Desymmetrization of meso-dienyne by asymmetric Pauson–Khand type reaction catalysts
2004
Jeong, Nakcheol | Kim, Dong Hoon | Choi, Jun Hun
Desymmetrization of the meso dienynes, such as propargyl 1-vinylallyl N-tosylamides (1a–c) and propargyl 1-vinylallyl ethers (1d–e), by asymmetric Pauson–Khand type reaction catalysts was studied. The corresponding vinyl substituted bicyclic pentenones (2 and 3) were obtained with high diastereoselectivity and enantioselectivity.
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书目信息
出版者
The Royal Society of Chemistry
其它主题
Diastereoselectivity; Enantioselectivity
语言
英语
类型
Journal Article; Text
2024-02-28
MODS