A self-assembling polymer-bound rotaxane under thermodynamic control
2003
Johnstone, Ken D. | Bampos, Nick | Sanders, Jeremy K. M. | Gunter, Maxwell J.
The thermodynamically controlled self-assembly of a neutral donor–acceptor rotaxane, stoppered via porphyrin coordination and bound to polystyrene beads is described, and the dynamic equilibrium between solid and solution phases has been examined by HR MAS nmr spectroscopy.
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