Characterization of aluminium-based water treatment residual for potential phosphorus removal in engineered wetlands

Babatunde, A.O.; Zhao, Y.Q.; Burke, A.M.; Morris, M.A.; Hanrahan, J.P.

Characterization of aluminium-based water treatment residual for potential phosphorus removal in engineered wetlands

2009

Babatunde, A.O. | Zhao, Y.Q. | Burke, A.M. | Morris, M.A. | Hanrahan, J.P.

Aluminium-based water treatment residual (Al-WTR) is the most widely generated residual from water treatment facilities worldwide. It is regarded as a by-product of no reuse potential and landfilled. This study assessed Al-WTR as potential phosphate-removing substrate in engineered wetlands. Results indicate specific surface area ranged from 28.0 m² g⁻¹ to 41.4 m² g⁻¹. X-ray Diffraction, Fourier transform infrared and energy-dispersive X-ray spectroscopes all indicate Al-WTR is mainly composed of amorphous aluminium which influences its phosphorus (P) adsorption capacity. The pH and electrical conductivity ranged from 5.9 to 6.0 and 0.104 dS m⁻¹ to 0.140 dS m⁻¹ respectively, showing that it should support plant growth. Batch tests showed adsorption maxima of 31.9 mg P g⁻¹ and significant P removal was achieved in column tests. Overall, results showed that Al-WTR can be used for P removal in engineered wetlands and it carries the benefits of reuse of a by-product that promotes sustainability.

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