Application of an electrochemical sensor using copper oxide nanoparticles/polyalizarin yellow R nanocomposite for hydrogen peroxide
2021
Amini, Nader | Rashidzadeh, Bahaaldin | Amanollahi, Nasrin | Maleki, Afshin | Yang, Jae-Kyu | Lee, Seung-Mok
In this study, copper oxide nanoparticles (CuONPs) were prepared by a simple chemical method and then characterized by scanning electron microscope (SEM). A novel electrochemical sensor for hydrogen peroxide (H₂O₂) analysis was prepared by immobilizing copper oxide nanoparticles and polyalizarin yellow R (PYAR) on bare glassy carbon electrode (PAYR/CuONPs/GCE). The electrocatalytical behavior of the proposed electrochemical sensor was also studied by cyclic voltammetry (CV), electrochemical impedance spectroscopy (EIS), and differential pulse voltammetry (DPV). Based on the results, the PAYR/CuONP nanocomposite had significant electrocatalytic oxidation and reduction properties for the detection and determination of H₂O₂. Some parameters such as linear range, sensitivity, and detection limit for reduction peak were obtained as 0.1–140 μM, 1.4154 μA cm⁻² μM⁻¹, and 0.03 μM, respectively, by the DPV technique. Some advantages of this electrode were having widespread linear range, low detection limit, and, most importantly, ability in simultaneous oxidation and reduction of H₂O₂ at two applied potentials.
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