Solidification/stabilization of municipal solid waste incineration fly ash using uncalcined coal gangue–based alkali-activated cementitious materials
2019
Zhao, Shujie | Muhammad, Faheem | Yu, Lin | Xia, Ming | Huang, Xiao | Jiao, Binquan | Lu, Ning | Li, Dongwei
The proper disposal of municipal solid waste incineration fly ash (MSWI FA) is necessary due to the presence of hazardous metals (Cu²⁺, Zn²⁺, Pb²⁺ and Cd²⁺). The solidification/stabilization through alkali-activated cementitious materials (having aluminosilicates) is regarded as one of the best methods for its disposal. In this paper, an uncalcined coal gangue–based alkali-activated cementitious material was used to solidify the MSWI FA. The compressive strength of these cementitious materials was evaluated through different contents of alkali activators, SiO₂/Na₂O molar ratios, liquid/solid ratios and curing temperatures by utilizing a single-factor experiment. The specimens with the highest compressive strength (31.37 MPa) were used for solidification of MSWI FA. The results indicated that compressive strength decreased with the addition of MSWI FA which caused the higher leaching of heavy metals. The solidification efficiencies of Cu²⁺, Zn²⁺, Pb²⁺ and Cd²⁺ were more than 95%. In addition, leaching concentrations had not surpassed the critical limit up to 20% addition of MSWI FA in solidified samples and representing the potential application of these samples for construction and landfill purposes. Heavy metals in MSWI FA were solidified through physical encapsulation and chemical bonding which was verified by speciation analysis, X-ray diffraction, Fourier transform infrared spectrometry and scanning electron microscopy with energy dispersive spectrometry analyses.
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