In this paper we have pointed out the hydrogeological condition in the catchment area of the Jablanica river in the south Serbia (Yugoslavia). The two units are separately presented here. The first one is mountainous part of the catchment area upstream of the gaging station of Lebane and the second one is the part of the terrain in the plain down stream to the river mounth near Pecenjevac. The hydrogeological characteristics of the two mentioned regions are given to explain the reasons of existing the constant flow of the Jablanica to Lebane and its disappearing course in the period of recession in the plain downstream. The quality of water in the Jablanica river at Lebane is good. Down stream of this gaging station the waste water collector flows into the river. In the part of recession period the ratio between them is unfavourable. We have also discussed the quality of water at the gaging station of Pecenjevac and pointed out the function of sandy-gravel deposits in the process of natural purification of the Jablanica flow.

Geochemical cycling of iron (Fe) mediated by sediment microbes drives the remobilization of phosphorus (P). Understanding the underlying mechanism is essential for the evaluation of P retention by wetlands. The diffusive gradients in thin film (DGT) and 16S rDNA sequencing techniques were combined to explore seasonal variations in the remobilization mechanism of sediment P in a free water surface wetland in southwest China. A significantly positive correlation between labile P and Fe concentrations was found from the sediment profiles, indicating coupled remobilization of Fe and P in the sediment. Fe-reducing bacterial genera, particularly Sphingomonas and Geothermobacter, were responsible for the reductive dissolution of Fe oxides and subsequent P release in sediment. The efflux of sediment P was higher in the rainy season (95 ± 87 ng cm⁻² d⁻¹) than in the dry season (39 ± 29 ng cm⁻² d⁻¹). Based on the significantly positive relationship between the efflux and total concentration of sediment P, we propose a promising regression equation for quantifying the release risk of sediment P. The Luoshijiang Wetland exhibited a higher release potential as indicated by a greater regression slope (0.558) compared to the other water bodies (0.055), which was mainly attributed to the lower labile Fe:P molar ratio in the sediment. Based on estimations of the diffusive flux of P at the sediment-water interface, sediment contributed more than 172 and 413 g of P per day to the water column in the dry and rainy seasons, respectively, accounting for 14.0% and 1.9% of the P mass in the surface water of the wetland.

Urban stormwater is an important pathway for transporting anthropogenic pollutants to water bodies. Phthalate esters (PAEs) are endocrine disruptors owing to their estrogenic activity and potential carcinogenicity and their ubiquitous presence has garnered global interest. However, their transportation by urban stormwater has been largely overlooked. This study, for the first time, investigated 15 PAEs in stormwater from six major stormwater drains in the highly urbanized Hong Kong, a major metropolitan city in China. The results showed that PAEs were ubiquitous in the stormwater of Hong Kong, with total concentrations (∑₁₅PAEs) spanning from 195 to 80,500 ng/L. Bis(2-n-butoxyethyl) phthalate (DBEP), diisopentyl phthalate (DiPP), dicyclohexyl phthalate (DCHP) and di-n-pentyl phthalate (DnPP) were detected in stormwater for the first time. Spatial variations in PAEs were observed among different stormwater drains, possibly due to the different land use patterns and intensities of human activities in their respective catchments. The highest and lowest levels of ∑₁₅PAEs were found in Kwai Chung (3860 ± 1960 ng/L) and the Ng Tung River (672 ± 557 ng/L), respectively. Additionally, significantly higher concentrations of ∑₁₅PAEs in stormwater were found in the wet season (2520 ± 2050 ng/L) than in the dry season (947 ± 904 ng/L). Principal component analysis classified domestic and industrial origins as two important sources of PAEs in the stormwater of Hong Kong. Stormwater played a crucial role in transporting PAEs, with an estimated annual flux of 0.705–29.4 kg. Thus, possible stormwater management measures were proposed to protect the receiving environment and local ecosystems from stormwater.

Atmospheric size-classified particles in sizes ranging from small to nanoparticles (PM₀.₁) are reported for Rangsit City in the Bangkok Metropolitan Region (BMR) of Thailand, for October 2019 (wet season) and January–February 2020 (dry season). The sampling involved the use of a PM₀.₁ cascade air sampler to determine the mass concentration. The PMs consisted of six stages including TSP–PM₁₀, PM₂.₅₋₁₀, PM₁.₀₋₂.₅, PM₀.₅₋₁.₀, PM₀.₅₋₁.₀ and PM₀.₁. Elemental carbon (EC) and organic carbon (OC) were evaluated by a carbon analyzer following the IMPROVE_TOR protocol. The average PM₀.₁ mass concentrations were found to be 13.47 ± 0.79 (wet season) and 18.88 ± 3.99 (dry season) μg/m³, respectively. The average OC/EC ratio for the rainy season was lower than that in the dry season. The char-EC/soot-EC ratios were consistently below 1 for the PM₀.₁ fraction in both seasons indicating that vehicular traffic appeared to be the main emission source. However, the influence of open biomass burning on fine and coarse PM particles on local air pollution was found to be an important issue during the wet season. In addition, long-range transport from other countries may also contribute to the carbon content in the Bangkok Metropolitan Region (BMR) atmosphere during the dry season. The higher secondary organic carbon to organic carbon (SOC/OC) ratio in the dry season is indicative of the contribution of secondary sources to the formation of PM, especially finer particles. A strong correlation between OC and EC in nanoparticles was found, indicating that they are derived from sources of constant emission, likely the diesel engines. Conversely, the OC and EC correlation for other size-specific PMs decreased during the dry season, indicating that these emission sources were more varied.

