Zur Synthese von N-(Chlormethyl)carbimidoylchloriden / Synthesis of N-(Chloromethyl)carboximidoyl Chlorides

Böhme, Horst; Ahrens, Kurt Henning; Drechsler, Hans-Joachim; Rumbaur, Georg

Zur Synthese von N-(Chlormethyl)carbimidoylchloriden / Synthesis of N-(Chloromethyl)carboximidoyl Chlorides

2014

Böhme, Horst | Ahrens, Kurt Henning | Drechsler, Hans-Joachim | Rumbaur, Georg

From N-(hydroxymethyl)- and N-(chloromethyl)carboxylic acid amides (3) and (4) respectively by treatment with 2 or 1 mol phosphorus pentachloride respectively N- (chloromethyl)carboximidoyl chlorides (10) are formed. As side products in addition to acyl chloride (6) and carbonitrile (14) can be isolated tris(chloromethyl)amine (7), N- (chloromethyl)carboximidic acid chloromethylester (15), N-bis(chloromethyl)phosphoramidic dichloride (11) and l,3-bis(chloromethyl)-2,2,2,4,4,4-hexachloro-2,2,4,4-tetrahydro- l,3,2,4-diazadiphosphetidin (12)

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Palabras clave de AGROVOC

amides carboxylic acids chlorides organochlorine compounds phosphorus

Información bibliográfica

Publicado en

Zeitschrift für Naturforschung

Volumen 33 Edición 6 Paginación 636 - 639 ISSN 0932-0776

Editorial

Verlag der Zeitschrift für Naturforschung

Otras materias

N-bis(chloromethyl)phosphoramidic dichloride; N- (chloromethyl)carboximidoyl chlorides; Tris(chloromethyl)amine; 3-bis(chloromethyl)-2; 4-tetrahydro-1; 4-hexachloro-2; 4-diaz£kdiphosphetidine; N-(chloromethyl)carboximidic acid chloromethylester

Idioma

Inglés

Tipo

Journal Article; Text

En AGRIS desde: 2024-02-28

Formato: MODS

Proveedor de Datos

Este registro bibliográfico ha sido proporcionado por National Agricultural Library

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Enlaces

DOI http://dx.doi.org/10.1515/znb-1978-0615

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