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Sulfentrazone dechlorination by iron-nickel bimetallic nanoparticles
2016
Nascimento, Mayra A. | Lopes, Renata P. | Cruz, Jean C. | Silva, Antônio A. | Lima, Cláudio F.
The sulfentrazone dechlorination using bimetallic nanoparticles of Fe/Ni was studied. Different variables that could influence the sulfentrazone conversion were investigated, such as nitrogen atmosphere, pH and dosage of the nanoparticles and initial concentration of sulfentrazone. The best results were obtained using controlled pH (pH 4.0) and 1.0 g L⁻¹ of nanomaterials, resulting in 100 % conversion in only 30 min. Kinetic studies were also conducted, evaluating the influence of different nanoparticle dosages (1.0 to 4.0 g L⁻¹), system temperatures (20 to 35 °C) and nickel levels in the composition of the nanomaterials (0.025 to 0.10 gNi/gFe). The mechanism of sulfentrazone conversion has changed due a direct reduction on the catalytic activity sites and indirect reduction by atomic hydrogen. Both mechanisms have followed pseudo-first order models. The conversion rate improved when the dosage of the nanomaterials, system temperature and nickel content in the composition of the nanocomposites were increased. Finally, the conversion products were elucidated by mass spectrometry and toxicity assays were performed using Daphnia Similis. The results showed that the dechlorination product is less toxic than sulfentrazone.
Show more [+] Less [-]Synthesis of TiO2–Reduced Graphene Oxide Nanocomposites for Efficient Adsorption and Photodegradation of Herbicides
2016
Liu, Xue | Hong, Hye-gŏl | Wu, Xiaoli | Wu, Yanhua | Ma, Yongqiang | Guan, Wenbi | Shi, Zhangyu
The elimination of herbicides in aquatic environment is influenced by various biotic or abiotic factors. Thus, efficient, more applicable, and flexible methods are in demand. Photodegradation has been applied to remove three main types of herbicides, phenylurea, triazine, and chloroacetanilide, from water, based on a series of TiO₂–reduced graphene oxide nanocomposites. Experimental results showed that the three types of herbicides could be mostly removed under simulated sunlight irradiation for 5 h with the as-prepared photocatalyst. Compared with pure TiO₂ or P25, the photodegradation efficiency has been markedly increased. Thus, the present work could promote a new strategy dealing with the pollution of herbicides in aquatic ecosystems.
Show more [+] Less [-]Remediation of Anthracene-Contaminated Soil by ClO2 in the Presence of Magnetic Fe3O4-CuO@Montmorillonite as Catalyst
2016
Ma, Yulin | Gu, Na | Gao, Jinlong | Wang, Kuitao | Wu, Yunxia | Meng, Xiaoyu
Fe₃O₄-CuO@montmorillonite was prepared using coprecipitation method, and its structure was determined by XRD, IR, and transmission electron micrograph (TEM). Montmorillonite in Fe₃O₄-CuO@montmorillonite nanocomposite allowed the silicate layer of montmorillonite to behave as a barrier, which prevented the agglomeration and natural crystallization of Fe₃O₄ and CuO. Furthermore, the chlorine dioxide (ClO₂) oxidative degradation of anthracene-contaminated soil was studied in detail using Fe₃O₄-CuO@montmorillonite as a magnetic heterogeneous catalyst. The operating parameters such as ClO₂ concentration, catalyst dosage, reaction time, and pH were evaluated. Compared with the conventional ClO₂ oxidation process without the catalyst, the ClO₂ catalytic oxidation system could significantly enhance the degradation efficiency. Under the optimal condition (anthracene concentration 89.8 mg/kg, water soil mass ratio 3:1, initial pH 7, ClO₂ concentration 1 mol/kg, catalyst dosage 1 g/kg, reaction time 30 min, and reaction temperature 25 °C), anthracene degradation efficiency achieved 96.2 %. The catalyst could be easily reused by magnetic separation and used at least 8 cycles without obvious loss of activity. The kinetic studies revealed that the ClO₂ catalytic oxidation degradation of anthracene-contaminated soil with Fe₃O₄-CuO@montmorillonite as catalyst followed pseudo-first-order kinetics with respect to ClO₂ concentration. Thus, this study showed potential application of ClO₂ catalytic oxidation process in remediation of organic pollutant-contaminated soil.
