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Research on groundwater seepage through fault zones in coal mines | Etude sur la diffusion des eaux souterraines à partir de zones de failles dans les mines de charbon Investigación sobre la filtración de aguas subterráneas a lo largo de las zonas de falla en las minas de carbón 煤矿断层带地下水渗漏研究 Pesquisa sobre infiltração de água subterrânea através de zonas de falha em minas de carvão 全文
2021
Yu, Haitao | Zhu, Shuyun | Wang, Xianhui
Water inrush in coal mines is commonly linked to fault zones. Excavation of the coal seam can lead to new fractures in the associated fault zone. Many water inrush disasters have a time lag, which is closely related to the fault zone’s permeability. In the present study, three kinds of fault analog samples (artificially reproduced samples analogous to the fault material) are prepared according to microscopic characteristics of natural fault samples, and permeability tests are carried out under constant water pressure. By monitoring the pressure change during the permeability test, the seepage process in the fault zone can be divided into three stages: slow growth, rapid growth, and saturation. In addition, a time-dependent equation of porosity and permeability in porous media is introduced in the coefficient partial differential equation module in COMSOL Multiphysics. By fully coupling with the Brinkman flow module, three kinds of numerical models of the fault zone with different initial porosity and permeability are established. The porosity growth rates in the three fault-zone seepage stages are 24, 23, and 2%, respectively. The growth rates of permeability are 122, 110, and 8%, respectively. The growth rates of flow velocity are 211, 185, and 11%, respectively. The growth rate of the fault model with low porosity and low permeability is lower than that of the other two models. By discussing different conceptual models of water inrush from faults, the results indicate that water inrush disasters can be delayed or prevented if the clay content in the fault is high.
显示更多 [+] 显示较少 [-]Machine-learning-based regional-scale groundwater level prediction using GRACE | Prévision du niveau des eaux souterraines à l’échelle régionale basée sur l’apprentissage automatique à l’aide de GRACE Predicción del nivel de las aguas subterráneas a escala regional usando GRACE 利用机器学习方法和GRACE数据预测区域地下水水位 Previsão do nível de água subterrânea em escala regional baseada em aprendizado de máquina usando GRACE 全文
2021
Malakar, Pragnaditya | Mukherjee, Abhijit | Bhanja, Soumendra N. | Ray, Ranjan Kumar | Sarkar, Sudeshna | Zahid, Anwar
The rapid decline of groundwater levels (GWL) due to pervasive groundwater abstraction in the densely populated (~1 billion) Indus-Ganges-Brahmaputra-Meghna (IGBM) transboundary river basins of South Asia, necessitates a robust framework of prediction and understanding. While few localized studies exist, three-dimensional regional-scale characterization of GWL prediction is yet to be implemented. Here, ‘support vector machine’, a machine-learning-based method, is applied to data from the Gravity Recovery and Climate Experiment (GRACE) and data on land-surface-model-based groundwater storage and meteorological variables, to predict the GWL anomaly (GWLA) in the IGBM. The study has three main objectives, (1) to understand the spatial (observation well locations) and subsurface (shallow vs. deep observation wells) variability in prediction results for in-situ GWLA data for a large number of observation wells (n = 4,791); (2) to determine its relationship with groundwater abstraction, and; (3) to outline the advantages and limitations of using GRACE data for predicting GWLAs. The findings, based on individual observation well results, suggest significant prediction efficiency (median statistics: r > 0.71, NSE > 0.70; p < 0.05) in most of the IGBM; however, the study identifies hotspots, mostly in the agriculture-intensive regions, having relatively poor model performance. Further analysis of the subsurface depth-wise prediction statistics reveals that the significant dominance of pumping in the deeper depths of the aquifer is linked to the relatively poor model performance for the deep observation wells (screen depth > 35 m) compared with the shallow observation wells (screen depth < 35 m), thus, highlighting the limitation of GRACE in representing spatial and depth-dependent local-scale pumping.
