Synthesis of polyfluorinated aromatic ethers and thioethers by synergistic cleavage of C-B bond and C-F bond of B(C6F5)3
2021
Ma, Cui-Cui | Zhu, Xing-Xing | Liu, Li | Dai, Jian-Jun | Xu, Jun | Xu, Hua-Jian
A concise and efficient method for the synthesis of polyfluorinated aromatic ethers and thioethers by synergistic cleavage of C-B bond and C-F bond of B(C₆F₅)₃ is reported. The reaction could proceed smoothly with excellent functional-group compatibility. In addition, the transformation represents the first general application of B(C₆F₅)₃ as reaction partners in cross-coupling reaction.
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