Tetrathiafulvalene-annulated [28]hexaphyrin(1.1.1.1.1.1): a multi-electron donor system subject to conformational control
2013
Jana, Atanu | Ishida, Masatoshi | Cho, Kevin | Ghosh, Sudip Kumar | Kwak, Kyuju | Ohkubo, Kei | Sung, Young Mo | Davis, Christina M. | Lynch, Vincent M. | Lee, Dongil | Fukuzumi, Shunichi | Kim, Dongho | Sessler, Jonathan L.
Tetrathiafulvalenes (TTF)-annulated [28]hexaphyrin affords an electron rich flexible π-conjugated system whose limiting conformations can be controlled through choice of solvents. The conformation-dependent intramolecular charge transfer character, as well as electron reserve capability of the hexakis-TTF annulated hexaphyrin, was analyzed.
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