显示更多 [+] 显示较少 [-]Multiple-tracers-aided surface-subsurface hydrological modeling for detailed characterization of regional catchment water dynamics in Kumamoto area, southern Japan | Modélisation hydrologique de surface-subsurface appuyé par plusieurs traceurs pour une caractérisation détaillée de la dynamique des eaux du bassin régional de la zone de Kumamoto, sud du Japon Modelización hidrológica superficial y subterránea con ayuda de múltiples trazadores para la caracterización detallada de la dinámica hídrica regional en las cuencas en la zona de Kumamoto, sur de Japón 日本南部Kumamoto地区区域流域水动力学详细特征的多示踪辅助地表水和地下水水文模拟 Modelagem hidrológica de subsuperfície e superfície auxiliada por múltiplos traçadores para caracterização detalhada da dinâmica da água de captação regional na área de Kumamoto, sul do Japão 全文
2021
Rahman, A. T. M Sakiur | Hosono, Takahiro | Tawara, Yasuhiro | Fukuoka, Youichi | Hazart, Aurelien | Shimada, Jun
Integrated watershed modeling techniques have been applied in recent years to examine surface and subsurface interactions. Model performance is often evaluated by best fit of the hydrograph, which alone cannot explicitly explain whole catchment dynamics. To overcome this problem, this study incorporated multiple tracers (³H, ⁸⁵Kr, and groundwater temperature) into a physically-based fully distributed modeling framework for characterizing regional-scale hydrological processes in Kumamoto, southern Japan. First, a simulation performed by a hydrometrically calibrated model showed satisfactory performance for river discharge and groundwater level. However, this model showed poor fitting for isotopic composition and temperature due to the structural uncertainty of the model. A new model was established reflecting recent deep bore log data and incorporating tracer data showed acceptable accuracy for hydrographs and tracers. Thus, more reliable estimates of groundwater storage, groundwater age and water flow paths were depicted over the regional catchment. Comparisons between the two models indicate that the model structure of an area with an uncertain lower boundary can be addressed by incorporating multiple tracer data. Tracer-aided models could be applied for a holistic understanding of contaminant transport dynamics besides flow simulation.
显示更多 [+] 显示较少 [-]Simulation of irrigation-induced groundwater recharge in an arid area of China | Simulation de la recharge en eau souterraine induite par l’irrigation dans une zone aride de la Chine Simulación de la recarga inducida de aguas subterráneas debido a la irrigación en una zona árida de China 中国某干旱区灌溉引起的地下水补给模拟 Simulação de recarga de água subterrânea induzida por irrigação em uma área árida da China 全文
2021
Wang, Wenke | Zhao, Jiahui | Duan, Lei
Accurate estimation of irrigation return flow plays an important role in the effective management of groundwater, especially in arid and semiarid irrigation regions. However, there is a lack of sufficient research to clarify hydrological process dynamics associated with irrigation return flow. In this study, first, a two-dimensional/three-dimensional model, HYDRUS-2D/3D, was adopted to analyze two different irrigation types in the Delingha Depression, which is located at the northeastern margin of the Qaidam Basin, China. Then, a 3D saturated flow model was established. This study determined the effect of agricultural water application on the dynamics of irrigation return flow. A large difference in the irrigation return-flow coefficient (IRFC) was seen during the growing season; an IRFC of 0.3 was obtained using flood irrigation, whereas ditch irrigation resulted in an IRFC of only 0.1. The lag time of recharge was approximately 150 days. It was necessary to consider the lag time for the 3D numerical model to obtain satisfactory results. Flood irrigation led to a groundwater recharge rate of 90 mm/year. These results indicate that the lag time should be considered when groundwater recharge is estimated or modeled.
