Facile synthesis of a mesostructured TiO₂–graphitized carbon (TiO₂–gC) composite through the hydrothermal process and its application as the anode of lithium ion batteries
2016
Sohn, Hiesang | Kim, Daeun | Lee, Jinwoo | Yoon, Songhun
A mesostructured TiO₂–graphitic carbon (TiO₂–gC) composite was synthesized through a simple and scalable hydrothermal method to be employed as an anode material in Li-ion batteries. In a wide voltage range (0.0–2.5 V), the TiO₂–gC composite anode possesses a high initial lithiation capacity (598 mA h g⁻¹) at 0.1 C (1 C: 150 mA g⁻¹), and it still retains 369 mA h g⁻¹ after 50 cycles at 0.5 C. Furthermore, under a high current density of 2 C, the TiO₂–gC anode exhibits stable capacity (252 mA h g⁻¹) retention for up to 200 cycles. This excellent electrochemical performance could be ascribed to a synergistic effect of well-developed mesoporosity with a high surface area (345.4 m² g⁻¹), the conductive graphitic carbon wall, and uniformly dispersed TiO₂ nanoparticles, resulting in improved Li⁺ penetration, fast electron transport and high structural stability during cycling.
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