Iridium(i)-catalyzed vinylic C–H borylation of 1-cycloalkenecarboxylates with bis(pinacolato)diboron
2013
Sasaki, Ikuo | Doi, Hana | Hashimoto, Toshiya | Kikuchi, Takao | Itō, Hajime | Ishiyama, Tatsuo
Ir(i)-catalyzed C–H borylation of 1-cycloalkenecarboxylic derivatives with bis(pinacolato)diboron affords various alkenylboronates with functional groups in excellent yields. This reaction was also used in a one-pot borylation/Suzuki–Miyaura cross-coupling procedure.
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