显示更多 [+] 显示较少 [-]Effect of riverbed sediment flushing and clogging on river-water infiltration rate: a case study in the Second Songhua River, Northeast China | Effet de la chasse et du colmatage des sédiments du lit d’une rivière sur le taux d’infiltration de l’eau: une étude de cas dans la deuxième rivière Songhua, au Nord-Est de la Chine Efecto del lavado y la depositación de sedimentos en la tasa de infiltración en el cauce de un río: un estudio de caso en el Second Songhua River, noreste de China 河床沉积物的冲淤对河水入渗速率的影响-以中国东北第二松花江为例 Efeito da descarga e do depósito no leito do rio e na taxa de infiltração da água do rio: um estudo de caso no Segundo Rio Songhua, nordeste da China 全文
2021
Cui, Geng | Su, Xiaosi | Liu, Yan | Zheng, Shida
Infiltration from natural rivers or streams is the most important source of aquifer recharge at riverbank filtration (RBF) sites. Due to the influence of river hydrological processes and changes in suspended solids in rivers, riverbed sediments often undergo significant flushing and clogging processes, which lead to obvious spatial and temporal changes in riverbed sediment permeability. Moreover, the lithology, structure, and thickness of natural riverbed sediments change with time, influencing the bank infiltration rate into groundwater. At present, how riverbed-sediment flushing and clogging influences the sediment hydraulic conductivity is not fully understood, which results in high uncertainty about the amount of water involved in RBF. An RBF site in the middle reach of the Second Songhua River, northeastern China, was studied, and continuous time series data of riverbed-sediment hydraulic conductivity were obtained for the first time. By identifying the hydrological conditions, using field monitoring, laboratory experiments and field tests, the mechanisms of change associated with sediment lithology, infiltration rate, and hydraulic conductivity during flushing and clogging processes were revealed.
显示更多 [+] 显示较少 [-]Groundwater sampling in karst terranes: passive sampling in comparison to event-driven sampling strategy | Échantillonnage des eaux souterraines en terrains karstiques: échantillonnage passif versus échantillonnage basé sur une stratégie évènementielle Muestreo de aguas subterráneas en terrenos kársticos: muestreo pasivo en comparación con la estrategia de muestreo por eventos 喀斯特岩层中的地下水采样:与事件驱动采样策略相比的被动采样 Amostragem de água subterrânea em terrenos cársticos: amostragem passiva em comparação à estratégia de amostragem baseada em eventos 全文
2021
Field, Malcolm S.
Karst aquifers are very easily contaminated because of the surficial features that commonly exist in karst terranes. Pollutant releases into sinkholes, sinking streams, and/or losing streams commonly result in concentrated solutes rapidly infiltrating and migrating through the subsurface to eventually discharge at downgradient springs unless intercepted by production wells, but slow percolation through soils also may result in serious contamination of karst aquifers. The unique features of karst terranes tend to cause significant problems in the interpretation of results obtained from water-quality grab samples of karst groundwater. To obtain more representative samples, event-driven sampling was proposed some decades ago, but event-driven sampling can be difficult and expensive to implement. In this paper, application of passive-sampling strategies is advocated as a means for effectively obtaining representative water-quality samples from karst aquifers. A passive-sampling methodology may be particularly useful for karst aquifers that may be found in complexly folded and faulted terranes. For example, a groundwater tracing investigation of a contaminated site in a karst terrane confirmed that several offsite springs and wells are connected to the contaminated site. Tracer recoveries suggested transport rates that were relatively slow for flow in a karstic aquifer (~0.02 m/s). Breakthrough curves were erratic and spiky. To obtain representative groundwater samples, a passive-sampling methodology is recommended.
