Difluoro(trimethylsilyl)acetonitrile: Synthesis and Fluoroalkylation Reactions
2012
Kosobokov, Mikhail D. | Dilman, Alexander D. | Levin, Vitalij V. | Struchkova, Marina I.
A new silicon reagent, difluoro(trimethylsilyl)acetonitrile, was prepared by insertion of difluorocarbene into silyl cyanide. The obtained silane served as a good cyanodifluoromethylating reagent toward aldehydes, N-tosylimines, N-alkylimines, and enamines under basic or acidic conditions.
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