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The Impact of RDF Valorization on the Leachate Quality and on Emissions from Cement Kiln (Case Study of a Region in Morocco)
2021
Ouigmane, Abdellah | Boudouch, Otmane | Hasib, Aziz | Ouhsine, Omar | Abba, El Hassan | Isaifan, Rima J. | Berkani, Mohamed
Energy recovery is a sustainable method of municipal solid waste (MSW) management. The co-incineration of refuse derived fuel (RDF) has shown several economic and environmental advantages. The objective of this research is to assess the impact of RDF recovery on leachate quality using leachate tests and calculation of greenhouse gases (GHG) reduction in the kilns of a cement plant. The qualitative results of the eluate show that there is an impact on leachate quality depending on the type of waste. The values of the chemical oxygen demand (COD), biological oxygen demand (BOD5), electrical conductivity and pH of the leachate from the raw waste after 120 hours of leaching are 29.33 gO2/kg DM, 14.00 g O2/kg DM, 4.27 ms/cm and 7.57. On the other hand, the values of the same quality parameters of the eluate generated by the waste without RDF are 19.33 g O2/kg DM, 20.67 g O2/kg DM, 2.77 ms/cm and 7.13; respectively. The calculation of GHG reduction shows that the substitution of 83,000 tonnes per year of petroleum coke by 15% of RDF (25,493 tonnes per year) can reduces 28,970 tCO2 eq.
Show more [+] Less [-]Application of a Decision-Making Model to Reduce CO2 Emissions in Iran (Case Study: CHP-CCS technology and renewable energy)
2020
Alinejad, H. R. | Behbahaninia, A. | Mackialeagha, M.
Iran is one of the largest producers of CO2 in the world. Therefore, in order to lessen its greenhouse gas production, thus complying with the Intended Nationally Determined Contributions (INDCs), it should cut its CO2 emissions by about 4% by 2030, compared to 2010. Hence this paper aims at finding an early solution to this problem. Because the country's electricity sector is responsible for the highest annual CO2 emissions, the paper focuses on two technologies that can effectively reduce CO2 emissions from the electricity sector, namely renewable energy and Combined Heat And Power Plants (CHP) with CO2 capture and storage (CCS). Further it assesses adoption of these technologies and their impact on Iran's annual CO2 emission by 2030, considering two main scenarios: the optimistic scenario (OS) which assumes that the policies of the Sixth Development Plan (SDP) will be fully realized as well as the fair scenario (FS) which believes that SDP policies will be followed to some extent by the end of the program. To this end, twenty six micro-factors, affecting CO2 emissions, have been identified and classified into five different groups. The detected micro factors are then introduced to a Gradient Boosting Decision Tree (GBDT) Algorithm to identify the most important specific microscopic factors in Iran. The final detected micro-factors have finally been included in a Gaussian regression model to predict CO2 emissions in Iran by 2030. The findings suggest that if Iran intends to comply with the INDCs, CHP-CCS technology is a solution that has an early return, compared to renewable technologies.
Show more [+] Less [-]Anthropogenic nitrate attenuation versus nitrous oxide release from a woodchip bioreactor
2022
White, Shane A. | Morris, Shaun A. | Wadnerkar, Praktan D. | Woodrow, Rebecca L. | Tucker, James P. | Holloway, Ceylena J. | Conrad, Stephen R. | Sanders, Christian J. | Hessey, Samantha | Santos, Isaac R.
