The geochemical and isotopic composition of surface waters and groundwater in the Velenje Basin, Slovenia, was investigated seasonally to determine the relationship between major aquifers and surface waters, water–rock reactions, relative ages of groundwater, and biogeochemical processes. Groundwater in the Triassic aquifer is dominated by HCO₃–, Ca²⁺, Mg²⁺and δ¹³CDICindicating degradation of soil organic matter and dissolution of carbonate minerals, similar to surface waters. In addition, groundwater in the Triassic aquifer has δ¹⁸O and δD values that plot near surface waters on the local and global meteoric water lines, and detectable tritium, likely reflecting recent (<50 years) recharge. In contrast, groundwater in the Pliocene aquifers is enriched in Mg²⁺, Na⁺, Ca²⁺, K⁺, and Si, and has high alkalinity and δ¹³CDICvalues, with low SO₄²–and NO₃–concentrations. These waters have likely been influenced by sulfate reduction and microbial methanogenesis associated with coal seams and dissolution of feldspars and Mg-rich clay minerals. Pliocene aquifer waters are also depleted in¹⁸O and²H, and have³H concentrations near the detection limit, suggesting these waters are older, had a different recharge source, and have not mixed extensively with groundwater in the Triassic aquifer.

Correct understanding of groundwater/surface-water (GW–SW) interaction in karst systems is of greatest importance for managing the water resources. A typical karst region, Fangshan in northern China, was selected as a case study. Groundwater levels and hydrochemistry analyses, together with isotope data based on hydrogeological field investigations, were used to assess the GW–SW interaction. Chemistry data reveal that water type and the concentration of cations in the groundwater are consistent with those of the surface water. Stable isotope ratios of all samples are close to the local meteoric water line, and the ³H concentrations of surface water and groundwater samples are close to that of rainfall, so isotopes also confirm that karst groundwater is recharged by rainfall. Cross-correlation analysis reveals that rainfall leads to a rise in groundwater level with a lag time of 2 months and groundwater exploitation leads to a fall within 1 month. Spectral analysis also reveals that groundwater level, groundwater exploitation and rainfall have significantly similar response periods, indicating their possible inter-relationship. Furthermore, a multiple nonlinear regression model indicates that groundwater level can be negatively correlated with groundwater exploitation, and positively correlated with rainfall. The overall results revealed that groundwater level has a close correlation with groundwater exploitation and rainfall, and they are indicative of a close hydraulic connection and interaction between surface water and groundwater in this karst system.

As a result of pumping in excess of recharge, water levels in alluvial aquifers within the Eastern San Joaquin Groundwater Subbasin, 130 km east of San Francisco (California, USA), declined below sea level in the early 1950s and have remained so to the present. Chloride concentrations in some wells increased during that time and exceeded the US Environmental Protection Agency’s secondary maximum contaminant level of 250 mg/L, resulting in removal of some wells from service. Sources of high-chloride water include irrigation return in 16 % of sampled wells and water from delta sediments and deeper groundwater in 50 % of sampled wells. Chloride concentrations resulting from irrigation return commonly did not exceed 100 mg/L, although nitrate concentrations were as high as 25 mg/L as nitrogen. Chloride concentrations ranged from less than 100–2,050 mg/L in wells affected by water from delta sediments and deeper groundwater. Sequential electromagnetic logs show movement of high-chloride water from delta sediments to pumping wells through permeable interconnected aquifer layers. δD and δ¹⁸O data show most groundwater originated as recharge along the front of the Sierra Nevada, but tritium and carbon-14 data suggest recharge rates in this area are low and have decreased over recent geologic time. Managed aquifer recharge at two sites show differences in water-level responses to recharge and in the physical movement of recharged water with depth related to subsurface geology. Well-bore flow logs also show rapid movement of water from recharge sites through permeable interconnected aquifer layers to pumping wells.