Show more [+] Less [-]Experimental Investigation of Arsenic (III, V) Removal from Aqueous Solution Using Synthesized α-Fe2O3/MCM-41 Nanocomposite Adsorbent
2016
Boojari, Hossein | Pourafshari Chenar, Mahdi | Pakizeh, Majid
Adsorption of arsenic (III, V) from aqueous solution onto the synthesized α-Fe₂O₃/MCM-41 nanocomposite adsorbent, as function of contact time, initial concentration of the solution, temperature, pH, and presence of other anionic species, has been investigated. Characterization of adsorbent was performed via XRD, FT-IR, TGA, TEM, and N₂ adsorption–desorption techniques. The synthesized adsorbent belonged to the group of mesoporous materials with the mean pore diameter of 2.37 nm, specific surface area of 507.5 m² g⁻¹, and total pore volume of 0.571 cm³ g⁻¹. The experimental data were analyzed by Langmuir, Freundlich, and Dubinin-Radushkevich (D–R) adsorption isotherms. Based on Langmuir isotherm, the maximum adsorption capacities at 298 K in the concentration range of 2–200 ppm were 133.3 and 102.1 mg g⁻¹ for As(ш) and As(v), respectively. The adsorption experiments at different contact times indicated that the kinetics of adsorption accurately followed the pseudo-second-order rate equation. Thermodynamics parameters were calculated, and it was found that the adsorption process was spontaneous, exothermic, and favored at lower temperatures. The capability of regeneration and reusability of adsorbent was also examined in alkaline solutions.
Show more [+] Less [-]Efficient Degradation of Methylene Blue by the Nano TiO2-functionalized Graphene Oxide Nanocomposite Photocatalyst for Wastewater Treatment
2016
Wang, Ruibin | Yang, Rendang | Wang, Bin | Gao, Wenhua
Herein, an efficient nano TiO₂-functionalized graphene oxide nanocomposite photocatalyst was readily prepared, using an ordinary solvothermal technique. It was noted that the as-prepared nanocomposite yielded a quadruple degradation capacity of the previously reported P25-graphene composite photocatalyst towards methylene blue (MB). To elucidate this, the Brunauer–Emmett–Teller (BET)-specific surface area, conductivity, and water contact angle measurements were all carried out. It was found out that graphene oxide was endowed with nontrivial photocatalytic activity by increasing its content in the nanocomposite (from 1/100 to 1/9, with respect to the dosage of nano TiO₂). Overall, the nano TiO₂-functionalized graphene oxide nanocomposite is a promising candidate in applications of environment remediation.
Show more [+] Less [-]Hg2+ detection using a disposable and miniaturized screen-printed electrode modified with nanocomposite carbon black and gold nanoparticles
2016
Cinti, Stefano | Santella, Francesco | Moscone, Danila | Arduini, Fabiana
A miniaturized screen-printed electrode (SPE) modified with a carbon black-gold nanoparticle (CBNP-AuNP) nanocomposite has been developed as an electrochemical sensor for the detection of inorganic mercury ions (Hg²⁺). The working electrode surface has been modified with nanocomposite constituted of CBNPs and AuNPs by an easy drop casting procedure that makes this approach extendible to an automatable mass production of modified SPEs. Square wave anodic stripping voltammetry (SWASV) was adopted to perform Hg²⁺ detection, revealing satisfactory sensitivity and detection limit, equal to 14 μA ppb⁻¹ cm⁻² and 3 ppb, respectively. The applicability of the CBNP-AuNP-SPE for the determination of inorganic mercury has been assessed in river water by a simple filtration and acidification of the sample as well as in soil by means of a facile acidic extraction procedure assisted by ultrasound.
Show more [+] Less [-]Novel two-step vapor-phase synthesis of UV–Vis light active Fe2O3/WO3 nanocomposites for phenol degradation
2016
Barreca, Davide | Carraro, Giorgio | Gasparotto, Alberto | Maccato, Chiara | Sada, Cinzia | Bontempi, Elza | Brisotto, Mariangela | Pliekhova, Olena | Štangar, Urška Lavrenčič
Supported Fe₂O₃/WO₃ nanocomposites were fabricated by an original vapor phase approach, involving the chemical vapor deposition (CVD) of Fe₂O₃ on Ti sheets and the subsequent radio frequency (RF)-sputtering of WO₃. Particular attention was dedicated to the control of the W/Fe ratio, in order to tailor the composition of the resulting materials. The target systems were analyzed by the joint use of complementary techniques, that is, X-ray diffraction (XRD), field emission-scanning electron microscopy (FE-SEM), atomic force microscopy (AFM), energy dispersive X-ray spectroscopy (EDXS), X-ray photoelectron spectroscopy (XPS), secondary ion mass spectrometry (SIMS), and optical absorption spectroscopy. The results showed the uniform decoration of α-Fe₂O₃ (hematite) globular particles by tiny WO₃ aggregates, whose content could be controlled by modulations of the sole sputtering time. The photocatalytic degradation of phenol in the liquid phase was selected as a test reaction for a preliminary investigation of the system behavior in wastewater treatment applications. The system activity under both UV and Vis light illumination may open doors for further material optimization in view of real-world end-uses.