Nitrogen loss via overland flow from agricultural land use is a global threat to waterways. On-farm denitrifying woodchip bioreactors can mitigate NO₃⁻ exports by increasing denitrification capacity. However, denitrification in sub-optimal conditions releases the greenhouse gas nitrous oxide (N₂O), swapping the pollution from aquatic to atmospheric reservoirs. Here, we assess NO₃⁻-N removal and N₂O emissions from a new edge-of-field surface-flow bioreactor during ten rain events on intensive farming land. Nitrate removal rates (NRR) varied between 5.4 and 76.2 g NO₃⁻-N m⁻³ wetted woodchip d⁻¹ with a mean of 30.3 ± 7.3 g NO₃⁻-N m⁻³. The nitrate removal efficiency (NRE) was ∼73% in ideal hydrological conditions and ∼18% in non-ideal conditions. The fraction of NO₃⁻-N converted to N₂O (rN₂O) in the bioreactor was ∼3.3 fold lower than the expected 0.75% IPCC emission factor. We update the global bioreactor estimated Q₁₀ (NRR increase every 10 °C) from a recent meta-analysis with previously unavailable data to >20 °C, yielding a new global Q₁₀ factor of 3.1. Mean N₂O CO₂-eq emissions (431.9 ± 125.4 g CO₂-eq emissions day⁻¹) indicate that the bioreactor was not significantly swapping aquatic NO₃⁻ for N₂O pollution. Our estimated NO₃⁻-N removal from the bioreactor (9.9 kg NO₃⁻-N ha⁻¹ yr⁻¹) costs US$13.14 per kg NO₃⁻-N removed and represents ∼30% NO₃⁻-N removal when incorporating all flow and overflow events. Overall, edge-of-field surface-flow bioreactors seem to be a cost-effective solution to reduce NO₃⁻-N runoff with minor pollution swapping to N₂O.
Show more [+] Less [-]Up in smoke: California's greenhouse gas reductions could be wiped out by 2020 wildfires
2022
Jerrett, Michael | Jina, Amir S. | Marlier, Miriam E.
In this short communication, we estimate that California's wildfire carbon dioxide equivalent (CO₂e) emissions from 2020 are approximately two times higher than California's total greenhouse gas (GHG) emission reductions since 2003. Without considering future vegetation regrowth, CO₂e emissions from the 2020 wildfires could be the second most important source in the state above either industry or electrical power generation. Regrowth may partly of fully occur over a long period, but due to exigencies of the climate crisis most of the regrowth will not occur quickly enough to avert greater than 1.5 degrees of warming. Global monetized damages caused by CO₂e from in 2020 wildfire emissions amount to some $7.1 billion USD. Our analysis suggests that significant societal benefits could accrue from larger investments in improved forest management and stricter controls on new development in fire-prone areas at the wildland-urban interface.
Show more [+] Less [-]Effect of microbial community structures and metabolite profile on greenhouse gas emissions in rice varieties
2022
Ding, Huina | Liu, Tianqi | Hu, Quanyi | Liu, Min | Cai, Mingli | Jiang, Yang | Cao, Cougui
Rice paddy fields are major sources of atmospheric methane (CH₄) and nitrous oxide (N₂O). Rice variety is an important factor affecting CH₄ and N₂O emissions. However, the interactive effects of rice metabolites and microorganisms on CH₄ and N₂O emissions in paddy fields are not clearly understood. In this study, a high greenhouse gas-emitting cultivar (YL 6) and a low greenhouse gas-emitting cultivar (YY 1540) were used as experimental materials. Metabolomics was used to examine the roots, root exudates, and bulk soil metabolites. High-throughput sequencing was used to determine the microbial community composition. YY 1540 had more secondary metabolites (flavonoids and isoflavonoids) in root exudates than YL 6. It was enriched with the uncultured members of the families Gemmatimonadanceae and Rhizobiales_Incertae_Sedis in bulk soil, and genera Burkholderia-Caballeronia-Paraburkholderia, Magnetospirillum, Aeromonas, and Anaeromyxobacter in roots, contributing to increased expression of pmoA and nosZ genes and reducing CH₄ and N₂O emissions. YL 6 roots and root exudates contained higher contents of carbohydrates [e.g., 6-O- acetylarbutin and 2-(3- hydroxyphenyl) ethanol 1′-glucoside] than those of YY 1540. They were enriched with genera RBG-16-58-14 in bulk soil and Exiguobacterium, and uncultured member of the Kineosporiaceae family in roots, which contributed to increased expression of mcrA, ammonia-oxidizing archaea, ammonia-oxidizing bacteria, nirS, and nirK genes and greenhouse gas emissions. In general, these results established a link between metabolites, microorganisms, microbial functional genes, and greenhouse gas emissions. The metabolites of root exudates and roots regulated CH₄ and N₂O emissions by influencing the microbial community composition in bulk soil and roots.
Show more [+] Less [-]Investigating detection probability of mobile survey solutions for natural gas pipeline leaks under different atmospheric conditions
2022
Tian, Shanru | Riddick, Stuart N. | Cho, Younki | Bell, Clay S. | Zimmerle, Daniel J. | Smits, Kathleen M.
