Abelmoschus esculentus (Okra) seed extract for stabilization of the biosynthesized TiO2 photocatalyst used for degradation of stable organic substance in water

The seed extract of Abelmoschus esculentus (AE), also known as Okra, was used as a source of reducing and capping agents to synthesized biogenic titanium dioxide nanoparticles (TiO₂ NPs) due to its rich flavonoid contents. The synthesized AE-TiO₂ nanoparticles were further evaluated by the effect of loading of TiO₂ NPs and irradiation time on the photocatalytic degradation of methylene blue dye. The synthesized TiO₂ NPs were then characterized by scanning electron microscopy (SEM), X-ray diffraction (XRD), thermogravimetric analysis (TGA), energy dispersive X-ray spectroscopy (EDS), Fourier transformed infrared (FTIR) spectroscopy, Raman spectra, UV–visible spectrophotometry, and particle size distribution (PSD). The findings confirmed the successful synthesis of the spherical anatase phase of TiO₂ NPs, as well as the existence of phytochemicals in the extract, which were involved in the capping/stabilization of NPs. The synthesized TiO₂ NPs were found to be 60–120 nm in size and almost uniformly distributed throughout the sample. The photocatalytic activity measured in a 300 mL cylindrical photochemical reactor and irradiated with 250 watts UV lamp was investigated based on methylene blue degradation. Effects of irradiation time and catalyst loading were elucidated and correlated with the characteristics of the catalysts. The findings revealed that the synthesized TiO₂ NPs were well-dispersed, stable, and could achieve more than 80 % degradation in 240 min of irradiation with 90 mg/L of AE-TiO₂ NPs loading compared to only 70 % by the commercial one. These results suggested that AE-TiO₂ NPs possesses significant catalytic activity, and the photocatalytic process could be used to degrade, decolorize, and mineralize the methylene blue dye. The polyphenolic tannins present in the extract were the reason behind the desirable characteristics of the nanoparticles and better photocatalytic activity of AE-TiO₂ NPs.