Total synthesis of granulodione

Kasamatsu, Akihiko; Kuwabara, Motoi; Matsuzawa, Akinobu; Sugita, Kazuyuki

Total synthesis of granulodione

2019

Kasamatsu, Akihiko | Kuwabara, Motoi | Matsuzawa, Akinobu | Sugita, Kazuyuki

In this paper, we report the total synthesis of a sesquiterpene, granulodione, having a 15-norilludane skeleton. The coupling of two fragments 3 and 4 via aldol condensation, followed by Saegusa oxidation, SmI2-mediated cyclization, and oxidation enabled expeditious and efficient synthesis of granulodione.

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AGROVOC Keywords

chemical structure oxidation sesquiterpenoids

Bibliographic information

Published in

Tetrahedron letters

Volume 60 Issue 2 Pagination 113 - 114 ISSN 0040-4039

Publisher

Boston : Springer US

Other Subjects

Condensation reactions; Samarium(ii) iodide; Granulodione; Norilludane; Total synthesis; Reductive cyclization

Language

English

Type

Journal Article; Text

In AGRIS since: 2024-02-28

Format: MODS

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DOI DOI https://dx.doi.org/10.1016/j.tetlet.2018.11.069

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Total synthesis of granulodione

2019

AGROVOC Keywords

Bibliographic information