An unexpected pathway for hydrodesulfurization of gazole over a CoMoS active phase supported on a mesoporous TiO₂ catalyst
2017
Naboulsi, I. | Felipe Linares Aponte, C. | Lebeau, B. | Brunet, S. | Michelin, L. | Bonne, M. | Blin, J. L.
Using dual mesoporous titania as a support, due to the presence of intrinsic Brönsted acid sites, the main approach to 4,6-dimethylbenzothiophene (46DMDBT) hydrodesulfurization (HDS) becomes the direct desulfurization (DDS) route through isomerization and dismutation reactions, instead of the hydrogenation (HYD) pathway usually observed with a conventional promoted (by Ni or Co) MoS₂/Al₂O₃ catalyst.
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