Synthesis of heterojunction photocatalysts composed of Ag 2 S quantum dots combined with Bi 4 Ti 3 O 12 nanosheets for the degradation of dyes

Facilitating the separation of photogenerated electron/hole pairs and widening the light-responsive region are crucial to enhance the overall photocatalytic performance of photocatalysts. To achieve this aim, here we have prepared Ag₂S/Bi₄Ti₃O₁₂ heterojunction composite photocatalysts by assembling Ag₂S quantum dots onto the surface of Bi₄Ti₃O₁₂ nanosheets. Transmission electron microscopy observation demonstrates that two types of Ag₂S quantum dots separately with size of 40–70 and 7–17 nm are uniformly assembled onto the surface of large-sized Bi₄Ti₃O₁₂ thin nanosheets. The as-prepared Ag₂S/Bi₄Ti₃O₁₂ heterojunction composites exhibit much enhanced light absorption (particularly in the visible and near-infrared region) and highly efficient separation of electrons and holes photogenerated in Bi₄Ti₃O₁₂. Rhodamine B (RhB) aqueous solution was chosen as the target organic pollutant to evaluate the photocatalytic performance of the samples under simulated sunlight irradiation. It is found that the Ag₂S/Bi₄Ti₃O₁₂ heterojunction composites manifest significantly enhanced photocatalytic activity toward the RhB degradaton. In particular, the 15wt% Ag₂S/Bi₄Ti₃O₁₂ composite exhibits the highest photocatalytic activity, which is ca. 2.8 and 4.0 times higher than bare Bi₄Ti₃O₁₂ and Ag₂S, respectively. The enhanced photocatalytic activity of the composites can be explained as a result of the Z-scheme electron transfer from the conduction band of Bi₄Ti₃O₁₂ to the valence band of Ag₂S, and thus more photogenerated holes in the valence band of Bi₄Ti₃O₁₂ and electrons in the conduction band of Ag₂S are able to participate in the photocatalytic reactions. Active species trapping experiments were carried out, from which it is concluded that photogenerated holes and •O₂⁻ radicals play the dominant and secondary role in the photocatalysis, respectively.