Urea/ZnCl2 in situ hydrothermal carbonization of Camellia sinensis waste to prepare N-doped biochar for heavy metal removal
2019
Guo, Shasha | Gao, Yuefang | Wang, Yancheng | Liu, Zhengjun | Wei, Xingneng | Peng, Pai | Xiao, Bin | Yang, Yajun
Environmental benefits of biochar require a simple and effective method for preparation of functional N-doped biochar. In this study, urea/ZnCl₂ was developed to prepare N-doped biochar via in situ hydrothermal carbonization (HTC) of Camellia sinensis waste at 120–280 °C for 2 h under 1.0–9.8 MPa. Physicochemical and structural properties of the N-doped biochar were investigated by Raman spectra, elemental analysis, BET surface area, SEM, TEM, XRD, and XPS. The results showed that the N content in biochar could reach up to 7.79% at 280 °C. Surface chemistry suggested that pyridinic N, pyrollic N, and graphitic N were the major N species on the biochar. Moreover, the N-doped biochar was successfully employed to remove metal ions Cu²⁺, Pb²⁺, Zn²⁺, and Cr⁶⁺. Adsorption data fit closely to the pseudo-second-order kinetic equation and the Langmuir adsorption isotherm model for all metal ions.
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