Neonicotinoids are the most widely used class of insecticides in the world, but they have raised numerous concerns regarding their effects on biodiversity. Thus, the objective of this work was to do a critical review of the contamination of the environment (soil, water, air, biota) by neonicotinoids (acetamiprid, clothianidin, imidacloprid, thiacloprid, thiamethoxam) and of their impacts on terrestrial and aquatic biodiversity. Neonicotinoids are very frequently detected in soils and in freshwater, and they are also found in the air. They have only been recently monitored in coastal and marine environments, but some studies already reported the presence of imidacloprid and thiamethoxam in transitional or semi-enclosed ecosystems (lagoons, bays, and estuaries). The contamination of the environment leads to the exposure and to the contamination of non-target organisms and to negative effects on biodiversity. Direct impacts of neonicotinoids are mainly reported on terrestrial invertebrates (e.g., pollinators, natural enemies, earthworms) and vertebrates (e.g., birds) and on aquatic invertebrates (e.g., arthropods). Impacts on aquatic vertebrate populations and communities, as well as on microorganisms, are less documented. In addition to their toxicity to directly exposed organisms, neonicotinoid induce indirect effects via trophic cascades as demonstrated in several species (terrestrial and aquatic invertebrates). However, more data are needed to reach firmer conclusions and to get a clearer picture of such indirect effects. Finally, we identified specific knowledge gaps that need to be filled to better understand the effects of neonicotinoids on terrestrial, freshwater, and marine organisms, as well as on ecosystem services associated with these biotas.

Copper-based plant protection products (PPPs) are widely used in both conventional and organic farming, and to a lesser extent for non-agricultural maintenance of gardens, greenspaces, and infrastructures. The use of copper PPPs adds to environmental contamination by this trace element. This paper aims to review the contribution of these PPPs to the contamination of soils and waters by copper in the context of France (which can be extrapolated to most of the European countries), and the resulting impacts on terrestrial and aquatic biodiversity, as well as on ecosystem functions. It was produced in the framework of a collective scientific assessment on the impacts of PPPs on biodiversity and ecosystem services in France. Current science shows that copper, which persists in soils, can partially transfer to adjacent aquatic environments (surface water and sediment) and ultimately to the marine environment. This widespread contamination impacts biodiversity and ecosystem functions, chiefly through its effects on phototrophic and heterotrophic microbial communities, and terrestrial and aquatic invertebrates. Its effects on other biological groups and biotic interactions remain relatively under-documented.

Abstract The Tara Microplastics mission was conducted for 7 months to investigate plastic pollution along nine major rivers in Europe—Thames, Elbe, Rhine, Seine, Loire, Garonne, Ebro, Rhone, and Tiber. An extensive suite of sampling protocols was applied at four to five sites on each river along a salinity gradient from the sea and the outer estuary to downstream and upstream of the first heavily populated city. Biophysicochemical parameters including salinity, temperature, irradiance, particulate matter, large and small microplastics (MPs) concentration and composition, prokaryote and microeukaryote richness, and diversity on MPs and in the surrounding waters were routinely measured onboard the French research vessel Tara or from a semi-rigid boat in shallow waters. In addition, macroplastic and microplastic concentrations and composition were determined on river banks and beaches. Finally, cages containing either pristine pieces of plastics in the form of films or granules, and others containing mussels were immersed at each sampling site, 1 month prior to sampling in order to study the metabolic activity of the plastisphere by meta-OMICS and to run toxicity tests and pollutants analyses. Here, we fully described the holistic set of protocols designed for the Mission Tara Microplastics and promoted standard procedures to achieve its ambitious goals: (1) compare traits of plastic pollution among European rivers, (2) provide a baseline of the state of plastic pollution in the Anthropocene, (3) predict their evolution in the frame of the current European initiatives, (4) shed light on the toxicological effects of plastic on aquatic life, (5) model the transport of microplastics from land towards the sea, and (6) investigate the potential impact of pathogen or invasive species rafting on drifting plastics from the land to the sea through riverine systems.

There is growing interest in using the ecosystem services framework for environmental risk assessments of chemicals, including plant protection products (PPPs). Although this topic is increasingly discussed in the recent scientific literature, there is still a substantial gap between most ecotoxicological studies and a solid evaluation of potential ecotoxicological consequences on ecosystem services. This was recently highlighted by a collective scientific assessment (CSA) performed by 46 scientific experts who analyzed the international science on the impacts of PPPs on biodiversity, ecosystem functions, and ecosystem services. Here, we first point out the main obstacles to better linking knowledge on the ecotoxicological effects of PPPs on biodiversity and ecological processes with ecosystem functions and services. Then, we go on to propose and discuss possible pathways for related improvements. We describe the main processes governing the relationships between biodiversity, ecological processes, and ecosystem functions in response to effects of PPP, and we define categories of ecosystem functions that could be directly linked with the ecological processes used as functional endpoints in investigations on the ecotoxicology of PPPs. We then explore perceptions on the possible links between these categories of ecosystem functions and ecosystem services among a sub-panel of the scientific experts from various fields of environmental science. We find that these direct and indirect linkages still need clarification. This paper, which reflects the difficulties faced by the multidisciplinary group of researchers involved in the CSA, suggests that the current gap between most ecotoxicological studies and a solid potential evaluation of ecotoxicological consequences on ecosystem services could be partially addressed if concepts and definitions related to ecological processes, ecosystem functions, and ecosystem services were more widely accepted and shared within the ecotoxicology community. Narrowing this gap would help harmonize and extend the science that informs decision-making and policy-making, and ultimately help to better address the trade-off between social benefits and environmental losses caused by the use of PPPs.

