Total synthesis of granulodione
2019
Kasamatsu, Akihiko | Kuwabara, Motoi | Matsuzawa, Akinobu | Sugita, Kazuyuki
In this paper, we report the total synthesis of a sesquiterpene, granulodione, having a 15-norilludane skeleton. The coupling of two fragments 3 and 4 via aldol condensation, followed by Saegusa oxidation, SmI2-mediated cyclization, and oxidation enabled expeditious and efficient synthesis of granulodione.
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Эту запись предоставил National Agricultural Library