显示更多 [+] 显示较少 [-]Hydrogeology and groundwater management in a coastal granitic area with steep slopes in Galicia (Spain) | Hydrogéologie et gestion des eaux souterraines dans une zone granitique côtière avec des pentes fortes en Galice (Espagne) Hidrogeología y gestión del agua subterránea en una zona granítica costera de Galicia (España) con pendientes pronunciadas 西班牙Galicia陡坡沿海花岗岩地区的水文地质学和地下水管理 Hidrogeologia e gestão das águas subterrâneas em uma zona costeira granítica com encostas íngremes na Galícia (Espanha) 全文
2021
Naves, Acacia | Samper, Javier | Pisani, Bruno | Mon, Alba | Dafonte, Jorge | Montenegro, Luis | García-Tomillo, Aitor
Groundwater availability, management and protection are great challenges for the sustainability of groundwater resources in the scattered rural areas of the Atlantic regions of Europe where groundwater is the only option for water supply. This report presents a hydrogeological study of the coastal granitic area of Oia in northwestern Spain, which has unique geomorphological and hydrogeological features with steep slopes favoring the erosion of the weathered granite. The hydrogeological conceptual model of the study area includes: (1) the regolith layer, which is present only in the flat summit of the mountains; (2) the slope debris and the colluvial deposits, which are present in the intermediate and lowest parts of the hillside; (3) the marine terrace; and (4) the underlying fractured granite. Groundwater recharge from rainfall infiltration varies spatially due to variations in terrain slope, geology and land use. The mean annual recharge estimated with a hydrological water balance model ranges from 75 mm in the steepest zone to 135 mm in the lowest flat areas. Groundwater flows mostly through the regolith and the detrital formations, which have the largest hydraulic conductivities. Groundwater discharges in seepage areas, springs, along the main creeks and into the sea. The conceptual hydrogeological model has been implemented in a groundwater flow model, which later has been used to select the best pumping scenario. Model results show that the future water needs for domestic and tourist water supply can be safely provided with eight pumping wells with a maximum pumping rate of 700 m³/day.
显示更多 [+] 显示较少 [-]Hydrogeology and Groundwater Management in a Coastal Granitic Area With Steep Slopes in Galicia (Spain) | Hydrogéologie et gestion des eaux souterraines dans une zone granitique côtière avec des pentes fortes en Galice (Espagne) | Hidrogeología y gestión del agua subterránea en una zona granítica costera de Galicia (España) con pendientes pronunciadas | 西班牙Galicia陡坡沿海花岗岩地区的水文地质学和地下水管理 | Hidrogeologia e gestão das águas subterrâneas em uma zona costeira granítica com encostas íngremes na Galícia (Espanha) 全文
2021
Naves, Acacia | Samper, Javier | Pisani, Bruno | Mon, Alba | Dafonte, Jorge | Montenegro, Luis | García-Tomillo, Aitor
[Abstract] Groundwater availability, management and protection are great challenges for the sustainability of groundwater resources in the scattered rural areas of the Atlantic regions of Europe where groundwater is the only option for water supply. This report presents a hydrogeological study of the coastal granitic area of Oia in northwestern Spain, which has unique geomorphological and hydrogeological features with steep slopes favoring the erosion of the weathered granite. The hydrogeological conceptual model of the study area includes: (1) the regolith layer, which is present only in the flat summit of the mountains; (2) the slope debris and the colluvial deposits, which are present in the intermediate and lowest parts of the hillside; (3) the marine terrace; and (4) the underlying fractured granite. Groundwater recharge from rainfall infiltration varies spatially due to variations in terrain slope, geology and land use. The mean annual recharge estimated with a hydrological water balance model ranges from 75 mm in the steepest zone to 135 mm in the lowest flat