The 2015 Paris agreement aims to cut greenhouse gas emissions and keep global temperature rise below 2 °C above pre-industrial levels. Reducing CH₄ emissions from leaking pipelines presents a relatively achievable objective. While walking and driving surveys are commonly used to detect leaks, the detection probability (DP) is poorly characterized. This study aims to investigate how leak rates, survey distance and speed, and atmospheric conditions affect the DP in controlled belowground conditions with release rates of 0.5–8.5 g min⁻¹. Results show that DP is highly influenced by survey speed, atmospheric stability, and wind speed. The average DP in Pasquill–Gifford stability (PG) class A is 85% at a low survey speed (2–11 mph) and decreases to 68%, 63%, 65%, and 60% in PGSC B/C, D, E/F, and G respectively. It is generally less than 25% at a high survey speed (22–34 mph), regardless of stability conditions and leak rates. Using the measurement data, a validated DP model was further constructed and showed good performance (R2: 0.76). The options of modeled favorable weather conditions (i.e., PG stability class and wind speed) to have a high DP (e.g., >50%) are rapidly decreased with the increase in survey speed. Walking survey is applicable over a wider range of weather conditions, including PG stability class A to E/F and calm to medium winds (0–5 m s⁻¹). A driving survey at a low speed (11 mph) can only be conducted under calm to low wind speed conditions (0–3 m s⁻¹) to have an equivalent DP to a walking survey. Only calm wind conditions in PG A (0–1 m s⁻¹) are appropriate for a high driving speed (34 mph). These findings showed that driving survey providers need to optimize the survey schemes to achieve a DP equivalence to the traditional walking survey.
Show more [+] Less [-]Effects of increasing organic nitrogen inputs on CO2, CH4, and N2O fluxes in a temperate grassland
2021
Chen, Jihui | Zhang, Yingjun | Yang, Yi | Tao, Tingting | Sun, Xiao | Guo, Peng
Understanding future climate change requires accurate estimates of the impacts of atmospheric nitrogen (N) deposition, composed of both inorganic and organic compounds, on greenhouse gas (GHG) fluxes in grassland ecosystems. However, previous studies have focused on inorganic compounds and have not considered the potential effects of organic N sources. Here, we conducted a grassland experiment that included organic, inorganic N, and a mix of them at a ratio of 4:6, with two input rates, to study N inputs induced CO₂, CH₄, and N₂O fluxes, as well as the potential abiotic and biotic mechanisms driving the fluxes. We found that N compositions significantly affected fluxes each of the three GHGs. Greater organic N decreased the impacts of N addition on CO₂ and N₂O emissions, caused primarily by low rates of increase in substrates (soil available N) for production of CO₂ and N₂O resulting from high ammonia volatilization rather than changes in microbial activity. Also, greater organic N slightly stimulated CH₄ uptake. Nitrogen composition effects on CO₂ emissions and CH₄ uptake were independent of N input rates and measurement dates, but N₂O emissions showed stronger responses to inorganic N under high N addition and in June. These results suggest that future studies should consider the source of N to improve our prediction of future climate impact of N deposition, and that management of N fertilization can help mitigate GHG emissions.
Show more [+] Less [-]How far climatic parameters associated with air quality induced risk state (AQiRS) during COVID-19 persuaded lockdown in India
2021
Mahato, Susanta | Talukdar, Swapan | Pal, Swades | Debanshi, Sandipta
Global temperature rises in response to accumulating greenhouse gases is a well-debated issue in the present time. Historical records show that greenhouse gases positively influence temperature. Lockdown incident has brought an opportunity to justify the relation between greenhouse gas centric air pollutants and climatic variables considering a concise period. The present work has intended to explore the trend of air quality parameters, and air quality induced risk state since pre to during the lockdown period in reference to India and justifies the influence of pollutant parameters on climatic variables. Results showed that after implementation of lockdown, about 70% area experienced air quality improvement during the lockdown. The hazardous area was reduced from 7.52% to 5.17%. The spatial association between air quality components and climatic variables were not found very strong in all the cases. Still, statistically, a significant relation was observed in the case of surface pressure and moisture. From this, it can be stated that pollutant components can control the climatic components. This study recommends that pollution source management could be a partially good step for bringing climatic resilience of a region.
