout) from a high mountain lake (Redon, Pyrenees) is reported. OC distributions in these compartments have been determined to assess their transport routes into fish. Food diets have been estimated by analysis of fish stomach content and food web stable isotopes (δ13C and δ15N). OCs with octanol−water partition coefficient (Kow) higher than 106 showed lower concentra tions in food than expected from theoretical octanol−water partition, indicating that the distribution of these compounds does not reach equilibrium within the life span of the food web organisms (ca. 1 year). On the other hand, the degree of biomagnification in fish increased with Kow, except in the case of the largest compound analyzed (seven chlorine substituents, PCB #180). OC exchange at fish gill and gut has been evaluated using a fugacity model based on the water, food, and fish concentrations. All compounds exhibited a net gill loss and a net gut uptake. A pseudostationary state was only achieved for compounds with log(Kow) < 6. Calculation of fish average residence times for the compounds in apparent steady state gave values of days to a few weeks for HCHs, 1 year for HCB and 4,4‘-DDE, and 2−3 years for 4,4‘-DDT and PCB#28 and PCB#52. Residence times longer than one decade were found for the more chlorinated PCB. | Financial support from the EU projects EUROLIMPACS (GOCE-CT-2003-505540) and EMERGE (EVK1-CT-1999-00032) and ACA-CIRIT (Generalitat de Catalunya). | Peer reviewed