Characteristics and formation mechanisms of autumn haze pollution in Chengdu based on high time-resolved water-soluble ion analysis

Wu, Pan; Huang, Xiaojuan; Zhang, Junke; Luo, Bin; Luo, Jinqi; Song, Hongyi; Zhang, Wei; Rao, Zhihan; Feng, Yanpeng; Zhang, Jianqiang

Characteristics and formation mechanisms of autumn haze pollution in Chengdu based on high time-resolved water-soluble ion analysis

2019

To investigate the characteristics and formation mechanisms of haze pollution in the autumn season in the Sichuan Basin, hourly concentrations of water-soluble inorganic ions in PM₂.₅ (Na⁺, K ⁺, NH₄⁺, Mg²⁺, Ca²⁺, Cl⁻, NO₃⁻, and SO₄²⁻) and major gaseous precursors (HCl, NH₃, SO₂, HONO, and HNO₃) were measured by a gas and aerosol collector combined with ion chromatography (GAC-IC) from September to November 2017 at an urban site in Chengdu. The average mass concentration of total water-soluble ions was 36.9 ± 29.4 μg m⁻³, accounting for 62.8% of PM₂.₅ mass. Nitrate was the most abundant ion, comprising 41.2% of the total ions, followed by sulfate (27.1%) and ammonium (18.1%), indicating the important contribution of motor vehicle emissions to PM₂.₅ in Chengdu. Secondary formation of inorganic ions and biomass burning emissions played a vital role in the haze pollution processes. The formation of nitrate aerosol was particularly dominant and exhibited the most substantial increase during haze processes. It was likely to be produced primarily through homogeneous reactions, whereas heterogeneous reactions dominated sulfate formation. Additionally, distinct differences in diurnal patterns of secondary inorganic ions between clean days and polluted days were observed, reflecting different formation characteristics under polluted conditions. Due to a large increase of acidic aerosols, most particles collected on polluted days were acidic, and ammonium in most samples existed mainly as NH₄HSO₄ and NH₄NO₃. Furthermore, backward-trajectory cluster analysis revealed that air masses originating from the northeast of Chengdu prevailed in the autumn season, and haze pollution was dominated mainly by short-distance transport within the Sichuan Basin.

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