Perennial contaminated groundwater seepage is threatening the downstream ecosystem of the Kazipally Pharmaceutical industrial area located in South India. The sources of seepage are unknown for the last three decades that challenging the regulatory authorities and industries. In general, water quality monitoring and geophysical techniques are applied to identify the sources. However, these techniques may lead to ambiguous results and fail to identify the seepage sources, especially when the area is urbanized/paved, and groundwater is already contaminated with other leakage sources that have similar chemical compounds. In the present study, a novel and multidisciplinary approach were adopted that includes satellite-based Land Surface Temperature (LST) observations, field-based Electrical Resistivity Tomography (ERT), continuous Soil Electrical Conductivity (SEC) and Volumetric Soil Moisture (VSM%) measurements along with groundwater levels monitoring to identify the sources and to control the seepage. The integrated results identified that the locations with the Standard Thermal Anomaly (STA) in the range of −0.5 to -1 °C, VSM% >50%, SEC > 1.5 mS/cm, bulk resistivity < 12 Ω m with shallow groundwater levels < 3 m below ground level (bgl) are potentially contaminated perennial seepage sources. Impermeable sheet piles have been installed across the groundwater flow direction to control the seepage up to 1.5 m bgl, where groundwater frequently intercepts land surface. The quantity of dry season groundwater seepage has been declined by 79.2% after these interventions, which in turn minimized the treatment cost of 1,96,283 USD/year and improved the downstream ecosystem.

Understanding wetland water quality dynamics and associated influencing factors is important to assess the numerous ecosystem services they provide. We present a combined self-organizing map (SOM) and linear mixed-effects model (LMEM) to relate water quality variation of multipond systems (MPSs, a common type of non-floodplain wetlands in agricultural regions of southern China) to their extrinsic and intrinsic influences for the first time. Across the 6 test MPSs with environmental gradients, ammonium nitrogen (NH₄⁺-N), total nitrogen (TN), and total phosphate (TP) almost always exceeded the surface water quality standard (2.0, 2.0, and 0.4 mg/L, respectively) in the up- and midstream ponds, while chlorophyll-a (Chl-a) exhibited hypertrophic state (≥28 μg/L) in the midstream ponds during the wet season. Synergistic influences explained 69±12% and 73±10% of the water quality variations in the wet and dry season, respectively. The adverse, extrinsic influences were generally 1.4, 6.9, 3.2, and 4.3 times of the beneficial, intrinsic influences for NH₄⁺-N, nitrate nitrogen (NO₃⁻-N), TP, and potassium permanganate index (CODMₙ), respectively, although the influencing direction and degree of forest and water area proportion were spatiotemporally unstable. While CODMₙ was primarily linked with rural residential areas in the midstream, higher TN and TP concentrations in the up- and midstream were associated with agricultural land, and NH₄⁺-N reflected a small but non-negligible source of free-range poultry feeding. Pond surface sediments exhibited consistent, adverse effects with amplifications during rainfall, while macrophyte biomass can reflect the biological uptake of CODMₙ and Chl-a, especially in the mid- and downstream during the wet season. Our study advances nonpoint source pollution (NPSP) research for small water bodies, explores nutrient “source-sink” dynamics, and provides a timely guide for rural planning and pond management. The modelling procedures and analytical results can inform refined assessment of similar NFWs elsewhere, where restoration efforts are required.

This study focused on the seasonal variation and source identification of heavy metals (HMs) while considering effects of municipal wastewater (MWW) in peri-urban farms of Hue city, central Vietnam. Moreover, associated non-carcinogenic and carcinogenic health risks from consuming vegetables containing HMs were also assessed considering the hazard quotient and cancer risk, respectively. Therefore, concentrations of Fe, Mn, Zn, Cu, Cr, Cd, Pb, and As were determined in irrigation water, soil, and lettuce samples collected during dry and wet seasons from one upstream site where irrigation water has no impact on MWW as well as from two downstream sites in farms on the outskirt of the city. Although irrigation water and soil in the same farms were not polluted as strongly, lettuce samples were polluted with Cd, Zn, and Pb. Furthermore, levels of soil Cu and As and HMs (except for Cu) in lettuce in the wet season were significantly higher (p < 0.05) than those in the dry season, indicating the impact of MWW with seasonal change. The health risk assessment via lettuce consumption demonstrated an unacceptable carcinogenic risk owing to Cd and a cumulative non-carcinogenic risk owing to selected HMs in the lettuce, while all other risks were negligible. Correlation and principal component analyses were performed to identify HM sources, indicating that Cu, Zn, Cd, Pb, Cr, and As in irrigation water and soil could have anthropogenic sources (e.g., untreated MWW, fertilizer use); meanwhile, irrigation-water and soil Fe, Mn, As, and Cr could originate from non-anthropogenic sources (e.g., parent materials weathering). This study revealed that rapid urbanization together with high precipitation leading to urban floods in Hue city was a significant factor spreading HMs in agricultural farms, suggesting the importance of wastewater treatment system, which can reduce the HM load in the city to protect the local food production.