areas. Groundwater flows mostly through the regolith and the detrital formations, which have the largest hydraulic conductivities. Groundwater discharges in seepage areas, springs, along the main creeks and into the sea. The conceptual hydrogeological model has been implemented in a groundwater flow model, which later has been used to select the best pumping scenario. Model results show that the future water needs for domestic and tourist water supply can be safely provided with eight pumping wells with a maximum pumping rate of 700 m3/day. | [Résumé] La disponibilité, la gestion et la protection des eaux souterraines sont de grands défis pour la durabilité de ces ressources en eaux dans les zones rurales dispersées des régions atlantiques de l’Europe où l’eau souterraine est la seule option pour l’approvisionnement en eau. Cet article présente une étude hydrogéologique de la zone granitique côtière d’Oia dans le nord-ouest de l’Espagne, qui présente des caractéristiques géomorphologiques et hydrogéologiques uniques avec des pentes fortes favorisant l’érosion du granite altéré. Le modèle conceptuel hydrogéologique de la zone d’étude comprend: (1) la couche de régolithe présente seulement sous le sommet plat des montagnes; (2) les débris de pente et les dépôts colluviaux présents dans les parties intermédiaires et les plus basses du versant; (3) la terrasse marine; et (4) le granite fracturé sous-jacent. La recharge des eaux souterraines par l’infiltration des précipitations varie dans l’espace en raison des variations de la pente du terrain, de la géologie et de l’occupation des sols. La recharge annuelle moyenne estimée à l’aide d’un modèle hydrologique de bilan en eau varie de 75 mm dans la zone la plus abrupte à 135 mm dans les zones plates les plus basses. Les eaux souterraines s’écoulent principalement à travers le régolithe et les formations détritiques, qui ont les plus fortes conductivités hydrauliques. Les eaux souterraines émergent dans les zones de suintement, aux sources, le long des principaux ruisseaux et en mer. Le modèle hydrogéologique conceptuel a été mis en œuvre dans un modèle d’écoulement des eaux souterraines, qui a ensuite été utilisé pour sélectionner le meilleur scénario de pompage. Les résultats du modèle montrent que les futurs besoins en eau pour l’approvisionnement en eau domestique et touristique peuvent être fournis en toute sécurité avec huit puits de pompage d’un débit maximum de 700 m3/jour. | [Resumen] La disponibilidad, la gestión y la protección de las aguas subterráneas es un gran reto para la sostenibilidad de los recursos hídricos subterráneos en las zonas rurales dispersas de las regiones atlánticas de Europa en las que las aguas subterráneas son la única opción para el suministro de agua. En este artículo se presenta un estudio hidrogeológico de la zona granítica costera de Oia en Galicia en el noroeste de España, con unas especiales características geomorfológicas e hidrogeológicas y pendientes que favorecen la erosión del granito meteorizado. El modelo conceptual hidrogeológico de la zona de estudio incluye: (1) la capa de regolito presente en la cumbre plana de la sierra costera; (2) los derrubios de ladera y los depósitos coluviales en las partes intermedias y bajas de la ladera; (3) la terraza marina; y (4) el granito fracturado subyacente. La recarga por infiltración de la precipitación varía espacialmente debido a la variabilidad espacial de la pendiente del terreno, la geología y el uso del suelo. La recarga media anual estimada con un modelo hidrológico de balance de agua oscila entre 75 mm en las zonas de mayor pendiente y 135 mm en las zonas llanas más bajas. El flujo subterráneo discurre principalmente a través del regolito y las formaciones detríticas que presentan las mayores conductividades hidráulicas. La descarga subterránea se produce en las zonas de rezume, los manantiales, los principales arroyos y en el mar. El modelo conceptual hidrogeológico se ha implementado en un modelo numérico de flujo subterráneo que posteriormente se ha utilizado para seleccionar el escenario óptimo de bombeo. Los resultados del modelo muestran que la futura demanda de agua para el abastecimiento doméstico y turístico se puede satisfacer de forma segura mediante ocho pozos de bombeo con un caudal punta de 700 m3/día. | [摘要] 地下水的可利用性, 管理和保护是欧洲大西洋地区分散的农村地区地下水资源可持续性的重要议题, 而地下水是这些地区唯一的供水选择。