A concise synthesis of (±)-3-deoxyisoaltholactone
2014
Fearnley, Stephen Philip | Lory, Pedro
The novel styryl lactone analog (±)-3-deoxyisoaltholactone was synthesized in 5 steps from dihydrofuran. An intramolecular vinylsilane–oxocarbenium condensation thus afforded the central cis-fused bicyclic ether array in near quantitative yield as a single stereoisomer.
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Bibliographic information
Publisher
Elsevier Ltd
Other Subjects
Cis-fused ether array; Vinylsilane; Styryl lactone; Stereoisomers; Isoaltholactone; Oxocarbenium
Language
English
Type
Journal Article; Text
2024-02-28
MODS
Data Provider
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