Experimental data on the contribution of a dump site in Tanzania as a point source of the 17 possible congeners of PCDD/Fs to the environment is presented. Dry and wet season samples were collected around Pugu municipal dump site followed by GCxGC-TOFMS analysis. The dominant congeners were OctaCDD, 1,2,3,4,6,7,8-HepCDF; 1,2,3,4,6,7,8-HeptaCDD and 1,2,4,7-PeCDD. The concentrations of the congeners expressed as TEQ WHO₂₀₀₅ ranged from 11.69 to 48.97 pg/g with a mean of 29.44 pg/g for the dry season and TEQ WHO₂₀₀₅ 4.13–85.82 pg/g with a mean of 41.51 pg/g for the wet season. These levels were speculated high enough to accumulate in free-range chickens and cause harmful effects to humans that consumed them especially residents around Pugu dump site. Exposure of people to PCDD/Fs through dermal absorption and soil ingestion were estimated using the VLIER-HUMAAN Mathematical model. Exposure through dermal absorption was estimated to be 1.2 × 10⁻⁴ and 9.8 × 10⁻⁶ ng TEQ/kg day for children and adults respectively while through soil ingestion via consumption of contaminated foods and other sources was 0.0045 and 0.27 ng TEQ/kg day for children and adults respectively. These values however were well below the WHO tolerable daily intake. Generally, there was no significant variation for total PCDD/Fs in the dry and wet season (α = 0.08). Strong positive correlation (r = 0.94) between total PCDD/Fs and organic matter content was observed during the wet season.

Evolution of the microbial community structure in crude oil contaminated marine sediments was assessed under aerobic biodegradation during wet (18 °C) and dry (28 °C) seasons experiments, to account for seasonal variations in nutrients and temperature, under biostimulation and natural attenuation conditions. NMDS showed significant variation in the microbial communities between the wet and the dry season experiments, and between the biostimulation and the natural attenuation treatments in the dry season microcosms. No significant variation in the microbial community and oil biodegradation was observed during the wet season experiments due to high background nitrogen levels eliminating the effect of biostimulation. Larger variations were observed in the dry season experiments and were correlated to enhanced alkanes removal in the biostimulated microcosms, where Alphaproteobacteria dominated the total microbial community by the end of biodegradation (54%). Many hydrocarbonoclastic bacterial genera showed successive dominance during the operation affecting the ultimate performance of the microcosms.

The occurrence, distribution, and ecological risk of 10 quinolones (QNs) were investigated in the water and sediment samples from Baiyangdian Lake, China. The field samplings were conducted in April (dry season) and August (wet season) 2018, the results showed that QNs was extensively distributed in the Baiyangdian Lake. For the occurrence, Flumequine (FLU) and Ofloxacin (OFL) were the most detected QNs in Baiyangdian Lake. For the temporal variation, the sum concentration of QNs in water and sediment were ranged from 153 ng/L to 3093 ng/L and from 40.1 ng/g to 1475 ng/g in April, while ranged from 3.83 ng/L to 769 ng/L and from 20.3 ng/g to 373 ng/g in August. For the spatial variation, all of QNs exhibited significance difference in concentration at different sampling areas. Furthermore, PNEC plays an important role in ecological risk assessment, thus the PNECs of FLU and OFL were derived by assessment factors (AF), species sensitivity distribution (SSD), and AQUATOX model methods. The results showed that: PNECAFs, PNECSSDs, and PNECAQUATOXs were 18.7 μg/L, 196 μg/L, and 128 μg/L for FLU, respectively; and were 0.021 μg/L, 4.40 μg/L, and 3.00 μg/L for OFL, respectively. The PNECs for FLU and OFL derived by three approaches showed the rank of: PNECSSDs > PNECAQUATOXs > PNECAFs; while the risk quotients (RQs) followed the other rank of: RQSSDs < RQAQUATOXs < RQAFs. The results was indicated that the indirect ecological effects plays an important role in the derived PNECs for QNs, without considering the indirect ecological effects in natural ecosystem can lead to under-protective or over-protective PNECs (RQs) for chemicals. Therefore, AQUATOX model can be applied in deriving PNECs during the ecological risk assessment.