A concise synthesis of (±)-3-deoxyisoaltholactone
2014
Fearnley, Stephen Philip | Lory, Pedro
The novel styryl lactone analog (±)-3-deoxyisoaltholactone was synthesized in 5 steps from dihydrofuran. An intramolecular vinylsilane–oxocarbenium condensation thus afforded the central cis-fused bicyclic ether array in near quantitative yield as a single stereoisomer.
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