Desymmetrization of meso-dienyne by asymmetric Pauson–Khand type reaction catalysts
2004
Jeong, Nakcheol | Kim, Dong Hoon | Choi, Jun Hun
Desymmetrization of the meso dienynes, such as propargyl 1-vinylallyl N-tosylamides (1a–c) and propargyl 1-vinylallyl ethers (1d–e), by asymmetric Pauson–Khand type reaction catalysts was studied. The corresponding vinyl substituted bicyclic pentenones (2 and 3) were obtained with high diastereoselectivity and enantioselectivity.
Show more [+] Less [-]AGROVOC Keywords
Bibliographic information
This bibliographic record has been provided by National Agricultural Library