Complete denitrification of nitrate and nitrite to N₂ gas by samarium(ii) iodide
2020
Marks, Walker R. | Baumgardner, Douglas F. | Reinheimer, Eric W. | Gilbertson, John D.
The reduction of nitrogen oxides (NₓOyⁿ⁻) to dinitrogen gas by samarium(ii) iodide is reported. The polyoxoanions nitrate (NO₃⁻) and nitrite (NO₂⁻), as well as nitrous oxide (N₂O) and nitric oxide (NO) were all shown to react with stoichiometric amounts of SmI₂ in THF for the complete denitrification to N₂.
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