Show more [+] Less [-]Revisiting the involvement of ammonia oxidizers and denitrifiers in nitrous oxide emission from cropland soils
2021
Wei, Wei | Isobe, Kazuo | Shiratori, Yutaka | Yano, Midori | Toyoda, Sakae | Koba, Keisuke | Yoshida, Naohiro | Shen, Haoyang | Senoo, Keishi
Nitrous oxide (N₂O), an ozone-depleting greenhouse gas, is generally produced by soil microbes, particularly NH₃ oxidizers and denitrifiers, and emitted in large quantities after N fertilizer application in croplands. N₂O can be produced via multiple processes, and reduced, with the involvement of more diverse microbes with different physiological constraints than previously thought; therefore, there is a lack of consensus on the production processes and microbes involved under different agricultural practices. In this study, multiple approaches were applied, including N₂O isotopocule analyses, microbial gene transcript measurements, and selective inhibition assays, to revisit the involvement of NH₃ oxidizers and denitrifiers, including the previously-overlooked taxa, in N₂O emission from a cropland, and address the biological and environmental factors controlling the N₂O production processes. Then, we synthesized the results from those approaches and revealed that the overlooked denitrifying bacteria and fungi were more involved in N₂O production than the long-studied ones. We also demonstrated that the N₂O production processes and soil microbes involved were different based on fertilization practices (plowing or surface application) and fertilization types (manure or urea). In particular, we identified the following intensified activities: (1) N₂O production by overlooked denitrifying fungi after manure fertilization onto soil surface; (2) N₂O production by overlooked denitrifying bacteria and N₂O reduction by long-studied N₂O-reducing bacteria after manure fertilization into the plowed layer; and (3) N₂O production by NH₃-oxidizing bacteria and overlooked denitrifying bacteria and fungi when urea fertilization was applied into the plowed layer. We finally propose the conceptual scheme of N flow after fertilization based on distinct physiological constraints among the diverse NH₃ oxidizers and denitrifiers, which will help us understand the environmental context-dependent N₂O emission processes.
Show more [+] Less [-]Effects of nitrogen-enriched biochar on rice growth and yield, iron dynamics, and soil carbon storage and emissions: A tool to improve sustainable rice cultivation
2021
Yin, Xiaolei | Peñuelas, Josep | Sardans, Jordi | Xu, Xuping | Chen, Youyang | Fang, Yunying | Wu, Liangquan | Singh, Bhupinder Pal | Tavakkoli, Ehsan | Wang, Weiqi
Biochar is often applied to paddy soils as a soil improver, as it retains nutrients and increases C sequestration; as such, it is a tool in the move towards C-neutral agriculture. Nitrogen (N) fertilizers have been excessively applied to rice paddies, particularly in small farms in China, because N is the major limiting factor for rice production. In paddy soils, dynamic changes in iron (Fe) continuously affect soil emissions of methane (CH₄) and carbon dioxide (CO₂); however, the links between Fe dynamics and greenhouse gas emissions, dissolved organic carbon (DOC), and rice yields following application of biochar remain unclear. The aims of this study were to examine the effects of two rates of nitrogen (N)-enriched biochar (4 and 8 t ha⁻¹ y⁻¹) on paddy soil C emissions and storage, rice yields, and Fe dynamics in subtropical early and late rice growing seasons. Field application of N-enriched biochar at 4 and 8 t ha⁻¹ increased C emissions in early and late rice, whereas application at 4 t ha⁻¹ significantly increased rice yields. The results of a culture experiment and a field experiment showed that the application of N-enriched biochar increased soil Fe²⁺concentration. There were positive correlations between Fe²⁺concentrations and soil CO₂, CH₄, and total C emissions, and with soil DOC concentrations. On the other way around, these correlations were negative for soil Fe³⁺concentrations. In the soil culture experiment, under the exclusion of plant growth, N-enriched biochar reduced cumulative soil emissions of CH₄ and CO₂. We conclude that moderate inputs of N-rich biochar (4 t ha⁻¹) increase rice crop yield and biomass, and soil DOC concentrations, while moderating soil cumulative C emissions, in part, by the impacts of biochar on soil Fe dynamics. We suggest that water management strategies, such as dry-wet cycles, should be employed in rice cultivation to increase Fe²⁺ oxidation for the inhibition of soil CH₄ and CO₂ production. Overall, we showed that application of 4 t ha⁻¹ of N-enriched biochar may represent a potential tool to improve sustainable food production and security, while minimizing negative environmental impacts.
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