本文介绍了西班牙西北部Oia沿海花岗岩区的水文地质研究, 该地区具有独特的地貌和水文地质特征, 其陡峭的斜坡有利于风化花岗岩的侵蚀。研究区的水文地质概念模型包括:(1)仅存在于扁平化山峰的风化层; (2)山坡中部和最低处存在的坡积碎屑和崩积物; (3)海成阶地; (4)下伏的破碎花岗岩。由于地形坡度,地质和土地利用的变化, 地下水的降雨入渗补给在空间上也不同。采用水文水平衡模型估算的年均补给量从最陡的75 mm到最低平地的135 mm之间变化。地下水主要沿渗透系数最大的风化层和碎屑岩层流动。地下水排泄形式包括渗出区, 泉和沿小溪流入大海。概念性水文地质模型已用于建立地下水流模型, 之后用于优化抽水方案。模型结果表明采用八口开采井可以安全地满足生活和旅游用水的未来用水需求, 最高开采量可达700 m3/day。 | [Resumo] Disponibilidade, gestão e proteção das águas subterrâneas são grandes desafios para a sustentabilidade dos recursos hídricos subterrâneos nas áreas rurais dispersas das regiões atlânticas da Europa onde as águas subterrâneas são a única opção de abastecimento. Esse artigo apresenta um estudo hidrogeológico da área granítica costeira de Oia, no noroeste da Espanha, que apresenta características geomorfologias e hidrogeológicas únicas com encostas íngremes que favorecem a erosão do granito intemperizado. O modelo conceitual hidrogeológico da área de estudo inclui: (1) a camada regolítica, que está presente apenas no cume plano das montanhas; (2) os entulhos de encosta e os depósitos coluviais, que estão presentes nas partes intermediarias e mais baixas da encosta; (3) o terraço marinho; e (4) o granito fraturado subjacente. A recarga das águas subterrâneas pela infiltração da chuva varia espacialmente devido a variações na inclinação do terreno, geologia e uso da terra. A recarga média anual estimada com um modelo de balanço hídrico varia de 75 mm na zona mais íngreme a 135 mm nas áreas planas mais baixas. A água subterrânea flui principalmente através do regolito e das formações detríticas, que possuem as maiores condutividades. As águas subterrâneas descarregam em áreas de infiltração, nascentes, ao longo dos riachos principais e no mar. O modelo hidrogeológico conceitual foi implementado em um modelo de fluxo de água subterrânea, que posteriormente foi usado para selecionar o melhor cenário de bombeamento. Os resultados do modelo mostram que as necessidades futuras de água para abastecimento doméstico e turístico podem ser fornecidas com segurança com oito poços de bombeamento com uma vazão máxima de 700 m3/dia. | This work has been funded by the Water Authority of the Galician Regional Government (Xunta de Galicia), the Spanish Ministry of Economy and Competitiveness (Project PID2019-109544RB-I00), FEDER funds and the Galician Regional Government, Xunta de Galicia (Grant number ED431C 2017/57) from “Consolidación e estruturación de unidades de investigación competitivas”, Grupos de referencia competitiva | Xunta de Galicia; ED431C 2017/57
显示更多 [+] 显示较少 [-]An analytical methodology to estimate the changes in fresh groundwater resources with sea-level rise and coastal erosion in strip-island unconfined aquifers: illustration with Savary Island, Canada | Méthode analytique visant à estimer les changements des ressources d’eau douce souterraines liée à la montée du niveau de la mer et à l’érosion côtière dans les aquifères libres des îles étroites: illustration avec l’île de Savary, Canada Metodología analítica para estimar los cambios en los recursos hídricos subterráneos de agua dulce con la elevación del nivel del mar y la erosión en los acuíferos no confinados de la franja de islas costeras: un ejemplo en la isla de Savary (Canadá) 估算带状岛屿潜水含水层中随海平面上升和海岸侵蚀而引起的地下淡水资源变化的解析法:以加拿大Savary岛为例 Uma metodologia analítica para estimar as mudanças nos recursos de água doce subterrânea com a elevação do nível do mar e erosão costeira em aquíferos não confinados em faixa insular: exemplo da Ilha de Savary, Canadá 全文
2021
Chesnaux, R. | Marion, D. | Boumaiza, L. | Richard, S. | Walter, J.