Improved groundwater flow conceptualization was achieved using environmental stable isotope (ESI) and hydrochemical information to complete a numerical groundwater flow model with reasonable certainty. The study aimed to assess the source of excess water at a pumping shaft located near the town of Stilfontein, North West Province, South Africa. The results indicate that the water intercepted at Margaret Shaft comes largely from seepage of a nearby mine tailings dam (Dam 5) and from the upper dolomite aquifer. If pumping at the shaft continues at the current rate and Dam 5 is decommissioned, neighbouring shallow farm boreholes would dry up within approximately 10 years. Stable isotope data of shaft water indicate that up to 50 % of the pumped water from Margaret Shaft is recirculated, mainly from Dam 5. The results are supplemented by tritium data, demonstrating that recent recharge is taking place through open fractures as well as man-made underground workings, whereas hydrochemical data of fissure water samples from roughly 950 m below ground level exhibit mine-water signatures. Pumping at the shaft, which captures shallow groundwater as well as seepage from surface dams, is a highly recommended option for preventing flooding of downstream mines. The results of this research highlight the importance of additional methods (ESI and hydrochemical analyses) to improve flow conceptualization and numerical modelling.

The impacts of wastewater on Indigenous drinking water sources is an issue of concern across Canada. This study investigated the wastewater impacts on groundwater resources at a First Nations reserve located on a vulnerable fractured sedimentary bedrock aquifer in southern Ontario. The objectives were to examine the spatiotemporal variability of a variety of tracers of wastewater and their movement to groundwater. The tracers included nitrate, E. coli, total coliforms, and the artificial sweeteners sucralose, acesulfame, and cyclamate. Isotopes in the groundwater were also examined, including tritium and the isotopes of oxygen and nitrogen in dissolved inorganic nitrate. Three multilevel monitoring systems (seven-channel continuous multi-channel tubing) were retrofitted in unused drinking-water wells on the reserve and monitored from December 2015 to November 2016. Results indicate that groundwater at various depths has been impacted by the septic systems on the reserve. The fractures intersected by the three retrofitted wells contain a mix of newly recharged and older water, and contaminant peaks do not always correspond with ports aligned with higher hydraulic conductivity, showing variable travel times for the constituents. The selection of wastewater management systems that are appropriate for the particular hydrogeological setting on the reserves is critical to providing safe, clean drinking water to Indigenous communities. In particular, special consideration should be made for communities situated on fractured sedimentary bedrock aquifers with thin overburden.

Geothermal resources are practical and competitive clean-energy alternatives to fossil fuels, and study on the recharge sources of geothermal water supports its sustainable exploitation. In order to provide evidence on the recharge source of water and circulation dynamics of the Tangshan Geothermal System (TGS) near Nanjing (China), a comprehensive investigation was carried out using multiple chemical and isotopic tracers (δ²H, δ¹⁸O, δ³⁴S, ⁸⁷Sr/⁸⁶Sr, δ¹³C, ¹⁴C and ³H). The results confirm that a local (rather than regional) recharge source feeds the system from the exposed Cambrian and Ordovician carbonate rocks area on the upper part of Tangshan Mountain. The reservoir temperature up to 87 °C, obtained using empirical as well as theoretical chemical geothermometers, requires a groundwater circulation depth of around 2.5 km. The temperature of the geothermal water is lowered during upwelling as a consequence of mixing with shallow cold water up to a 63% dilution. The corrected ¹⁴C age shows that the geothermal water travels at a very slow pace (millennial scale) and has a low circulation rate, allowing sufficient time for the water to become heated in the system. This study has provided key information on the genesis of TGS and the results are instructive to the effective management of the geothermal resources. Further confirmation and even prediction associated with the sustainability of the system could be achieved through continuous monitoring and modeling of the responses of the karstic geothermal reservoir to hot-water mining.

Wells along two regional flow paths were sampled to characterize changes in water quality and the vulnerability to contamination of the Memphis aquifer across a range of hydrologic and land-use conditions in the southeastern United States. The flow paths begin in the aquifer outcrop area and end at public supply wells in the confined parts of the aquifer at Memphis, Tennessee. Age-date tracer (e.g. SF₆, ³H, ¹⁴C) data indicate that a component of young water is present in the aquifer at most locations along both flow paths, which is consistent with previous studies at Memphis that documented leakage of shallow water into the Memphis aquifer locally where the overlying confining unit is thin or absent. Mixtures of young and old water were most prevalent where long-term pumping for public supply has lowered groundwater levels and induced downward movement of young water. The occurrence of nitrate, chloride and synthetic organic compounds was correlated to the fraction of young water along the flow paths. Oxic conditions persisted for 10 km or more down dip of the confining unit, and the presence of young water in confined parts of the aquifer suggest that contaminants such as nitrate-N have the potential for transport. Long-term monitoring data for one of the flow-path wells screened in the confined part of the aquifer suggest that the vulnerability of the aquifer as indicated by the fraction of young water is increasing over time.