Microplastics provide a persistent substrate that can facilitate microbial transport across ecosystems. Since most marine plastic debris originates from land and reaches the ocean through rivers, the potential dispersal of freshwater bacteria into the sea represents a significant concern. To address this question, we explored the plastisphere on microplastic debris (MPs) and on pristine microplastics (pMPs) as well as the bacteria living in surrounding waters, along the river-sea continuum in nine major European rivers sampled during the 7 months of the Tara Microplastics mission. In both marine and riverine waters, we found a clear niche partitioning among MPs and pMPs plastispheres when compared to the bacteria living in the surrounding waters. Across this large dataset, we found that bacterial community structure varied along the river salinity gradient, with plastisphere communities exhibiting almost complete segregation between freshwater and marine ecosystems. We also described for the first time a virulent human pathogenic bacterium (Shewanella putrefaciens), capable of infecting human intestinal epithelial cells, detected exclusively on MPs in riverine environments. Our findings indicate that salinity is the main driver of plastisphere communities along the river-to-sea continuum, helping to mitigate the risk of pathogens transfer between freshwater and marine systems.

Mangrove ecosystems are known to play a key role in the global carbon cycle, due to their productivity and their ability for carbon sequestration both in the biomass and in the soil. In the latter, various geochemical processes lead to the production of dissolved organic matter (DOM) that can be exported through tidal pumping and then constitute an important source of organic carbon for adjacent ecosystems. DOM characteristics, and their variabilities, within mangrove soils depend on several factors, including the mangrove species, yet these variations and their origin still need to be precisely constrained. This study examined DOM sources in soils of a carbonate atoll mangrove (Ouvéa, New Caledonia), focusing on two tree species, Rhizophora apiculata and Bruguiera gymnorhiza, at different growth stages. We analysed porewater properties and DOM optical characteristics through spectroscopic and EEM-PARAFAC methods. Our results indicate distinct TOC and DOC concentrations across species, with mature B. gymnorhiza soils showing the highest TOC content (~ 30%) but the lowest DOC content (32 mg L−1). These differences seem not to be directly related to site physicochemical conditions (redox, pH, salinity) but may rather reflect differences in DOM sources and production, notably due to different symbiotic relationships with mycorrhizal fungi, which influence microbial activity and organic matter diagenesis. DOM absorbance patterns also varied significantly between species: Beneath R. apiculata, DOM had higher protein-like and fulvic-like fluorescence, indicating fresher organic matter, while beneath B. gymnorhiza, especially in mature stands, DOM was more humified, suggesting older OM because of a possible long-term accumulation due to the basin-like morphology of this site.

This study investigates the relationship between green marketing practices and the sustainability performance of manufacturing firms in emerging markets. A self-administered questionnaire was used to collect data from 270 respondents, and the analysis was conducted using Smart PLS-SEM (version 4). The results demonstrate a significant positive relationship between green internal marketing and the overall sustainability performance of the firms. Specifically, green marketing communication was found to positively influence both environmental and social performance, although it did not have a significant effect on financial performance. Likewise, the adoption of green products substantially improved environmental performance but did not significantly impact financial or social performance. Additionally, the study supports a positive association between green strategy implementation and sustainability performance. These findings underscore the critical role of integrating green marketing practices into sustainability initiatives. The research provides valuable insights for managers and policymakers, emphasizing the need for a holistic approach to green marketing to enhance environmental and social outcomes, even if financial benefits are not immediately apparent. This study contributes to the growing body of knowledge on sustainable business practices and offers practical implications for achieving long-term sustainability in manufacturing firms.

Forward Osmosis is a suitable pretreatment process for reverse osmosis for secondary-treated sewage reuse and secondary-treated industrial effluents. In this study, the FO process is investigated for concentrating synthetic secondary treated tannery effluents using 24 g.L-1 and 38 g.L-1 of NaCl solution as draw solution. Results showed that 38 g.L-1 NaCl solution when used, provided higher flux and lower flux decline ratio as compared to 24 g.L-1 NaCl solution. The solute rejection by FO membrane was more in FO experiments using 38 g.L-1 NaCl solution as DS as compared to 24 g.L-1 NaCl solution. Contact angle, Fourier transform infrared spectroscopy, and scanning electronic microscopy tests on pristine and chemically cleaned membranes indicated the change in membrane structure and the presence of foulants on the membrane surface, indicating insufficient chemical cleaning. Findings signify implications on the concentration of DS and the cleaning method adopted for concentrating treated tannery effluent efficaciously using the FO process.

Landslides are significant natural hazards that cause damage to the environment, life, and properties, mainly in hilly terrain. This research was mostly focused on generating a landslide susceptibility zone map of Papumpare District, Arunachal Pradesh, and classifying the region from high susceptibility to least susceptibility using AHP modeling techniques considering the landslide causative factors. The Analytical Hierarchy Process (AHP) is a multicriteria decision-making model (MCDM) in which each parameter is compared based on its role in triggering a landslide. A total of eight parameters were selected based on the factors that could affect the most, like Slope, Rainfall, Drainage Density, Lineament Density, Geomorphology, Soil, Geology, and Land use/Land cover. These layers were prepared using ArcGIS 10.8 software and ERDAS IMAGINE 2014. Based on the output, the region was classified into five zones of landslide susceptibility classes. Of these, the high-very-high landslides are mostly amassed near the steep and disturbed slopes due to earth-cutting, especially for building or construction of roads. Validation was done using the ROC curve (73.2%) suggesting good performance of the model. The outcome of this work will provide information for proper landslide hazard management and will help in formulating suitable mitigation strategies in the future.