New routes to manganese higher-nuclearity topologies: synthesis of the cluster [Mn₈(μ₄-O)₄(phpz)₈(thf)₄]
2005
Tanase, Stefania | Aromí, G. (Guillem) | Bouwman, Elisabeth | Kooijman, Huub | Spek, Anthony L. | Reedijk, Jan
Reaction of Mn(ClO₄)₂·6H₂O with 3(5)-methyl-5(3)-(2-hydroxyphenyl)pyrazole (H₂phpz) affords a highly asymmetric octanuclear manganese(iii) cluster resulting from the different bridging coordination modes of the ligand H₂phpz.
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