³H, δ¹³C and hydrochemical data were used to estimate the corrected groundwater age derived from conventional ¹⁴C age of dissolved inorganic carbon (DIC). The Middle-Upper Devonian aquifer system from the Baltic upland recharge area in eastern Lithuania towards the discharge area on the Baltic Sea coast in the west was considered. The concentration of total dissolved solids (TDS) in groundwater changes from 300 to 24,000 mg/L and increases downgradient towards the coast. The other major constituents have the same trend as the TDS. The hydrochemical facies of groundwater vary from an alkali-earth carbonates facies at the eastern upland area to an alkali-earth carbonate-sulfate and chloride facies at transit and discharge areas. Meteoric water percolating through the Quaternary and Devonian aquifers regulate the initial ¹⁴C activities of groundwater involving two main members of DIC: soil CO₂ with modern ¹⁴C activity uptake and dissolution of ¹⁴C-free aquifer carbonates. Other sources of DIC are less common. ¹⁴C activity of DIC in the groundwater ranged from 60 to 108 pMC at the shallow depths. With an increase of the aquifers depth the dolomitization of aqueous solution and leakage of the “old” groundwater from lower aquifers take place, traced by lower activities (7–30 pMC).

The Eocene deposits of Kazan Basin in Turkey contain a rare trona mineral which is planned to be extracted by solution mining. The complex flow dynamics and mixing mechanisms as noted from previous hydraulic and hydrochemical data need to be augmented with environmental tracer and noble gas data to develop a conceptual model of the system for the assessment of the impacts of the mining and to develop sustainable groundwater management policies throughout the area. The tracers used include the stable isotopes of water (δ²H, δ¹⁸O), δ¹³C and¹⁴C of dissolved inorganic carbon (DIC), tritium (³H), the chlorofluorocarbons CFC-11 and CFC-12, and the noble gases He and Ne. The system studied consists of three aquifers: shallow, middle, and deep. CFC data indicate modern recharge in the shallow system. The estimates of ages through¹⁴C dating for the deeper aquifer system are up to 34,000 years. Helium concentrations cover a wide range of values from 5 × 10⁻⁸to 1.5 × 10⁻⁵ cm³STP/g.³He/⁴He ratios vary from 0.09RAto 1.29RA(where RAis the atmospheric³He/⁴He ratio of 1.384 × 10⁻⁶), the highest found in water from the shallow aquifer. Mantle-derived³He is present in some of the samples indicating upward groundwater movement, possibly along a NE–SW-striking fault-like feature in the basin.

A wide range of lithologic units and tectonic disturbances by cross-cutting faults and folds has resulted in the quite complex hydrogeological setting of the sedimentary outlier and its surroundings at Mekelle, northern Ethiopia. The environmental isotopes of oxygen and hydrogen and patterns of dissolved ion concentrations in the groundwater, coupled with understanding of the three-dimensional geological framework, are used to conceptualize the groundwater flow model and recharge–discharge mechanisms in the area. In agreement with the piezometric-surface map, recharge areas are determined to be the highlands (northwest, north, east and south of the study area), characterized by relatively more depleted isotopic compositions, higher d-excess, and lower concentrations of dissolved ions in the groundwater samples; the narrow major river valleys of Giba, Illala, Chelekot and Faucea Mariam are discharge areas. The groundwater divide between the Tekeze and the Denakil basins coincides with the surface-water divide line of these two basins. In most cases, groundwater feeds the semi-perennial streams and rivers in the area. However, isotopic signatures in some wells indicate that there are localities where river flow and seepage from micro-dams locally feed the adjacent aquifers. The lithostratigraphic, geomorphologic, isotopic and hydrochemical settings observed in this study indicate that three groundwater flow systems (shallow/local, intermediate and deep/semi-regional) can exist here. Tritium data indicate that the groundwater in the study area has generally short residence time and is dependent on modern precipitation.