Closed-form analytical solutions for assessing the consequences of climate change on fresh groundwater oceanic island lenses have been developed by hydrogeologists during the last decade. Based on existing equations, this study focuses on the case of strip oceanic islands when three combined effects of climate change are observed to affect the freshwater lens volume and its groundwater resource renewal: sea-level rise, erosion, and change in groundwater recharge rates. New equations, integrating these combined effects of climate change on fresh groundwater resources are provided. These equations are solved by a novel methodology based on a Dupuit-Forchheimer groundwater flow model that allows for determination of the hydrogeological parameters included in the equations. The approach is illustrated with the strip island of Savary, which is located along the Pacific Coast of Canada in the province of British Columbia. This example illustrates, on the one hand, the volume depletion of the island freshwater lens and, on the other hand, the decrease of the renewal rate of groundwater. The proposed approach can be applied to any strip islands worldwide to assess the cumulative effects of sea-level rise and shore erosion on groundwater resources, depending on the predicted climate change scenarios. The results can then help decision-makers to anticipate the effects of climate change on the groundwater availability in strip oceanic islands and plan future groundwater use accordingly.
显示更多 [+] 显示较少 [-]Fate of nitrate during groundwater recharge in a fractured karst aquifer in Southwest Germany | Devenir des nitrates lors de la recharge en eau souterraine d’un aquifère karstique fracturé dans le Sud-Ouest de l’Allemagne Destino del nitrato cuando se recarga el agua subterránea en un acuífero kárstico fracturado en el suroeste de Alemania 德国西南部裂隙岩溶含水层地下水补给过程中的硝酸盐归宿 Destino do nitrato durante recarga de águas subterrâneas em um aquífero cárstico fissural no sudoeste da Alemanha 全文
2021
Visser, Anna-Neva | Lehmann, Moritz F. | Rügner, Hermann | D’Affonseca, Fernando Mazo | Grathwohl, Peter | Blackwell, Nia | Kappler, Andreas | Osenbrück, Karsten
Over the past decades, fractured and karst groundwater systems have been studied intensively due to their high vulnerability to nitrate (NO₃⁻) contamination, yet nitrogen (N) turnover processes within the recharge area are still poorly understood. This study investigated the role of the karstified recharge area in NO₃⁻ transfer and turnover by combining isotopic analysis of NO₃⁻ and nitrite (NO₂⁻) with time series data of hydraulic heads and specific electrical conductivity from groundwater monitoring wells and a karstic spring in Germany. A large spatial variability of groundwater NO₃⁻ concentrations (0.1–0.8 mM) was observed, which cannot be explained solely by agricultural land use. Natural-abundance N and O isotope measurements of NO₃⁻ (δ¹⁵N and δ¹⁸O) confirm that NO₃⁻ derives mainly from manure or fertilizer applications. Fractional N elimination by denitrification is indicated by relatively high δ¹⁵N- and δ¹⁸O-NO₃⁻ values, elevated NO₂⁻ concentrations (0.05–0.14 mM), and δ¹⁵N-NO₂⁻ values that were systematically lower than the corresponding values of δ¹⁵N-NO₃⁻. Hydraulic and chemical response patterns of groundwater wells suggest that rain events result in the displacement of water from transient storage compartments such as the epikarst or the fissure network of the phreatic zone. Although O₂ levels of the investigated groundwaters were close to saturation, local denitrification might be promoted in microoxic or anoxic niches formed in the ferrous iron-bearing carbonate rock formations. The results revealed that (temporarily) saturated fissure networks in the phreatic zone and the epikarst may play an important role in N turnover during the recharge of fractured aquifers.
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