Show more [+] Less [-]The application of catalyst-recovered SnO2 as an anode material for lithium secondary batteries
2016
Ryu, Da-Jeong | Jung, Hee-Won | Lee, Sung Hun | Park, Da-Jeong | Ryu, Kwang-Sun
We studied the electrochemical characteristics of tin dioxide (SnO₂) recovered from waste catalyst material which had been previously used in a polymer synthesis reaction. In order to improve the electrochemical performance of the SnO₂ anode electrode, we synthesized a nanocomposite of recovered SnO₂ and commercial iron oxide (Fe₂O₃) (weight ratio 95:5) using a solid state method. X-ray diffraction (XRD) and field emission scanning electron microscopy (FE-SEM) analyses revealed an additional iron oxide phase within a porous nanocomposite architecture. The electrochemical characterizations were based on galvanostatic charge–discharge (CD) curves, cyclic voltammetry (CV), and electrochemical impedance spectroscopy (EIS). In the first discharge, the capacity of the SnO₂–Fe₂O₃ nanocomposite was 1700 mAh g⁻¹, but was reduced to about 1200 mAh g⁻¹ in the second discharge. Thereafter, a discharge capacity of about 1000 mAh g⁻¹was maintained up to the 20th cycle. The SnO₂–Fe₂O₃ nanocomposite showed better reversible capacities and rate capabilities than either the recovered SnO₂ or commercial Fe₂O₃ nanoparticle samples.
Show more [+] Less [-]Ce-Fe-reduced graphene oxide nanocomposite as an efficient catalyst for sulfamethazine degradation in aqueous solution
2016
Wan, Zhong | Wang, Jianlong
A heterogeneous Fenton catalyst Ce⁰–Fe⁰-reduced graphene oxide (Ce–Fe–RGO) was synthesized with chemical reduction methods and used for degradation of sulfamethazine. The introduction of Ce and graphene increased the dispersibility of iron particles which was confirmed by SEM and TEM. The results of VSM analysis showed good magnetism of Ce–Fe–RGO. The catalyst performance was compared with other kinds of catalysts (Fe⁰ and Ce⁰–Fe⁰) for degradation of sulfamethazine. The results showed that Ce⁰–Fe–RGO had good catalytic performance and adsorption. X-ray diffraction showed the change of iron oxide on catalyst surface after use. The total sulfur (TS), total nitrogen (TN), total organic carbon (TOC), and intermediates, such as small organic molecular and anion ions, were analyzed by IC under different pH conditions. Finally, the possible catalytic mechanism was tentatively proposed based on inhibitor experimental results and XPS characterization. The main active species was hydroxyl radical on catalyst surface and the transition between Ce³⁺ and Ce⁴⁺ which enhanced the reduction from Fe³⁺ to Fe²⁺ and formation of ·OH and ·O₂ ⁻.
Show more [+] Less [-]Controlled acid catalyzed sol gel for the synthesis of highly active TiO2-chitosan nanocomposite and its corresponding photocatalytic activity
2016
Afzal, Saba | Samsudin, Emy Marlina | Julkapli, Nurhidayatullaili Muhd | Abd Hamid, Sharifah Bee
For the synthesis of a highly active TiO₂-chitosan nanocomposite, pH plays a crucial role towards controlling its morphology, size, crystallinity, thermal stability, and surface adsorption properties. The presence of chitosan (CS) biopolymer facilitates greater sustainability to the photoexcited electrons and holes on the catalysts’ surface. The variation of synthesis pH from 2 to 5 resulted in different physico-chemical and photocatalytic properties, whereby a pH of 3 resulted in TiO₂-chitosan nanocomposite with the highest photocatalytic degradation (above 99 %) of methylene orange (MO) dye. This was attributed to the efficient surface absorption properties, high crystallinity, and the presence of reactive surfaces of –NH₂ and –OH groups, which enhances the adsorption-photodegradation effect. The larger surface oxygen vacancies coupled with reduced electron-hole recombination further enhanced the photocatalytic activity. It is undeniable that the pH during synthesis is critical towards the development of the properties of the TiO₂-chitosan nanocomposite for the enhancement of photocatalytic activity.
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