Reactive Black 5 dye degradation using filters of smuggled cigarette modified with Fe3+
2017
Glugoski, Letícia Polli | de Jesus Cubas, Paloma | Fujiwara, Sérgio Toshio
This study presents an attempt to solve two serious environmental problems: the generation of toxic effluents and solid waste disposal. The work proposes recycling cigarette filters with the purpose of degrading reactive dyes, which are used in the textile industry. Filters of smuggled cigarettes were recycled through Fe³⁺ immobilization on their surface. The material obtained was characterized through Fourier transform infrared spectroscopy (FTIR), atomic absorption spectroscopy (AAS), scanning electron microscopy–energy-dispersive spectroscopy (SEM-EDS), and ultraviolet–visible spectroscopy (UV–vis). The factorial design revealed that the most suitable conditions for the degradation of Reactive Black 5 dye were obtained by using 1 g of material at pH 3.0 in a 100 mg L⁻¹ hydrogen peroxide solution. The material showed excellent performance in the Reactive Black 5 dye degradation process; in 60 min, 99.09 % dye was removed. At pH 7.0, the dye degradation was 72.67 %, indicating that the material prepared can be used at pH values greater than 3.0 without the occurrence of hydrated Fe³⁺ oxide precipitation. Furthermore, the material showed no loss of catalytic activity after three degradation studies.
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