Synthesis and characterization of a novel composite of rice husk-derived graphene oxide with titania microspheres (GO-RH/TiO2) for effective treatment of cationic dye methylene blue in aqueous solutions

Manpetch, Panlekha; Singhapong, Wadwan; Jaroenworaluck, Angkhana

Synthesis and characterization of a novel composite of rice husk-derived graphene oxide with titania microspheres (GO-RH/TiO2) for effective treatment of cationic dye methylene blue in aqueous solutions

2022

Manpetch, Panlekha | Singhapong, Wadwan | Jaroenworaluck, Angkhana

Graphene oxide (GO) was synthesized utilizing rice husk (RH) as the starting raw material via a modified Hummers’ method. Ground pencil leads were used as a control powder of the starting raw material to monitor the consistency of the synthesis method. TiO₂ microspheres were synthesized via a precipitated method using the pluronic F127 solution as the pore template. GO derived from RH (GO-RH) was composited with TiO₂ microspheres as GO-RH/TiO₂ composites by an impregnation method with weight ratios of 3:1, 2:2, and 1:3. Characterized results revealed GO-RH formed a ternary phase material of graphene oxide, graphite oxide, and silica. A typical microstructure of the calcined TiO₂ microspheres was found as the agglomerated anatase nanoparticles. Furthermore, the composites belong to large surface areas and numerous oxygen-containing functionalities on their surfaces. Removal efficiencies of cationic dye methylene blue (MB) from aqueous solutions by the composites, GO-RH and TiO₂, were studied under UV illumination for 180 min. Due to the effective combination of adsorption and photodegradation for the MB removal, the composites provided the higher efficiencies (99–100%) faster than those of GO-RH and TiO₂ and could be reused at least 4 times. Finally, a mechanism of the MB removal by the composites was proposed.

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